Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid Hydrogel

This article presents a study of the synthesis and characterization of new biphasic hybrid composite materials consisting of intercalated complexes (ICC) of natural mineral bentonite with copper hexaferrocyanide (phase I), which are incorporated into the bulk of the polymer matrix (phase II). It has...

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Main Authors: Galymzhan Kulamkadyrovich Mamytbekov, Dmitry Anatol’evich Zheltov, Yernat Rashidovich Nurtazin
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/15/12/2586
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author Galymzhan Kulamkadyrovich Mamytbekov
Dmitry Anatol’evich Zheltov
Yernat Rashidovich Nurtazin
author_facet Galymzhan Kulamkadyrovich Mamytbekov
Dmitry Anatol’evich Zheltov
Yernat Rashidovich Nurtazin
author_sort Galymzhan Kulamkadyrovich Mamytbekov
collection DOAJ
description This article presents a study of the synthesis and characterization of new biphasic hybrid composite materials consisting of intercalated complexes (ICC) of natural mineral bentonite with copper hexaferrocyanide (phase I), which are incorporated into the bulk of the polymer matrix (phase II). It has been established that the sequential modification of bentonite with copper hexaferrocyanide and introduction of acrylamide and acrylic acid cross-linked copolymers into its volume by means of in situ polymerization promote the formation of a heterogeneous porous structure in the resulting hybrid material. The sorption abilities of prepared hybrid composite toward radionuclides of liquid radioactive waste (LRW) have been studied, and the mechanism for binding radionuclide metal ions with the components of the hybrid composition have been described.
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spelling doaj.art-039bd29a9ca9410e9de0dfee8992f6d72023-11-18T12:11:48ZengMDPI AGPolymers2073-43602023-06-011512258610.3390/polym15122586Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid HydrogelGalymzhan Kulamkadyrovich Mamytbekov0Dmitry Anatol’evich Zheltov1Yernat Rashidovich Nurtazin2Institute of Nuclear Physics, Ibragimov Street 1, Almaty 050032, KazakhstanInstitute of Nuclear Physics, Ibragimov Street 1, Almaty 050032, KazakhstanInstitute of Nuclear Physics, Ibragimov Street 1, Almaty 050032, KazakhstanThis article presents a study of the synthesis and characterization of new biphasic hybrid composite materials consisting of intercalated complexes (ICC) of natural mineral bentonite with copper hexaferrocyanide (phase I), which are incorporated into the bulk of the polymer matrix (phase II). It has been established that the sequential modification of bentonite with copper hexaferrocyanide and introduction of acrylamide and acrylic acid cross-linked copolymers into its volume by means of in situ polymerization promote the formation of a heterogeneous porous structure in the resulting hybrid material. The sorption abilities of prepared hybrid composite toward radionuclides of liquid radioactive waste (LRW) have been studied, and the mechanism for binding radionuclide metal ions with the components of the hybrid composition have been described.https://www.mdpi.com/2073-4360/15/12/2586biphasic hybrid composite materialsliquid radioactive waste (LRW)polymer and mineral matrixcopper hexaferrocyanidesorption
spellingShingle Galymzhan Kulamkadyrovich Mamytbekov
Dmitry Anatol’evich Zheltov
Yernat Rashidovich Nurtazin
Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid Hydrogel
Polymers
biphasic hybrid composite materials
liquid radioactive waste (LRW)
polymer and mineral matrix
copper hexaferrocyanide
sorption
title Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid Hydrogel
title_full Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid Hydrogel
title_fullStr Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid Hydrogel
title_full_unstemmed Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid Hydrogel
title_short Synthesis and Investigation of the Properties of Biphasic Hybrid Composites Based on Bentonite, Copper Hexacyanoferrate, Acrylamide and Acrylic Acid Hydrogel
title_sort synthesis and investigation of the properties of biphasic hybrid composites based on bentonite copper hexacyanoferrate acrylamide and acrylic acid hydrogel
topic biphasic hybrid composite materials
liquid radioactive waste (LRW)
polymer and mineral matrix
copper hexaferrocyanide
sorption
url https://www.mdpi.com/2073-4360/15/12/2586
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AT dmitryanatolevichzheltov synthesisandinvestigationofthepropertiesofbiphasichybridcompositesbasedonbentonitecopperhexacyanoferrateacrylamideandacrylicacidhydrogel
AT yernatrashidovichnurtazin synthesisandinvestigationofthepropertiesofbiphasichybridcompositesbasedonbentonitecopperhexacyanoferrateacrylamideandacrylicacidhydrogel