Dichloridobis[1-(2,4,6-trimethylphenyl)-1H-imidazole-κN3]copper(II)
In the title complex, [CuCl2(C12H14N2)2], the Cu2+ cation is situated on an inversion centre and is coordinated by two N atoms from symmetry-related 1-mesityl-1H-imidazole ligands and by two chloride anions in a slightly distorted square-planar geometry. In the organic ligand, the dihedral angle bet...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-11-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813028821 |
| _version_ | 1818959595615289344 |
|---|---|
| author | Yantao Zhang Zhuzhen Lin |
| author_facet | Yantao Zhang Zhuzhen Lin |
| author_sort | Yantao Zhang |
| collection | DOAJ |
| description | In the title complex, [CuCl2(C12H14N2)2], the Cu2+ cation is situated on an inversion centre and is coordinated by two N atoms from symmetry-related 1-mesityl-1H-imidazole ligands and by two chloride anions in a slightly distorted square-planar geometry. In the organic ligand, the dihedral angle between the benzene ring of the mesityl moiety and the imidazole ring is 76.99 (18)°. Weak intramolecular C—H...Cl hydrogen-bonding interactions consolidate the molecular conformation. |
| first_indexed | 2024-12-20T11:44:08Z |
| format | Article |
| id | doaj.art-02eae9564a6e4dd2bdd6034774986c1e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:44:08Z |
| publishDate | 2013-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-02eae9564a6e4dd2bdd6034774986c1e2022-12-21T19:41:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-11-016911m621m62110.1107/S1600536813028821Dichloridobis[1-(2,4,6-trimethylphenyl)-1H-imidazole-κN3]copper(II)Yantao ZhangZhuzhen LinIn the title complex, [CuCl2(C12H14N2)2], the Cu2+ cation is situated on an inversion centre and is coordinated by two N atoms from symmetry-related 1-mesityl-1H-imidazole ligands and by two chloride anions in a slightly distorted square-planar geometry. In the organic ligand, the dihedral angle between the benzene ring of the mesityl moiety and the imidazole ring is 76.99 (18)°. Weak intramolecular C—H...Cl hydrogen-bonding interactions consolidate the molecular conformation.http://scripts.iucr.org/cgi-bin/paper?S1600536813028821 |
| spellingShingle | Yantao Zhang Zhuzhen Lin Dichloridobis[1-(2,4,6-trimethylphenyl)-1H-imidazole-κN3]copper(II) Acta Crystallographica Section E |
| title | Dichloridobis[1-(2,4,6-trimethylphenyl)-1H-imidazole-κN3]copper(II) |
| title_full | Dichloridobis[1-(2,4,6-trimethylphenyl)-1H-imidazole-κN3]copper(II) |
| title_fullStr | Dichloridobis[1-(2,4,6-trimethylphenyl)-1H-imidazole-κN3]copper(II) |
| title_full_unstemmed | Dichloridobis[1-(2,4,6-trimethylphenyl)-1H-imidazole-κN3]copper(II) |
| title_short | Dichloridobis[1-(2,4,6-trimethylphenyl)-1H-imidazole-κN3]copper(II) |
| title_sort | dichloridobis 1 2 4 6 trimethylphenyl 1h imidazole 954 n3 copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813028821 |
| work_keys_str_mv | AT yantaozhang dichloridobis1246trimethylphenyl1himidazole954n3copperii AT zhuzhenlin dichloridobis1246trimethylphenyl1himidazole954n3copperii |