The Negative Photoconductivity of Ag/AgO Grown by Spray-Pyrolysis

The main goal of this work is to provide a general description of the negative photoconductivity effect observed in Ag/AgO films grown by the spray-pyrolysis technique. X-ray diffractograms display hybrid films with high texturized AgO and metallic Ag phases. Scanning electron microscopy images show...

Full description

Bibliographic Details
Main Authors: Aline Bastos de Paiva, Luis Miguel Bolaños Vargas, Matheus José da Silva, Ariano De Giovanni Rodrigues, Demétrio A. W. Soares, Marcelos Lima Peres, Marcio Peron Franco de Godoy
Format: Article
Language:English
Published: MDPI AG 2022-03-01
Series:Surfaces
Subjects:
Online Access:https://www.mdpi.com/2571-9637/5/1/14
_version_ 1797442004162969600
author Aline Bastos de Paiva
Luis Miguel Bolaños Vargas
Matheus José da Silva
Ariano De Giovanni Rodrigues
Demétrio A. W. Soares
Marcelos Lima Peres
Marcio Peron Franco de Godoy
author_facet Aline Bastos de Paiva
Luis Miguel Bolaños Vargas
Matheus José da Silva
Ariano De Giovanni Rodrigues
Demétrio A. W. Soares
Marcelos Lima Peres
Marcio Peron Franco de Godoy
author_sort Aline Bastos de Paiva
collection DOAJ
description The main goal of this work is to provide a general description of the negative photoconductivity effect observed in Ag/AgO films grown by the spray-pyrolysis technique. X-ray diffractograms display hybrid films with high texturized AgO and metallic Ag phases. Scanning electron microscopy images show small Ag particles on the surface. Due to its surface nature, X-ray photoelectron spectroscopy revealed the predominance of the metallic character of Ag 3d spectra as compared to Ag<sup>2+</sup>. Negative photoconductivity with photoresponse in the order of seconds is observed under several wavelengths of excitation. We found that the amplitude of the negative photoresponse is strongly dependent on the optical absorbance and enhanced by surface plasmon resonance. The low-cost technique employed and the special features regarding negative photoconductivity provide an exciting platform for developing optical-electronic devices with low power consumption.
first_indexed 2024-03-09T12:35:31Z
format Article
id doaj.art-02fb78b81a374b24b5a24c92e19aafb5
institution Directory Open Access Journal
issn 2571-9637
language English
last_indexed 2024-03-09T12:35:31Z
publishDate 2022-03-01
publisher MDPI AG
record_format Article
series Surfaces
spelling doaj.art-02fb78b81a374b24b5a24c92e19aafb52023-11-30T22:24:47ZengMDPI AGSurfaces2571-96372022-03-015120921710.3390/surfaces5010014The Negative Photoconductivity of Ag/AgO Grown by Spray-PyrolysisAline Bastos de Paiva0Luis Miguel Bolaños Vargas1Matheus José da Silva2Ariano De Giovanni Rodrigues3Demétrio A. W. Soares4Marcelos Lima Peres5Marcio Peron Franco de Godoy6Departamento de Física, Universidade Federal de São Carlos, São Carlos 13565-905, SP, BrazilInstituto de Física e Química, Universidade Federal de Itajuba, Itajubá 37500-903, MG, BrazilInstituto de Física e Química, Universidade Federal de Itajuba, Itajubá 37500-903, MG, BrazilDepartamento de Física, Universidade Federal de São Carlos, São Carlos 13565-905, SP, BrazilInstituto de Física e Química, Universidade Federal de Itajuba, Itajubá 37500-903, MG, BrazilInstituto de Física e Química, Universidade Federal de Itajuba, Itajubá 37500-903, MG, BrazilDepartamento de Física, Universidade Federal de São Carlos, São Carlos 13565-905, SP, BrazilThe main goal of this work is to provide a general description of the negative photoconductivity effect observed in Ag/AgO films grown by the spray-pyrolysis technique. X-ray diffractograms display hybrid films with high texturized AgO and metallic Ag phases. Scanning electron microscopy images show small Ag particles on the surface. Due to its surface nature, X-ray photoelectron spectroscopy revealed the predominance of the metallic character of Ag 3d spectra as compared to Ag<sup>2+</sup>. Negative photoconductivity with photoresponse in the order of seconds is observed under several wavelengths of excitation. We found that the amplitude of the negative photoresponse is strongly dependent on the optical absorbance and enhanced by surface plasmon resonance. The low-cost technique employed and the special features regarding negative photoconductivity provide an exciting platform for developing optical-electronic devices with low power consumption.https://www.mdpi.com/2571-9637/5/1/14oxidesphotoconductivitysilversurface plasmon resonance
spellingShingle Aline Bastos de Paiva
Luis Miguel Bolaños Vargas
Matheus José da Silva
Ariano De Giovanni Rodrigues
Demétrio A. W. Soares
Marcelos Lima Peres
Marcio Peron Franco de Godoy
The Negative Photoconductivity of Ag/AgO Grown by Spray-Pyrolysis
Surfaces
oxides
photoconductivity
silver
surface plasmon resonance
title The Negative Photoconductivity of Ag/AgO Grown by Spray-Pyrolysis
title_full The Negative Photoconductivity of Ag/AgO Grown by Spray-Pyrolysis
title_fullStr The Negative Photoconductivity of Ag/AgO Grown by Spray-Pyrolysis
title_full_unstemmed The Negative Photoconductivity of Ag/AgO Grown by Spray-Pyrolysis
title_short The Negative Photoconductivity of Ag/AgO Grown by Spray-Pyrolysis
title_sort negative photoconductivity of ag ago grown by spray pyrolysis
topic oxides
photoconductivity
silver
surface plasmon resonance
url https://www.mdpi.com/2571-9637/5/1/14
work_keys_str_mv AT alinebastosdepaiva thenegativephotoconductivityofagagogrownbyspraypyrolysis
AT luismiguelbolanosvargas thenegativephotoconductivityofagagogrownbyspraypyrolysis
AT matheusjosedasilva thenegativephotoconductivityofagagogrownbyspraypyrolysis
AT arianodegiovannirodrigues thenegativephotoconductivityofagagogrownbyspraypyrolysis
AT demetrioawsoares thenegativephotoconductivityofagagogrownbyspraypyrolysis
AT marceloslimaperes thenegativephotoconductivityofagagogrownbyspraypyrolysis
AT marcioperonfrancodegodoy thenegativephotoconductivityofagagogrownbyspraypyrolysis
AT alinebastosdepaiva negativephotoconductivityofagagogrownbyspraypyrolysis
AT luismiguelbolanosvargas negativephotoconductivityofagagogrownbyspraypyrolysis
AT matheusjosedasilva negativephotoconductivityofagagogrownbyspraypyrolysis
AT arianodegiovannirodrigues negativephotoconductivityofagagogrownbyspraypyrolysis
AT demetrioawsoares negativephotoconductivityofagagogrownbyspraypyrolysis
AT marceloslimaperes negativephotoconductivityofagagogrownbyspraypyrolysis
AT marcioperonfrancodegodoy negativephotoconductivityofagagogrownbyspraypyrolysis