Diaquabis[2-(2-hydroxyethyl)pyridine-κ2N,O]cobalt(II) dichloride

In the title salt, [Co(C7H9NO)2(H2O)2]Cl2, the CoII cation, located on an inversion center, is N,O-chelated by two hydroxyethylpyridine ligands and coordinated by two water molecules in a distorted O4N2 octahedral geometry. In the crystal, the Cl− anions link with the complex cations via O...

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Main Authors: Hocine Merazig, Lamia Bendjeddou, Nasreddine Hadjadj, Fatiha Guenifa, Ouahida Zeghouan
Format: Article
Language:English
Published: International Union of Crystallography 2013-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813018321
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author Hocine Merazig
Lamia Bendjeddou
Nasreddine Hadjadj
Fatiha Guenifa
Ouahida Zeghouan
author_facet Hocine Merazig
Lamia Bendjeddou
Nasreddine Hadjadj
Fatiha Guenifa
Ouahida Zeghouan
author_sort Hocine Merazig
collection DOAJ
description In the title salt, [Co(C7H9NO)2(H2O)2]Cl2, the CoII cation, located on an inversion center, is N,O-chelated by two hydroxyethylpyridine ligands and coordinated by two water molecules in a distorted O4N2 octahedral geometry. In the crystal, the Cl− anions link with the complex cations via O—H...Cl hydrogen bonds, forming a three-dimensional supramolecular architecture. π–π stacking is observed between the pyridine rings of adjacent molecules [centroid–centroid distance = 3.5810 (11) Å].
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spelling doaj.art-02de9ebb5da1419db369e1e3acb9ac102022-12-21T19:41:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-08-01698m439m44010.1107/S1600536813018321Diaquabis[2-(2-hydroxyethyl)pyridine-κ2N,O]cobalt(II) dichlorideHocine MerazigLamia BendjeddouNasreddine HadjadjFatiha GuenifaOuahida ZeghouanIn the title salt, [Co(C7H9NO)2(H2O)2]Cl2, the CoII cation, located on an inversion center, is N,O-chelated by two hydroxyethylpyridine ligands and coordinated by two water molecules in a distorted O4N2 octahedral geometry. In the crystal, the Cl− anions link with the complex cations via O—H...Cl hydrogen bonds, forming a three-dimensional supramolecular architecture. π–π stacking is observed between the pyridine rings of adjacent molecules [centroid–centroid distance = 3.5810 (11) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536813018321
spellingShingle Hocine Merazig
Lamia Bendjeddou
Nasreddine Hadjadj
Fatiha Guenifa
Ouahida Zeghouan
Diaquabis[2-(2-hydroxyethyl)pyridine-κ2N,O]cobalt(II) dichloride
Acta Crystallographica Section E
title Diaquabis[2-(2-hydroxyethyl)pyridine-κ2N,O]cobalt(II) dichloride
title_full Diaquabis[2-(2-hydroxyethyl)pyridine-κ2N,O]cobalt(II) dichloride
title_fullStr Diaquabis[2-(2-hydroxyethyl)pyridine-κ2N,O]cobalt(II) dichloride
title_full_unstemmed Diaquabis[2-(2-hydroxyethyl)pyridine-κ2N,O]cobalt(II) dichloride
title_short Diaquabis[2-(2-hydroxyethyl)pyridine-κ2N,O]cobalt(II) dichloride
title_sort diaquabis 2 2 hydroxyethyl pyridine 954 2n o cobalt ii dichloride
url http://scripts.iucr.org/cgi-bin/paper?S1600536813018321
work_keys_str_mv AT hocinemerazig diaquabis22hydroxyethylpyridine9542nocobaltiidichloride
AT lamiabendjeddou diaquabis22hydroxyethylpyridine9542nocobaltiidichloride
AT nasreddinehadjadj diaquabis22hydroxyethylpyridine9542nocobaltiidichloride
AT fatihaguenifa diaquabis22hydroxyethylpyridine9542nocobaltiidichloride
AT ouahidazeghouan diaquabis22hydroxyethylpyridine9542nocobaltiidichloride