Evaluation of the Antimicrobial, Thermal, Mechanical, and Barrier Properties of Corn Starch–Chitosan Biodegradable Films Reinforced with Cellulose Nanocrystals

Packaging materials play an essential role in the preservation and marketing of food and other products. To improve their conservation capacity, antimicrobial agents that inhibit bacterial growth are used. Biopolymers such as starch and chitosan are a sustainable alternative for the generation of fi...

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Main Authors: Claudio Alonso Díaz-Cruz, Carolina Caicedo, Enrique Javier Jiménez-Regalado, Ramón Díaz de León, Ricardo López-González, Rocio Yaneli Aguirre-Loredo
Format: Article
Language:English
Published: MDPI AG 2022-05-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/14/11/2166
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author Claudio Alonso Díaz-Cruz
Carolina Caicedo
Enrique Javier Jiménez-Regalado
Ramón Díaz de León
Ricardo López-González
Rocio Yaneli Aguirre-Loredo
author_facet Claudio Alonso Díaz-Cruz
Carolina Caicedo
Enrique Javier Jiménez-Regalado
Ramón Díaz de León
Ricardo López-González
Rocio Yaneli Aguirre-Loredo
author_sort Claudio Alonso Díaz-Cruz
collection DOAJ
description Packaging materials play an essential role in the preservation and marketing of food and other products. To improve their conservation capacity, antimicrobial agents that inhibit bacterial growth are used. Biopolymers such as starch and chitosan are a sustainable alternative for the generation of films for packaging that can also serve as a support for preservatives and antimicrobial agents. These substances can replace packaging of synthetic origin and maintain good functional properties to ensure the quality of food products. Films based on a mixture of corn starch and chitosan were developed by the casting method and the effect of incorporating cellulose nanocrystals (CNC) at different concentrations (0 to 10% <i>w</i>/<i>w</i>) was studied. The effect of the incorporation of CNC on the rheological, mechanical, thermal and barrier properties, as well as the antimicrobial activity of nanocomposite films, was evaluated. A significant modification of the functional and antimicrobial properties of the starch–chitosan films was observed with an increase in the concentration of nanomaterials. The films with CNC in a range of 0.5 to 5% presented the best performance. In line with the physicochemical characteristics which are desired in antimicrobial materials, this study can serve as a guide for the development this type of packaging for food use.
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spelling doaj.art-0287c93c6f6043b6b86598ed396ec6c62023-11-23T14:40:43ZengMDPI AGPolymers2073-43602022-05-011411216610.3390/polym14112166Evaluation of the Antimicrobial, Thermal, Mechanical, and Barrier Properties of Corn Starch–Chitosan Biodegradable Films Reinforced with Cellulose NanocrystalsClaudio Alonso Díaz-Cruz0Carolina Caicedo1Enrique Javier Jiménez-Regalado2Ramón Díaz de León3Ricardo López-González4Rocio Yaneli Aguirre-Loredo5Departamento de Ingeniería Química, Facultad de Ciencias Químicas, Universidad Autónoma de Coahuila, Blvd. Venustiano Carranza SN, Saltillo 25280, Coahuila, MexicoGrupo de Investigación en Química y Biotecnología (QUIBIO), Facultad de Ciencias Básicas, Universidad Santiago de Cali, Pampalinda, Santiago de Cali 760035, ColombiaDepartamento de Procesos de Polimerización, Centro de Investigación en Química Aplicada (CIQA), Blvd. Enrique Reyna Hermosillo 140, Saltillo 25294, Coahuila, MexicoDepartamento de Procesos de Polimerización, Centro de Investigación en Química Aplicada (CIQA), Blvd. Enrique Reyna Hermosillo 140, Saltillo 25294, Coahuila, MexicoDepartamento de Procesos de Polimerización, Centro de Investigación en Química Aplicada (CIQA), Blvd. Enrique Reyna Hermosillo 140, Saltillo 25294, Coahuila, MexicoDepartamento de Procesos de Polimerización, Centro de Investigación en Química Aplicada (CIQA), Blvd. Enrique Reyna Hermosillo 140, Saltillo 25294, Coahuila, MexicoPackaging materials play an essential role in the preservation and marketing of food and other products. To improve their conservation capacity, antimicrobial agents that inhibit bacterial growth are used. Biopolymers such as starch and chitosan are a sustainable alternative for the generation of films for packaging that can also serve as a support for preservatives and antimicrobial agents. These substances can replace packaging of synthetic origin and maintain good functional properties to ensure the quality of food products. Films based on a mixture of corn starch and chitosan were developed by the casting method and the effect of incorporating cellulose nanocrystals (CNC) at different concentrations (0 to 10% <i>w</i>/<i>w</i>) was studied. The effect of the incorporation of CNC on the rheological, mechanical, thermal and barrier properties, as well as the antimicrobial activity of nanocomposite films, was evaluated. A significant modification of the functional and antimicrobial properties of the starch–chitosan films was observed with an increase in the concentration of nanomaterials. The films with CNC in a range of 0.5 to 5% presented the best performance. In line with the physicochemical characteristics which are desired in antimicrobial materials, this study can serve as a guide for the development this type of packaging for food use.https://www.mdpi.com/2073-4360/14/11/2166biodegradable filmcorn starchchitosancellulose nanocrystalsantimicrobial filmnanocomposite
spellingShingle Claudio Alonso Díaz-Cruz
Carolina Caicedo
Enrique Javier Jiménez-Regalado
Ramón Díaz de León
Ricardo López-González
Rocio Yaneli Aguirre-Loredo
Evaluation of the Antimicrobial, Thermal, Mechanical, and Barrier Properties of Corn Starch–Chitosan Biodegradable Films Reinforced with Cellulose Nanocrystals
Polymers
biodegradable film
corn starch
chitosan
cellulose nanocrystals
antimicrobial film
nanocomposite
title Evaluation of the Antimicrobial, Thermal, Mechanical, and Barrier Properties of Corn Starch–Chitosan Biodegradable Films Reinforced with Cellulose Nanocrystals
title_full Evaluation of the Antimicrobial, Thermal, Mechanical, and Barrier Properties of Corn Starch–Chitosan Biodegradable Films Reinforced with Cellulose Nanocrystals
title_fullStr Evaluation of the Antimicrobial, Thermal, Mechanical, and Barrier Properties of Corn Starch–Chitosan Biodegradable Films Reinforced with Cellulose Nanocrystals
title_full_unstemmed Evaluation of the Antimicrobial, Thermal, Mechanical, and Barrier Properties of Corn Starch–Chitosan Biodegradable Films Reinforced with Cellulose Nanocrystals
title_short Evaluation of the Antimicrobial, Thermal, Mechanical, and Barrier Properties of Corn Starch–Chitosan Biodegradable Films Reinforced with Cellulose Nanocrystals
title_sort evaluation of the antimicrobial thermal mechanical and barrier properties of corn starch chitosan biodegradable films reinforced with cellulose nanocrystals
topic biodegradable film
corn starch
chitosan
cellulose nanocrystals
antimicrobial film
nanocomposite
url https://www.mdpi.com/2073-4360/14/11/2166
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