Studi Kinetika Reaksi Metanolisis Pembuatan Metil Ester Sulfonat (MES) Menggunakan Reaktor Batch Berpengaduk
Surfactant is a surface active agent which is widely applied in chemical industry related to its ability to stabilize the emulsion between the oil phase and the water phase. Surfactant-based on vegetable oil is a technology developed in the field of surfactant which has been dominated by surfactants...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Politeknik Negeri Malang
2017-10-01
|
| Series: | Jurnal Teknik Kimia dan Lingkungan |
| Subjects: | |
| Online Access: | http://jurnal.polinema.ac.id/index.php/jtkl/article/view/1709 |
| _version_ | 1797831027520962560 |
|---|---|
| author | Abdul Chalim Agung Ari Wibowo Ade Sonya Suryandari Muhammad Muhajjir Syarifuddin Moh. Tohir |
| author_facet | Abdul Chalim Agung Ari Wibowo Ade Sonya Suryandari Muhammad Muhajjir Syarifuddin Moh. Tohir |
| author_sort | Abdul Chalim |
| collection | DOAJ |
| description | Surfactant is a surface active agent which is widely applied in chemical industry related to its ability to stabilize the emulsion between the oil phase and the water phase. Surfactant-based on vegetable oil is a technology developed in the field of surfactant which has been dominated by surfactants made from petroleum. Methyl ester sulfonate (MES) is an anionic surfactant produced by the reaction between fatty acid methyl ester with a sulfonating agent or called as sulfonation reaction. MES undergoes an advanced process called methanolysis and neutralization reactions. This study investigated the effect of reactant molar ratio, reaction time and reaction temperature on MES yield on methanolysis reaction. The highest MES yield of 49.71% was achieved at a reaction temperature of 120°C, the reaction time of 120 minutes and the molar ratio between MES and methanol of 1:3. The rate constants of methanolysis reactions are determined by reacting the reactants in the stirred batch reactor under those operating conditions. |
| first_indexed | 2024-04-09T13:46:33Z |
| format | Article |
| id | doaj.art-027c814d0c134d798063d0ce6b33a089 |
| institution | Directory Open Access Journal |
| issn | 2579-8537 2579-9746 |
| language | English |
| last_indexed | 2024-04-09T13:46:33Z |
| publishDate | 2017-10-01 |
| publisher | Politeknik Negeri Malang |
| record_format | Article |
| series | Jurnal Teknik Kimia dan Lingkungan |
| spelling | doaj.art-027c814d0c134d798063d0ce6b33a0892023-05-09T03:24:29ZengPoliteknik Negeri MalangJurnal Teknik Kimia dan Lingkungan2579-85372579-97462017-10-0111283410.33795/jtkl.v1i1.231714Studi Kinetika Reaksi Metanolisis Pembuatan Metil Ester Sulfonat (MES) Menggunakan Reaktor Batch BerpengadukAbdul ChalimAgung Ari WibowoAde Sonya SuryandariMuhammad Muhajjir SyarifuddinMoh. TohirSurfactant is a surface active agent which is widely applied in chemical industry related to its ability to stabilize the emulsion between the oil phase and the water phase. Surfactant-based on vegetable oil is a technology developed in the field of surfactant which has been dominated by surfactants made from petroleum. Methyl ester sulfonate (MES) is an anionic surfactant produced by the reaction between fatty acid methyl ester with a sulfonating agent or called as sulfonation reaction. MES undergoes an advanced process called methanolysis and neutralization reactions. This study investigated the effect of reactant molar ratio, reaction time and reaction temperature on MES yield on methanolysis reaction. The highest MES yield of 49.71% was achieved at a reaction temperature of 120°C, the reaction time of 120 minutes and the molar ratio between MES and methanol of 1:3. The rate constants of methanolysis reactions are determined by reacting the reactants in the stirred batch reactor under those operating conditions.http://jurnal.polinema.ac.id/index.php/jtkl/article/view/1709reaction kineticsmethanolysismethyl ester sulfonatebatch reactorsurfactant |
| spellingShingle | Abdul Chalim Agung Ari Wibowo Ade Sonya Suryandari Muhammad Muhajjir Syarifuddin Moh. Tohir Studi Kinetika Reaksi Metanolisis Pembuatan Metil Ester Sulfonat (MES) Menggunakan Reaktor Batch Berpengaduk Jurnal Teknik Kimia dan Lingkungan reaction kinetics methanolysis methyl ester sulfonate batch reactor surfactant |
| title | Studi Kinetika Reaksi Metanolisis Pembuatan Metil Ester Sulfonat (MES) Menggunakan Reaktor Batch Berpengaduk |
| title_full | Studi Kinetika Reaksi Metanolisis Pembuatan Metil Ester Sulfonat (MES) Menggunakan Reaktor Batch Berpengaduk |
| title_fullStr | Studi Kinetika Reaksi Metanolisis Pembuatan Metil Ester Sulfonat (MES) Menggunakan Reaktor Batch Berpengaduk |
| title_full_unstemmed | Studi Kinetika Reaksi Metanolisis Pembuatan Metil Ester Sulfonat (MES) Menggunakan Reaktor Batch Berpengaduk |
| title_short | Studi Kinetika Reaksi Metanolisis Pembuatan Metil Ester Sulfonat (MES) Menggunakan Reaktor Batch Berpengaduk |
| title_sort | studi kinetika reaksi metanolisis pembuatan metil ester sulfonat mes menggunakan reaktor batch berpengaduk |
| topic | reaction kinetics methanolysis methyl ester sulfonate batch reactor surfactant |
| url | http://jurnal.polinema.ac.id/index.php/jtkl/article/view/1709 |
| work_keys_str_mv | AT abdulchalim studikinetikareaksimetanolisispembuatanmetilestersulfonatmesmenggunakanreaktorbatchberpengaduk AT agungariwibowo studikinetikareaksimetanolisispembuatanmetilestersulfonatmesmenggunakanreaktorbatchberpengaduk AT adesonyasuryandari studikinetikareaksimetanolisispembuatanmetilestersulfonatmesmenggunakanreaktorbatchberpengaduk AT muhammadmuhajjirsyarifuddin studikinetikareaksimetanolisispembuatanmetilestersulfonatmesmenggunakanreaktorbatchberpengaduk AT mohtohir studikinetikareaksimetanolisispembuatanmetilestersulfonatmesmenggunakanreaktorbatchberpengaduk |