Chemical and Mechanical Properties of Metakaolin-Based Geopolymers with Waste Corundum Powder Resulting from Erosion Testing

Alkali activated binders, based on an aluminosilicate powder that is activated by an alkaline solution, have been proven to encapsulate a wide number of different wastes, both in the form of liquids and solids. In this study, we investigated the effect that the addition of a spent abrasive powder, m...

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Main Authors: Giovanni Dal Poggetto, Pakamon Kittisayarm, Suphahud Pintasiri, Pongpak Chiyasak, Cristina Leonelli, Duangrudee Chaysuwan
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/14/23/5091
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author Giovanni Dal Poggetto
Pakamon Kittisayarm
Suphahud Pintasiri
Pongpak Chiyasak
Cristina Leonelli
Duangrudee Chaysuwan
author_facet Giovanni Dal Poggetto
Pakamon Kittisayarm
Suphahud Pintasiri
Pongpak Chiyasak
Cristina Leonelli
Duangrudee Chaysuwan
author_sort Giovanni Dal Poggetto
collection DOAJ
description Alkali activated binders, based on an aluminosilicate powder that is activated by an alkaline solution, have been proven to encapsulate a wide number of different wastes, both in the form of liquids and solids. In this study, we investigated the effect that the addition of a spent abrasive powder, mainly composed of corundum grains (RC), had on the mechanical, physical, and chemical properties of metakaolin-based geopolymers. The waste was introduced into the geopolymer matrix as a substitute for metakaolin, or added as a filler to the geopolymeric paste. The 3D cross-linking of the geopolymer structure, with and without the presence of the corundum, was investigated via Fourier transform infrared spectroscopy, X-ray diffraction, and ionic conductivity measurements of the eluate that was produced after 24 h of immersion of the sample in water. The RC powder did not significantly modify the matrix reticulation but increased densification, as observed with scanning electron microscopy, and there was increased resistance to compression by 10 wt% addition of RC, and also when added to the paste as a filler at 20 wt%.
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spelling doaj.art-0229f182198c4afdbf9adca9d444c6822023-11-24T11:58:10ZengMDPI AGPolymers2073-43602022-11-011423509110.3390/polym14235091Chemical and Mechanical Properties of Metakaolin-Based Geopolymers with Waste Corundum Powder Resulting from Erosion TestingGiovanni Dal Poggetto0Pakamon Kittisayarm1Suphahud Pintasiri2Pongpak Chiyasak3Cristina Leonelli4Duangrudee Chaysuwan5Department of Engineering “Enzo Ferrari”, University of Modena and Reggio Emilia, Via P. Vivarelli 10, 41125 Modena, ItalyDepartment of Materials Engineering, Faculty of Engineering, Kasetsart University, Bangkok 10900, ThailandDepartment of Materials Engineering, Faculty of Engineering, Kasetsart University, Bangkok 10900, ThailandDepartment of Materials Engineering, Faculty of Engineering, Kasetsart University, Bangkok 10900, ThailandDepartment of Engineering “Enzo Ferrari”, University of Modena and Reggio Emilia, Via P. Vivarelli 10, 41125 Modena, ItalyDepartment of Materials Engineering, Faculty of Engineering, Kasetsart University, Bangkok 10900, ThailandAlkali activated binders, based on an aluminosilicate powder that is activated by an alkaline solution, have been proven to encapsulate a wide number of different wastes, both in the form of liquids and solids. In this study, we investigated the effect that the addition of a spent abrasive powder, mainly composed of corundum grains (RC), had on the mechanical, physical, and chemical properties of metakaolin-based geopolymers. The waste was introduced into the geopolymer matrix as a substitute for metakaolin, or added as a filler to the geopolymeric paste. The 3D cross-linking of the geopolymer structure, with and without the presence of the corundum, was investigated via Fourier transform infrared spectroscopy, X-ray diffraction, and ionic conductivity measurements of the eluate that was produced after 24 h of immersion of the sample in water. The RC powder did not significantly modify the matrix reticulation but increased densification, as observed with scanning electron microscopy, and there was increased resistance to compression by 10 wt% addition of RC, and also when added to the paste as a filler at 20 wt%.https://www.mdpi.com/2073-4360/14/23/5091geopolymerrecycled corundumalkali activationmetakaolinmechanical performancesemireactive filler
spellingShingle Giovanni Dal Poggetto
Pakamon Kittisayarm
Suphahud Pintasiri
Pongpak Chiyasak
Cristina Leonelli
Duangrudee Chaysuwan
Chemical and Mechanical Properties of Metakaolin-Based Geopolymers with Waste Corundum Powder Resulting from Erosion Testing
Polymers
geopolymer
recycled corundum
alkali activation
metakaolin
mechanical performance
semireactive filler
title Chemical and Mechanical Properties of Metakaolin-Based Geopolymers with Waste Corundum Powder Resulting from Erosion Testing
title_full Chemical and Mechanical Properties of Metakaolin-Based Geopolymers with Waste Corundum Powder Resulting from Erosion Testing
title_fullStr Chemical and Mechanical Properties of Metakaolin-Based Geopolymers with Waste Corundum Powder Resulting from Erosion Testing
title_full_unstemmed Chemical and Mechanical Properties of Metakaolin-Based Geopolymers with Waste Corundum Powder Resulting from Erosion Testing
title_short Chemical and Mechanical Properties of Metakaolin-Based Geopolymers with Waste Corundum Powder Resulting from Erosion Testing
title_sort chemical and mechanical properties of metakaolin based geopolymers with waste corundum powder resulting from erosion testing
topic geopolymer
recycled corundum
alkali activation
metakaolin
mechanical performance
semireactive filler
url https://www.mdpi.com/2073-4360/14/23/5091
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