Diaquabis[2-(2-hydroxyethyl)pyridine-κ2N,O]cobalt(II) dichloride
In the title salt, [Co(C7H9NO)2(H2O)2]Cl2, the CoII cation, located on an inversion center, is N,O-chelated by two hydroxyethylpyridine ligands and coordinated by two water molecules in a distorted O4N2 octahedral geometry. In the crystal, the Cl− anions link with the complex cations via O...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2013-08-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813018321 |
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author | Hocine Merazig Lamia Bendjeddou Nasreddine Hadjadj Fatiha Guenifa Ouahida Zeghouan |
author_facet | Hocine Merazig Lamia Bendjeddou Nasreddine Hadjadj Fatiha Guenifa Ouahida Zeghouan |
author_sort | Hocine Merazig |
collection | DOAJ |
description | In the title salt, [Co(C7H9NO)2(H2O)2]Cl2, the CoII cation, located on an inversion center, is N,O-chelated by two hydroxyethylpyridine ligands and coordinated by two water molecules in a distorted O4N2 octahedral geometry. In the crystal, the Cl− anions link with the complex cations via O—H...Cl hydrogen bonds, forming a three-dimensional supramolecular architecture. π–π stacking is observed between the pyridine rings of adjacent molecules [centroid–centroid distance = 3.5810 (11) Å]. |
first_indexed | 2024-12-20T11:54:41Z |
format | Article |
id | doaj.art-02de9ebb5da1419db369e1e3acb9ac10 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-20T11:54:41Z |
publishDate | 2013-08-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-02de9ebb5da1419db369e1e3acb9ac102022-12-21T19:41:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-08-01698m439m44010.1107/S1600536813018321Diaquabis[2-(2-hydroxyethyl)pyridine-κ2N,O]cobalt(II) dichlorideHocine MerazigLamia BendjeddouNasreddine HadjadjFatiha GuenifaOuahida ZeghouanIn the title salt, [Co(C7H9NO)2(H2O)2]Cl2, the CoII cation, located on an inversion center, is N,O-chelated by two hydroxyethylpyridine ligands and coordinated by two water molecules in a distorted O4N2 octahedral geometry. In the crystal, the Cl− anions link with the complex cations via O—H...Cl hydrogen bonds, forming a three-dimensional supramolecular architecture. π–π stacking is observed between the pyridine rings of adjacent molecules [centroid–centroid distance = 3.5810 (11) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536813018321 |
spellingShingle | Hocine Merazig Lamia Bendjeddou Nasreddine Hadjadj Fatiha Guenifa Ouahida Zeghouan Diaquabis[2-(2-hydroxyethyl)pyridine-κ2N,O]cobalt(II) dichloride Acta Crystallographica Section E |
title | Diaquabis[2-(2-hydroxyethyl)pyridine-κ2N,O]cobalt(II) dichloride |
title_full | Diaquabis[2-(2-hydroxyethyl)pyridine-κ2N,O]cobalt(II) dichloride |
title_fullStr | Diaquabis[2-(2-hydroxyethyl)pyridine-κ2N,O]cobalt(II) dichloride |
title_full_unstemmed | Diaquabis[2-(2-hydroxyethyl)pyridine-κ2N,O]cobalt(II) dichloride |
title_short | Diaquabis[2-(2-hydroxyethyl)pyridine-κ2N,O]cobalt(II) dichloride |
title_sort | diaquabis 2 2 hydroxyethyl pyridine 954 2n o cobalt ii dichloride |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536813018321 |
work_keys_str_mv | AT hocinemerazig diaquabis22hydroxyethylpyridine9542nocobaltiidichloride AT lamiabendjeddou diaquabis22hydroxyethylpyridine9542nocobaltiidichloride AT nasreddinehadjadj diaquabis22hydroxyethylpyridine9542nocobaltiidichloride AT fatihaguenifa diaquabis22hydroxyethylpyridine9542nocobaltiidichloride AT ouahidazeghouan diaquabis22hydroxyethylpyridine9542nocobaltiidichloride |