Geochemistry of Fe3+ in the hydrothermal dickite from Jedlina Zdroj (Lower Silesia, Poland)
Geochemical analysis for Fe was made on a representative sample of dickite-rich hydrothermal clay from Jedlina Zdroj. The mineralogy of the sample is comparatively simple, dickite being the principal component (>95 wt. % of the total sample), with lesser amounts of goethite and barite. Geochemica...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2009-01-01
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| Series: | Journal of the Serbian Chemical Society |
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| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2009/0352-51390912477P.pdf |
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| author | Premović Pavle I. Ciesielczuk Justyna Todorović Bratislav Ž. Đorđević Dragan M. Krstić Nenad S. |
| author_facet | Premović Pavle I. Ciesielczuk Justyna Todorović Bratislav Ž. Đorđević Dragan M. Krstić Nenad S. |
| author_sort | Premović Pavle I. |
| collection | DOAJ |
| description | Geochemical analysis for Fe was made on a representative sample of dickite-rich hydrothermal clay from Jedlina Zdroj. The mineralogy of the sample is comparatively simple, dickite being the principal component (>95 wt. % of the total sample), with lesser amounts of goethite and barite. Geochemical fractionation and inductively coupled plasma-optical emission spectrometry indicated that most of the Fe (ca. 97 wt. % of the total metal) resides in the dickite. Electron spin resonance showed that some of the Fe in the dickite structure is in the form of Fe3+. A substantial proportion of these ions (as well as Fe) in the dickite matrix were probably contained in the original hydrothermal dickite-forming solution. From the geochemistry of Fe3+, it was deduced that the oxidation potential (Eh) and pH of the solution during the formation of dickite from the Jedlina Zdroj were approximately 0.45-0.95 V (highly oxygenated) and 0-4 (highly acidic), respectively. |
| first_indexed | 2024-12-13T13:00:58Z |
| format | Article |
| id | doaj.art-02ef6e5dceb54771991199d6ecb7c314 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 1820-7421 |
| language | English |
| last_indexed | 2024-12-13T13:00:58Z |
| publishDate | 2009-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-02ef6e5dceb54771991199d6ecb7c3142022-12-21T23:45:02ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212009-01-0174121477148910.2298/JSC0912477P0352-51390912477PGeochemistry of Fe3+ in the hydrothermal dickite from Jedlina Zdroj (Lower Silesia, Poland)Premović Pavle I.0Ciesielczuk Justyna1Todorović Bratislav Ž.2Đorđević Dragan M.3Krstić Nenad S.4Laboratorija za geohemiju, kosmohemiju i astrohemiju, Prirodno-matematički fakultet, NišDepartment of General Geology, Faculty of Earth Sciences, University of Silesia, Sosnowiec, PolandLaboratorija za opštu hemiju, Tehnološki fakultet, LeskovacLaboratorija za geohemiju, kosmohemiju i astrohemiju, Prirodno-matematički fakultet, NišLaboratorija za geohemiju, kosmohemiju i astrohemiju, Prirodno-matematički fakultet, NišGeochemical analysis for Fe was made on a representative sample of dickite-rich hydrothermal clay from Jedlina Zdroj. The mineralogy of the sample is comparatively simple, dickite being the principal component (>95 wt. % of the total sample), with lesser amounts of goethite and barite. Geochemical fractionation and inductively coupled plasma-optical emission spectrometry indicated that most of the Fe (ca. 97 wt. % of the total metal) resides in the dickite. Electron spin resonance showed that some of the Fe in the dickite structure is in the form of Fe3+. A substantial proportion of these ions (as well as Fe) in the dickite matrix were probably contained in the original hydrothermal dickite-forming solution. From the geochemistry of Fe3+, it was deduced that the oxidation potential (Eh) and pH of the solution during the formation of dickite from the Jedlina Zdroj were approximately 0.45-0.95 V (highly oxygenated) and 0-4 (highly acidic), respectively.http://www.doiserbia.nb.rs/img/doi/0352-5139/2009/0352-51390912477P.pdfkaolinitedickiteiron |
| spellingShingle | Premović Pavle I. Ciesielczuk Justyna Todorović Bratislav Ž. Đorđević Dragan M. Krstić Nenad S. Geochemistry of Fe3+ in the hydrothermal dickite from Jedlina Zdroj (Lower Silesia, Poland) Journal of the Serbian Chemical Society kaolinite dickite iron |
| title | Geochemistry of Fe3+ in the hydrothermal dickite from Jedlina Zdroj (Lower Silesia, Poland) |
| title_full | Geochemistry of Fe3+ in the hydrothermal dickite from Jedlina Zdroj (Lower Silesia, Poland) |
| title_fullStr | Geochemistry of Fe3+ in the hydrothermal dickite from Jedlina Zdroj (Lower Silesia, Poland) |
| title_full_unstemmed | Geochemistry of Fe3+ in the hydrothermal dickite from Jedlina Zdroj (Lower Silesia, Poland) |
| title_short | Geochemistry of Fe3+ in the hydrothermal dickite from Jedlina Zdroj (Lower Silesia, Poland) |
| title_sort | geochemistry of fe3 in the hydrothermal dickite from jedlina zdroj lower silesia poland |
| topic | kaolinite dickite iron |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2009/0352-51390912477P.pdf |
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