Photo-Aligned Nematic Liquid Crystals Enable the Modulation of Thermoplasmonic Heating

We experimentally demonstrate that the plasmonic heat delivered by a single layer of homogeneously distributed gold nanoparticles (AuNPs), immobilized on a glass substrate, can be optically tuned by taking advantage of the properties of an organic layer based on azobenzene and nematic liquid crystal...

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Main Authors: Giovanna Palermo, Rossella Grillo, Luigia Pezzi, Thomas Bürgi, Nelson Tabiryan, Luciano De Sio, Cesare Umeton
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/11/14/6272
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author Giovanna Palermo
Rossella Grillo
Luigia Pezzi
Thomas Bürgi
Nelson Tabiryan
Luciano De Sio
Cesare Umeton
author_facet Giovanna Palermo
Rossella Grillo
Luigia Pezzi
Thomas Bürgi
Nelson Tabiryan
Luciano De Sio
Cesare Umeton
author_sort Giovanna Palermo
collection DOAJ
description We experimentally demonstrate that the plasmonic heat delivered by a single layer of homogeneously distributed gold nanoparticles (AuNPs), immobilized on a glass substrate, can be optically tuned by taking advantage of the properties of an organic layer based on azobenzene and nematic liquid crystal (NLC) molecules. The effect, which exploits the dependence of the NLC refractive index value on the molecular director orientation, is realized using the polarization-dependent, light-induced molecular reorientation of a thin film of photo-aligning material that the NLC is in contact with. The reversibility of the optically induced molecular director reorientation of the NLC enables an active modulation of the plasmonic photo-induced heat.
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spelling doaj.art-02df1306d2ba42478434cef6cb9d6e7b2023-11-22T03:06:57ZengMDPI AGApplied Sciences2076-34172021-07-011114627210.3390/app11146272Photo-Aligned Nematic Liquid Crystals Enable the Modulation of Thermoplasmonic HeatingGiovanna Palermo0Rossella Grillo1Luigia Pezzi2Thomas Bürgi3Nelson Tabiryan4Luciano De Sio5Cesare Umeton6Department of Physics, University of Calabria, Via P. Bucci, 87036 Rende, ItalyDepartment of Physical Chemistry, University of Geneva, 41211 Geneva, SwitzerlandDepartment of Physics, University of Calabria, Via P. Bucci, 87036 Rende, ItalyDepartment of Physical Chemistry, University of Geneva, 41211 Geneva, SwitzerlandBeam Engineering for Advanced Measurements Company, 1300 Lee Road, Orlando, FL 32789, USACNR NANOTEC—Istituto di Nanotecnologia, UOS Cosenza, 87036 Rende, ItalyDepartment of Physics, University of Calabria, Via P. Bucci, 87036 Rende, ItalyWe experimentally demonstrate that the plasmonic heat delivered by a single layer of homogeneously distributed gold nanoparticles (AuNPs), immobilized on a glass substrate, can be optically tuned by taking advantage of the properties of an organic layer based on azobenzene and nematic liquid crystal (NLC) molecules. The effect, which exploits the dependence of the NLC refractive index value on the molecular director orientation, is realized using the polarization-dependent, light-induced molecular reorientation of a thin film of photo-aligning material that the NLC is in contact with. The reversibility of the optically induced molecular director reorientation of the NLC enables an active modulation of the plasmonic photo-induced heat.https://www.mdpi.com/2076-3417/11/14/6272thermoplasmonicsmetallic nanoparticlesliquid crystalsreconfigurabilityphoto-aligning materials
spellingShingle Giovanna Palermo
Rossella Grillo
Luigia Pezzi
Thomas Bürgi
Nelson Tabiryan
Luciano De Sio
Cesare Umeton
Photo-Aligned Nematic Liquid Crystals Enable the Modulation of Thermoplasmonic Heating
Applied Sciences
thermoplasmonics
metallic nanoparticles
liquid crystals
reconfigurability
photo-aligning materials
title Photo-Aligned Nematic Liquid Crystals Enable the Modulation of Thermoplasmonic Heating
title_full Photo-Aligned Nematic Liquid Crystals Enable the Modulation of Thermoplasmonic Heating
title_fullStr Photo-Aligned Nematic Liquid Crystals Enable the Modulation of Thermoplasmonic Heating
title_full_unstemmed Photo-Aligned Nematic Liquid Crystals Enable the Modulation of Thermoplasmonic Heating
title_short Photo-Aligned Nematic Liquid Crystals Enable the Modulation of Thermoplasmonic Heating
title_sort photo aligned nematic liquid crystals enable the modulation of thermoplasmonic heating
topic thermoplasmonics
metallic nanoparticles
liquid crystals
reconfigurability
photo-aligning materials
url https://www.mdpi.com/2076-3417/11/14/6272
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