Tetraphenylphosphonium hydrogen oxalate
In the title compound, C24H20P+·C2HO4−, two symmetry-independent ion pairs are present. The cations aggregate into puckered sheets via zigzag infinite chains of sixfold phenyl embraces and parallel fourfold phenyl embraces, while the anions form hydrogen-bonded chains between the...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680706463X |
| _version_ | 1798031446075506688 |
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| author | Philip A. W. Dean Donald C. Craig Marcia L. Scudder Ian G. Dance |
| author_facet | Philip A. W. Dean Donald C. Craig Marcia L. Scudder Ian G. Dance |
| author_sort | Philip A. W. Dean |
| collection | DOAJ |
| description | In the title compound, C24H20P+·C2HO4−, two symmetry-independent ion pairs are present. The cations aggregate into puckered sheets via zigzag infinite chains of sixfold phenyl embraces and parallel fourfold phenyl embraces, while the anions form hydrogen-bonded chains between the sheets of cations. In the two independent oxalate anions, the angles between the normals to the two least-squares carboxylate COO planes are unusually large, viz. 72.5 (1) and 82.1 (1)°. |
| first_indexed | 2024-04-11T19:57:37Z |
| format | Article |
| id | doaj.art-02d3ee404ec843a290a7ce13f2a48003 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:57:37Z |
| publishDate | 2008-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-02d3ee404ec843a290a7ce13f2a480032022-12-22T04:05:53ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641o243o24310.1107/S160053680706463XTetraphenylphosphonium hydrogen oxalatePhilip A. W. DeanDonald C. CraigMarcia L. ScudderIan G. DanceIn the title compound, C24H20P+·C2HO4−, two symmetry-independent ion pairs are present. The cations aggregate into puckered sheets via zigzag infinite chains of sixfold phenyl embraces and parallel fourfold phenyl embraces, while the anions form hydrogen-bonded chains between the sheets of cations. In the two independent oxalate anions, the angles between the normals to the two least-squares carboxylate COO planes are unusually large, viz. 72.5 (1) and 82.1 (1)°.http://scripts.iucr.org/cgi-bin/paper?S160053680706463X |
| spellingShingle | Philip A. W. Dean Donald C. Craig Marcia L. Scudder Ian G. Dance Tetraphenylphosphonium hydrogen oxalate Acta Crystallographica Section E |
| title | Tetraphenylphosphonium hydrogen oxalate |
| title_full | Tetraphenylphosphonium hydrogen oxalate |
| title_fullStr | Tetraphenylphosphonium hydrogen oxalate |
| title_full_unstemmed | Tetraphenylphosphonium hydrogen oxalate |
| title_short | Tetraphenylphosphonium hydrogen oxalate |
| title_sort | tetraphenylphosphonium hydrogen oxalate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053680706463X |
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