Ligand-controlled stereodivergent alkenylation of alkynes to access functionalized trans- and cis-1,3-dienes
The stereoselective synthesis of 1,3-dienes represents a challenge in organic synthesis. Here, the authors report a ligand-controlled stereodivergent access to both Z- and E-sulfonyl-1,3-dienes via photoredox and nickel catalysis.
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2023-01-01
|
| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-35688-2 |
| _version_ | 1797958532111269888 |
|---|---|
| author | Tianyu Long Chen Zhu Ling Li Liang Shao Shengqing Zhu Magnus Rueping Lingling Chu |
| author_facet | Tianyu Long Chen Zhu Ling Li Liang Shao Shengqing Zhu Magnus Rueping Lingling Chu |
| author_sort | Tianyu Long |
| collection | DOAJ |
| description | The stereoselective synthesis of 1,3-dienes represents a challenge in organic synthesis. Here, the authors report a ligand-controlled stereodivergent access to both Z- and E-sulfonyl-1,3-dienes via photoredox and nickel catalysis. |
| first_indexed | 2024-04-11T00:21:26Z |
| format | Article |
| id | doaj.art-02f570f044bf4eea93acb82ca6489f32 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-11T00:21:26Z |
| publishDate | 2023-01-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-02f570f044bf4eea93acb82ca6489f322023-01-08T12:15:23ZengNature PortfolioNature Communications2041-17232023-01-0114111110.1038/s41467-022-35688-2Ligand-controlled stereodivergent alkenylation of alkynes to access functionalized trans- and cis-1,3-dienesTianyu Long0Chen Zhu1Ling Li2Liang Shao3Shengqing Zhu4Magnus Rueping5Lingling Chu6State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-Dimension Materials, Donghua University, College of Chemistry and Chemical EngineeringKing Abdullah University of Science and Technology (KAUST), KAUST Catalysis Center (KCC)State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-Dimension Materials, Donghua University, College of Chemistry and Chemical EngineeringState Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-Dimension Materials, Donghua University, College of Chemistry and Chemical EngineeringState Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-Dimension Materials, Donghua University, College of Chemistry and Chemical EngineeringKing Abdullah University of Science and Technology (KAUST), KAUST Catalysis Center (KCC)State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-Dimension Materials, Donghua University, College of Chemistry and Chemical EngineeringThe stereoselective synthesis of 1,3-dienes represents a challenge in organic synthesis. Here, the authors report a ligand-controlled stereodivergent access to both Z- and E-sulfonyl-1,3-dienes via photoredox and nickel catalysis.https://doi.org/10.1038/s41467-022-35688-2 |
| spellingShingle | Tianyu Long Chen Zhu Ling Li Liang Shao Shengqing Zhu Magnus Rueping Lingling Chu Ligand-controlled stereodivergent alkenylation of alkynes to access functionalized trans- and cis-1,3-dienes Nature Communications |
| title | Ligand-controlled stereodivergent alkenylation of alkynes to access functionalized trans- and cis-1,3-dienes |
| title_full | Ligand-controlled stereodivergent alkenylation of alkynes to access functionalized trans- and cis-1,3-dienes |
| title_fullStr | Ligand-controlled stereodivergent alkenylation of alkynes to access functionalized trans- and cis-1,3-dienes |
| title_full_unstemmed | Ligand-controlled stereodivergent alkenylation of alkynes to access functionalized trans- and cis-1,3-dienes |
| title_short | Ligand-controlled stereodivergent alkenylation of alkynes to access functionalized trans- and cis-1,3-dienes |
| title_sort | ligand controlled stereodivergent alkenylation of alkynes to access functionalized trans and cis 1 3 dienes |
| url | https://doi.org/10.1038/s41467-022-35688-2 |
| work_keys_str_mv | AT tianyulong ligandcontrolledstereodivergentalkenylationofalkynestoaccessfunctionalizedtransandcis13dienes AT chenzhu ligandcontrolledstereodivergentalkenylationofalkynestoaccessfunctionalizedtransandcis13dienes AT lingli ligandcontrolledstereodivergentalkenylationofalkynestoaccessfunctionalizedtransandcis13dienes AT liangshao ligandcontrolledstereodivergentalkenylationofalkynestoaccessfunctionalizedtransandcis13dienes AT shengqingzhu ligandcontrolledstereodivergentalkenylationofalkynestoaccessfunctionalizedtransandcis13dienes AT magnusrueping ligandcontrolledstereodivergentalkenylationofalkynestoaccessfunctionalizedtransandcis13dienes AT linglingchu ligandcontrolledstereodivergentalkenylationofalkynestoaccessfunctionalizedtransandcis13dienes |