Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid Hydrogel
This article presents a study of the synthesis and characterization of new biphasic hybrid composite materials consisting of intercalated complexes (ICC) of natural mineral bentonite with copper hexaferrocyanide (phase I), which are incorporated into the bulk of the polymer matrix (phase II). It has...
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MDPI AG
2023-06-01
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author | Galymzhan Kulamkadyrovich Mamytbekov Dmitry Anatol’evich Zheltov Yernat Rashidovich Nurtazin |
author_facet | Galymzhan Kulamkadyrovich Mamytbekov Dmitry Anatol’evich Zheltov Yernat Rashidovich Nurtazin |
author_sort | Galymzhan Kulamkadyrovich Mamytbekov |
collection | DOAJ |
description | This article presents a study of the synthesis and characterization of new biphasic hybrid composite materials consisting of intercalated complexes (ICC) of natural mineral bentonite with copper hexaferrocyanide (phase I), which are incorporated into the bulk of the polymer matrix (phase II). It has been established that the sequential modification of bentonite with copper hexaferrocyanide and introduction of acrylamide and acrylic acid cross-linked copolymers into its volume by means of in situ polymerization promote the formation of a heterogeneous porous structure in the resulting hybrid material. The sorption abilities of prepared hybrid composite toward radionuclides of liquid radioactive waste (LRW) have been studied, and the mechanism for binding radionuclide metal ions with the components of the hybrid composition have been described. |
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format | Article |
id | doaj.art-039bd29a9ca9410e9de0dfee8992f6d7 |
institution | Directory Open Access Journal |
issn | 2073-4360 |
language | English |
last_indexed | 2024-03-11T02:00:34Z |
publishDate | 2023-06-01 |
publisher | MDPI AG |
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series | Polymers |
spelling | doaj.art-039bd29a9ca9410e9de0dfee8992f6d72023-11-18T12:11:48ZengMDPI AGPolymers2073-43602023-06-011512258610.3390/polym15122586Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid HydrogelGalymzhan Kulamkadyrovich Mamytbekov0Dmitry Anatol’evich Zheltov1Yernat Rashidovich Nurtazin2Institute of Nuclear Physics, Ibragimov Street 1, Almaty 050032, KazakhstanInstitute of Nuclear Physics, Ibragimov Street 1, Almaty 050032, KazakhstanInstitute of Nuclear Physics, Ibragimov Street 1, Almaty 050032, KazakhstanThis article presents a study of the synthesis and characterization of new biphasic hybrid composite materials consisting of intercalated complexes (ICC) of natural mineral bentonite with copper hexaferrocyanide (phase I), which are incorporated into the bulk of the polymer matrix (phase II). It has been established that the sequential modification of bentonite with copper hexaferrocyanide and introduction of acrylamide and acrylic acid cross-linked copolymers into its volume by means of in situ polymerization promote the formation of a heterogeneous porous structure in the resulting hybrid material. The sorption abilities of prepared hybrid composite toward radionuclides of liquid radioactive waste (LRW) have been studied, and the mechanism for binding radionuclide metal ions with the components of the hybrid composition have been described.https://www.mdpi.com/2073-4360/15/12/2586biphasic hybrid composite materialsliquid radioactive waste (LRW)polymer and mineral matrixcopper hexaferrocyanidesorption |
spellingShingle | Galymzhan Kulamkadyrovich Mamytbekov Dmitry Anatol’evich Zheltov Yernat Rashidovich Nurtazin Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid Hydrogel Polymers biphasic hybrid composite materials liquid radioactive waste (LRW) polymer and mineral matrix copper hexaferrocyanide sorption |
title | Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid Hydrogel |
title_full | Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid Hydrogel |
title_fullStr | Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid Hydrogel |
title_full_unstemmed | Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid Hydrogel |
title_short | Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid Hydrogel |
title_sort | synthesis and investigation of the properties of biphasic hybrid composites based on bentonite copper hexacyanoferrate acrylamide and acrylic acid hydrogel |
topic | biphasic hybrid composite materials liquid radioactive waste (LRW) polymer and mineral matrix copper hexaferrocyanide sorption |
url | https://www.mdpi.com/2073-4360/15/12/2586 |
work_keys_str_mv | AT galymzhankulamkadyrovichmamytbekov synthesisandinvestigationofthepropertiesofbiphasichybridcompositesbasedonbentonitecopperhexacyanoferrateacrylamideandacrylicacidhydrogel AT dmitryanatolevichzheltov synthesisandinvestigationofthepropertiesofbiphasichybridcompositesbasedonbentonitecopperhexacyanoferrateacrylamideandacrylicacidhydrogel AT yernatrashidovichnurtazin synthesisandinvestigationofthepropertiesofbiphasichybridcompositesbasedonbentonitecopperhexacyanoferrateacrylamideandacrylicacidhydrogel |