Removal of ammonium from aqueous solutions using alkali-modified biochars

Biochars converted from agricultural residuals can effectively remove ammonium from water. This work further improved the sorption ability of biochars to aqueous ammonium through alkali modification. Three modified biochars were prepared from agricultural residuals pre-treated with NaOH solution thr...

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Main Authors: Zhigang Liu, Yingwen Xue, Fei Gao, Xiaoru Cheng, Kai Yang
Format: Article
Language:English
Published: Taylor & Francis Group 2016-10-01
Series:Chemical Speciation & Bioavailability
Subjects:
Online Access:http://dx.doi.org/10.1080/09542299.2016.1142833
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author Zhigang Liu
Yingwen Xue
Fei Gao
Xiaoru Cheng
Kai Yang
author_facet Zhigang Liu
Yingwen Xue
Fei Gao
Xiaoru Cheng
Kai Yang
author_sort Zhigang Liu
collection DOAJ
description Biochars converted from agricultural residuals can effectively remove ammonium from water. This work further improved the sorption ability of biochars to aqueous ammonium through alkali modification. Three modified biochars were prepared from agricultural residuals pre-treated with NaOH solution through low-temperature (300 °C) slow pyrolysis. The modified biochars effectively removed ammonium ions from water under various conditions with relatively fast adsorption kinetics (reached equilibrium within 10 h) and extremely high adsorption capacity (>200 mg/g). The Langmuir maximum capacity of the three modified biochars were between 313.9 and 518.9 mg/g, higher than many other ammonium adsorbents. Although the sorption of ammonium onto the modified biochar was affected by pH and temperature, it was high under all of the tested conditions. Findings from this work indicated that alkali-modified biochars can be used as an alternative adsorbent for the removal of ammonium from wastewater.
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spelling doaj.art-022e3ef8e32547aeb51906bae98c05c62022-12-21T23:40:12ZengTaylor & Francis GroupChemical Speciation & Bioavailability0954-22992047-65232016-10-01281-4263210.1080/09542299.2016.11428331142833Removal of ammonium from aqueous solutions using alkali-modified biocharsZhigang Liu0Yingwen Xue1Fei Gao2Xiaoru Cheng3Kai Yang4Wuhan UniversityWuhan UniversityWuhan UniversityWuhan UniversityWuhan UniversityBiochars converted from agricultural residuals can effectively remove ammonium from water. This work further improved the sorption ability of biochars to aqueous ammonium through alkali modification. Three modified biochars were prepared from agricultural residuals pre-treated with NaOH solution through low-temperature (300 °C) slow pyrolysis. The modified biochars effectively removed ammonium ions from water under various conditions with relatively fast adsorption kinetics (reached equilibrium within 10 h) and extremely high adsorption capacity (>200 mg/g). The Langmuir maximum capacity of the three modified biochars were between 313.9 and 518.9 mg/g, higher than many other ammonium adsorbents. Although the sorption of ammonium onto the modified biochar was affected by pH and temperature, it was high under all of the tested conditions. Findings from this work indicated that alkali-modified biochars can be used as an alternative adsorbent for the removal of ammonium from wastewater.http://dx.doi.org/10.1080/09542299.2016.1142833Nutrientsorptionwater treatmentengineered biocharmodified biochar
spellingShingle Zhigang Liu
Yingwen Xue
Fei Gao
Xiaoru Cheng
Kai Yang
Removal of ammonium from aqueous solutions using alkali-modified biochars
Chemical Speciation & Bioavailability
Nutrient
sorption
water treatment
engineered biochar
modified biochar
title Removal of ammonium from aqueous solutions using alkali-modified biochars
title_full Removal of ammonium from aqueous solutions using alkali-modified biochars
title_fullStr Removal of ammonium from aqueous solutions using alkali-modified biochars
title_full_unstemmed Removal of ammonium from aqueous solutions using alkali-modified biochars
title_short Removal of ammonium from aqueous solutions using alkali-modified biochars
title_sort removal of ammonium from aqueous solutions using alkali modified biochars
topic Nutrient
sorption
water treatment
engineered biochar
modified biochar
url http://dx.doi.org/10.1080/09542299.2016.1142833
work_keys_str_mv AT zhigangliu removalofammoniumfromaqueoussolutionsusingalkalimodifiedbiochars
AT yingwenxue removalofammoniumfromaqueoussolutionsusingalkalimodifiedbiochars
AT feigao removalofammoniumfromaqueoussolutionsusingalkalimodifiedbiochars
AT xiaorucheng removalofammoniumfromaqueoussolutionsusingalkalimodifiedbiochars
AT kaiyang removalofammoniumfromaqueoussolutionsusingalkalimodifiedbiochars