Colloidal-chemistry based synthesis of quantized CuInS2/Se2 nanoparticles
Ternary chalcogenide nanoparticles, CuInS2 and CuInSe2, were synthesized in high- temperature boiling organic non-polar solvent. The X-ray diffraction analysis revealed that both materials have tetragonal (chalcopyrite) crystal structure. Morphology of the obtained materials was revealed by using...
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Format: | Article |
Language: | English |
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Serbian Chemical Society
2012-01-01
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Series: | Journal of the Serbian Chemical Society |
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Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2012/0352-51391100220A.pdf |
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author | Abazović Nadica D. Jovanović Dragana J. Stoiljković Milovan M. Mitrić Miodrag N. Ahrenkil Phillip S. Nedeljković Jovan M. Čomor Mirjana I. |
author_facet | Abazović Nadica D. Jovanović Dragana J. Stoiljković Milovan M. Mitrić Miodrag N. Ahrenkil Phillip S. Nedeljković Jovan M. Čomor Mirjana I. |
author_sort | Abazović Nadica D. |
collection | DOAJ |
description | Ternary chalcogenide nanoparticles, CuInS2 and CuInSe2, were synthesized in high- temperature boiling organic non-polar solvent. The X-ray diffraction analysis revealed that both materials have tetragonal (chalcopyrite) crystal structure. Morphology of the obtained materials was revealed by using transmission electron microscopy. Agglomerated spherical CuInS2 nanoparticles with broad size distribution in the range from 2 to 20 nm were obtained. In the case of CuInSe2, isolated particles with spherical or prismatic shape in the size range from 10 to 25 nm were obtained, as well as agglomerates consisting of much smaller particles with diameter of about 2-5 nm. The particles with the smallest diameters of both materials exhibit quantum size effect. |
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format | Article |
id | doaj.art-03ae00e549d44e719952f5edd1733bef |
institution | Directory Open Access Journal |
issn | 0352-5139 |
language | English |
last_indexed | 2024-12-18T06:51:21Z |
publishDate | 2012-01-01 |
publisher | Serbian Chemical Society |
record_format | Article |
series | Journal of the Serbian Chemical Society |
spelling | doaj.art-03ae00e549d44e719952f5edd1733bef2022-12-21T21:17:19ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392012-01-0177678979710.2298/JSC110420220AColloidal-chemistry based synthesis of quantized CuInS2/Se2 nanoparticlesAbazović Nadica D.Jovanović Dragana J.Stoiljković Milovan M.Mitrić Miodrag N.Ahrenkil Phillip S.Nedeljković Jovan M.Čomor Mirjana I.Ternary chalcogenide nanoparticles, CuInS2 and CuInSe2, were synthesized in high- temperature boiling organic non-polar solvent. The X-ray diffraction analysis revealed that both materials have tetragonal (chalcopyrite) crystal structure. Morphology of the obtained materials was revealed by using transmission electron microscopy. Agglomerated spherical CuInS2 nanoparticles with broad size distribution in the range from 2 to 20 nm were obtained. In the case of CuInSe2, isolated particles with spherical or prismatic shape in the size range from 10 to 25 nm were obtained, as well as agglomerates consisting of much smaller particles with diameter of about 2-5 nm. The particles with the smallest diameters of both materials exhibit quantum size effect.http://www.doiserbia.nb.rs/img/doi/0352-5139/2012/0352-51391100220A.pdfI-III-VI2 semiconductorsquantizationX-ray diffractionoptical properties |
spellingShingle | Abazović Nadica D. Jovanović Dragana J. Stoiljković Milovan M. Mitrić Miodrag N. Ahrenkil Phillip S. Nedeljković Jovan M. Čomor Mirjana I. Colloidal-chemistry based synthesis of quantized CuInS2/Se2 nanoparticles Journal of the Serbian Chemical Society I-III-VI2 semiconductors quantization X-ray diffraction optical properties |
title | Colloidal-chemistry based synthesis of quantized CuInS2/Se2 nanoparticles |
title_full | Colloidal-chemistry based synthesis of quantized CuInS2/Se2 nanoparticles |
title_fullStr | Colloidal-chemistry based synthesis of quantized CuInS2/Se2 nanoparticles |
title_full_unstemmed | Colloidal-chemistry based synthesis of quantized CuInS2/Se2 nanoparticles |
title_short | Colloidal-chemistry based synthesis of quantized CuInS2/Se2 nanoparticles |
title_sort | colloidal chemistry based synthesis of quantized cuins2 se2 nanoparticles |
topic | I-III-VI2 semiconductors quantization X-ray diffraction optical properties |
url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2012/0352-51391100220A.pdf |
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