Study on Gas Sorption and Iodine Uptake of a Metal-Organic Framework Based on Curcumin

Medi-MOF-1 is a highly porous Metal-Organic framework (MOF) constructed from Zn(II) and curcumin. The obtained crystal was characterized using powder X-ray diffraction (PXRD) and scanning electron microscopy (SEM). A micrometer-sized crystal with similar morphology was successfully obtained using th...

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Main Authors: Hongmin Su, Yang Zhou, Tao Huang, Fuxing Sun
Format: Article
Language:English
Published: MDPI AG 2023-07-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/28/13/5237
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author Hongmin Su
Yang Zhou
Tao Huang
Fuxing Sun
author_facet Hongmin Su
Yang Zhou
Tao Huang
Fuxing Sun
author_sort Hongmin Su
collection DOAJ
description Medi-MOF-1 is a highly porous Metal-Organic framework (MOF) constructed from Zn(II) and curcumin. The obtained crystal was characterized using powder X-ray diffraction (PXRD) and scanning electron microscopy (SEM). A micrometer-sized crystal with similar morphology was successfully obtained using the solvothermal method. Thanks to its high surface area, good stability, and abound pores, the as-synthesized medi-MOF-1 could be used as a functional porous material to adsorb different gases (H<sub>2</sub>, CO<sub>2</sub>, CH<sub>4</sub>, and N<sub>2</sub>) and iodine (I<sub>2</sub>). The activated sample exhibited a high I<sub>2</sub> adsorption ability of 1.936 g g<sup>–1</sup> at room temperature via vapor diffusion. Meanwhile, the adsorbed I<sub>2</sub> could be released slowly in ethanol, confirming the potential application for I<sub>2</sub> adsorption.
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spelling doaj.art-02671e5e4ede408c80a26e8fa55e67012023-11-18T17:10:14ZengMDPI AGMolecules1420-30492023-07-012813523710.3390/molecules28135237Study on Gas Sorption and Iodine Uptake of a Metal-Organic Framework Based on CurcuminHongmin Su0Yang Zhou1Tao Huang2Fuxing Sun3School of Environmental Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, ChinaSchool of Environmental Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, ChinaSchool of Environmental Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, ChinaState Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130021, ChinaMedi-MOF-1 is a highly porous Metal-Organic framework (MOF) constructed from Zn(II) and curcumin. The obtained crystal was characterized using powder X-ray diffraction (PXRD) and scanning electron microscopy (SEM). A micrometer-sized crystal with similar morphology was successfully obtained using the solvothermal method. Thanks to its high surface area, good stability, and abound pores, the as-synthesized medi-MOF-1 could be used as a functional porous material to adsorb different gases (H<sub>2</sub>, CO<sub>2</sub>, CH<sub>4</sub>, and N<sub>2</sub>) and iodine (I<sub>2</sub>). The activated sample exhibited a high I<sub>2</sub> adsorption ability of 1.936 g g<sup>–1</sup> at room temperature via vapor diffusion. Meanwhile, the adsorbed I<sub>2</sub> could be released slowly in ethanol, confirming the potential application for I<sub>2</sub> adsorption.https://www.mdpi.com/1420-3049/28/13/5237Metal-Organic frameworkgas sorptioniodine uptake
spellingShingle Hongmin Su
Yang Zhou
Tao Huang
Fuxing Sun
Study on Gas Sorption and Iodine Uptake of a Metal-Organic Framework Based on Curcumin
Molecules
Metal-Organic framework
gas sorption
iodine uptake
title Study on Gas Sorption and Iodine Uptake of a Metal-Organic Framework Based on Curcumin
title_full Study on Gas Sorption and Iodine Uptake of a Metal-Organic Framework Based on Curcumin
title_fullStr Study on Gas Sorption and Iodine Uptake of a Metal-Organic Framework Based on Curcumin
title_full_unstemmed Study on Gas Sorption and Iodine Uptake of a Metal-Organic Framework Based on Curcumin
title_short Study on Gas Sorption and Iodine Uptake of a Metal-Organic Framework Based on Curcumin
title_sort study on gas sorption and iodine uptake of a metal organic framework based on curcumin
topic Metal-Organic framework
gas sorption
iodine uptake
url https://www.mdpi.com/1420-3049/28/13/5237
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AT yangzhou studyongassorptionandiodineuptakeofametalorganicframeworkbasedoncurcumin
AT taohuang studyongassorptionandiodineuptakeofametalorganicframeworkbasedoncurcumin
AT fuxingsun studyongassorptionandiodineuptakeofametalorganicframeworkbasedoncurcumin