Characterization of PM2.5–bound Polycyclic Aromatic Hydrocarbons in Chiang Mai, Thailand during Biomass Open Burning Period of 2016

Polycyclic aromatic hydrocarbons (PAHs) bounded to ambient fine particles (PM2.5) were determined for enabling health risk assessment and source identification of ambient aerosols. Daily PM2.5 samples (24 h) were collected on quartz fiber filters by using a low volume air sampler (16.7 L min-1) dur...

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Main Authors: Duangduean Thepnuan, Somporn Chantara
Format: Article
Language:English
Published: Environmental Research Institute, Chulalongkorn University 2020-09-01
Series:Applied Environmental Research
Subjects:
Online Access:https://ph01.tci-thaijo.org/index.php/aer/article/view/239900
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author Duangduean Thepnuan
Somporn Chantara
author_facet Duangduean Thepnuan
Somporn Chantara
author_sort Duangduean Thepnuan
collection DOAJ
description Polycyclic aromatic hydrocarbons (PAHs) bounded to ambient fine particles (PM2.5) were determined for enabling health risk assessment and source identification of ambient aerosols. Daily PM2.5 samples (24 h) were collected on quartz fiber filters by using a low volume air sampler (16.7 L min-1) during smoke haze period (March–April 2016) in Chiang Mai, Thailand. An average concentration of PM2.5 (n=54) was 65.3±17.6 μg m-3. The samples were extracted with dichloromethane using ultrasonication prior to PAHs analysis by GC-MS. Average concentrations of 16-PAHs, non-carcinogenic (nc) PAHs and carcinogenic (c) PAHs were 10.23±2.49, 5.48±1.70 and 4.75±1.43 ng m-3, respectively. Ratio values of cPAHs/ncPAHs ranged from 0.44 to 1.98. Strong correlation (r= 0.76) between PM2.5 and cPAHs concentration was observed. Toxicity equivalent concentrations (TEQ) of PAHs was 1.13±0.34 ng m-3. The value of inhalation cancer risk (ICR) for exposure of ambient PAHs calculated from TEQ value was 1.0×10-4 indicating high risk for long term exposure. Diagnostic ratios (DRs) of various pairs of PAHs revealed that biomass burning is a major source during smoke haze period.
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spelling doaj.art-038eeffda1c94caca4cb27e1ec614f4a2024-02-14T10:49:38ZengEnvironmental Research Institute, Chulalongkorn UniversityApplied Environmental Research2287-075X2020-09-01423Characterization of PM2.5–bound Polycyclic Aromatic Hydrocarbons in Chiang Mai, Thailand during Biomass Open Burning Period of 2016Duangduean Thepnuan0Somporn Chantara1Faculty of Science and Technology, Chiang Mai Rajabhat University, Chiang Mai, ThailandFaculty of Science, Chiang Mai University, Chiang Mai, Thailand Polycyclic aromatic hydrocarbons (PAHs) bounded to ambient fine particles (PM2.5) were determined for enabling health risk assessment and source identification of ambient aerosols. Daily PM2.5 samples (24 h) were collected on quartz fiber filters by using a low volume air sampler (16.7 L min-1) during smoke haze period (March–April 2016) in Chiang Mai, Thailand. An average concentration of PM2.5 (n=54) was 65.3±17.6 μg m-3. The samples were extracted with dichloromethane using ultrasonication prior to PAHs analysis by GC-MS. Average concentrations of 16-PAHs, non-carcinogenic (nc) PAHs and carcinogenic (c) PAHs were 10.23±2.49, 5.48±1.70 and 4.75±1.43 ng m-3, respectively. Ratio values of cPAHs/ncPAHs ranged from 0.44 to 1.98. Strong correlation (r= 0.76) between PM2.5 and cPAHs concentration was observed. Toxicity equivalent concentrations (TEQ) of PAHs was 1.13±0.34 ng m-3. The value of inhalation cancer risk (ICR) for exposure of ambient PAHs calculated from TEQ value was 1.0×10-4 indicating high risk for long term exposure. Diagnostic ratios (DRs) of various pairs of PAHs revealed that biomass burning is a major source during smoke haze period. https://ph01.tci-thaijo.org/index.php/aer/article/view/239900PM2.5PAHsBiomass burningHealth risk assessmentDiagnostic ratio
spellingShingle Duangduean Thepnuan
Somporn Chantara
Characterization of PM2.5–bound Polycyclic Aromatic Hydrocarbons in Chiang Mai, Thailand during Biomass Open Burning Period of 2016
Applied Environmental Research
PM2.5
PAHs
Biomass burning
Health risk assessment
Diagnostic ratio
title Characterization of PM2.5–bound Polycyclic Aromatic Hydrocarbons in Chiang Mai, Thailand during Biomass Open Burning Period of 2016
title_full Characterization of PM2.5–bound Polycyclic Aromatic Hydrocarbons in Chiang Mai, Thailand during Biomass Open Burning Period of 2016
title_fullStr Characterization of PM2.5–bound Polycyclic Aromatic Hydrocarbons in Chiang Mai, Thailand during Biomass Open Burning Period of 2016
title_full_unstemmed Characterization of PM2.5–bound Polycyclic Aromatic Hydrocarbons in Chiang Mai, Thailand during Biomass Open Burning Period of 2016
title_short Characterization of PM2.5–bound Polycyclic Aromatic Hydrocarbons in Chiang Mai, Thailand during Biomass Open Burning Period of 2016
title_sort characterization of pm2 5 bound polycyclic aromatic hydrocarbons in chiang mai thailand during biomass open burning period of 2016
topic PM2.5
PAHs
Biomass burning
Health risk assessment
Diagnostic ratio
url https://ph01.tci-thaijo.org/index.php/aer/article/view/239900
work_keys_str_mv AT duangdueanthepnuan characterizationofpm25boundpolycyclicaromatichydrocarbonsinchiangmaithailandduringbiomassopenburningperiodof2016
AT sompornchantara characterizationofpm25boundpolycyclicaromatichydrocarbonsinchiangmaithailandduringbiomassopenburningperiodof2016