Synthesis and Characterization of Some New Metals Complexes of [N-(4-Nitrobenzoyl Amino)-Thioxomethyl] Phenylalanine
A new ligand [N-(4-nitrobenzoylamino)-thioxomethyl] phenylalanine is synthesized by reaction of 4-nitrobenzoyl isothiocyanate with phenylalanine (1:1). It is characterized by micro elemental analysis (C.H.N.S.), FT-IR, (UV-Vis) and 1H and 13CNMR spectra. Some metals ions complexes of this ligand w...
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| Format: | Article |
| Language: | Arabic |
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College of Science for Women, University of Baghdad
2016-03-01
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| Series: | Baghdad Science Journal |
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| Online Access: | http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2148 |
| _version_ | 1828762643226165248 |
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| author | Baghdad Science Journal |
| author_facet | Baghdad Science Journal |
| author_sort | Baghdad Science Journal |
| collection | DOAJ |
| description | A new ligand [N-(4-nitrobenzoylamino)-thioxomethyl] phenylalanine is synthesized by reaction of 4-nitrobenzoyl isothiocyanate with phenylalanine (1:1). It is characterized by micro elemental analysis (C.H.N.S.), FT-IR, (UV-Vis) and 1H and 13CNMR spectra. Some metals ions complexes of this ligand were prepared and characterized by FT-IR, UV-Visible spectra, conductivity measurements, magnetic susceptibility and atomic absorption. From results obtained, the following formula [M(NBA)2] where M2+ = Mn, Co, Ni, Cu, Zn, Pd, Cd and Hg, the proposed molecular structure for these complexes as tetrahedral geometry, except copper and palladium complexes are have square planer geometry. |
| first_indexed | 2024-12-11T01:47:31Z |
| format | Article |
| id | doaj.art-03739aa7374a462cbda1df1c66e48ec4 |
| institution | Directory Open Access Journal |
| issn | 2078-8665 2411-7986 |
| language | Arabic |
| last_indexed | 2024-12-11T01:47:31Z |
| publishDate | 2016-03-01 |
| publisher | College of Science for Women, University of Baghdad |
| record_format | Article |
| series | Baghdad Science Journal |
| spelling | doaj.art-03739aa7374a462cbda1df1c66e48ec42022-12-22T01:24:51ZaraCollege of Science for Women, University of BaghdadBaghdad Science Journal2078-86652411-79862016-03-0113110.21123/bsj.13.1.113-121Synthesis and Characterization of Some New Metals Complexes of [N-(4-Nitrobenzoyl Amino)-Thioxomethyl] PhenylalanineBaghdad Science JournalA new ligand [N-(4-nitrobenzoylamino)-thioxomethyl] phenylalanine is synthesized by reaction of 4-nitrobenzoyl isothiocyanate with phenylalanine (1:1). It is characterized by micro elemental analysis (C.H.N.S.), FT-IR, (UV-Vis) and 1H and 13CNMR spectra. Some metals ions complexes of this ligand were prepared and characterized by FT-IR, UV-Visible spectra, conductivity measurements, magnetic susceptibility and atomic absorption. From results obtained, the following formula [M(NBA)2] where M2+ = Mn, Co, Ni, Cu, Zn, Pd, Cd and Hg, the proposed molecular structure for these complexes as tetrahedral geometry, except copper and palladium complexes are have square planer geometry.http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2148"Phenylalanine, 4-Nitrobenzoylisothiocyanate, Metal complexes" |
| spellingShingle | Baghdad Science Journal Synthesis and Characterization of Some New Metals Complexes of [N-(4-Nitrobenzoyl Amino)-Thioxomethyl] Phenylalanine Baghdad Science Journal "Phenylalanine, 4-Nitrobenzoylisothiocyanate, Metal complexes" |
| title | Synthesis and Characterization of Some New Metals Complexes of [N-(4-Nitrobenzoyl Amino)-Thioxomethyl] Phenylalanine |
| title_full | Synthesis and Characterization of Some New Metals Complexes of [N-(4-Nitrobenzoyl Amino)-Thioxomethyl] Phenylalanine |
| title_fullStr | Synthesis and Characterization of Some New Metals Complexes of [N-(4-Nitrobenzoyl Amino)-Thioxomethyl] Phenylalanine |
| title_full_unstemmed | Synthesis and Characterization of Some New Metals Complexes of [N-(4-Nitrobenzoyl Amino)-Thioxomethyl] Phenylalanine |
| title_short | Synthesis and Characterization of Some New Metals Complexes of [N-(4-Nitrobenzoyl Amino)-Thioxomethyl] Phenylalanine |
| title_sort | synthesis and characterization of some new metals complexes of n 4 nitrobenzoyl amino thioxomethyl phenylalanine |
| topic | "Phenylalanine, 4-Nitrobenzoylisothiocyanate, Metal complexes" |
| url | http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2148 |
| work_keys_str_mv | AT baghdadsciencejournal synthesisandcharacterizationofsomenewmetalscomplexesofn4nitrobenzoylaminothioxomethylphenylalanine |