Colloidal-chemistry based synthesis of quantized CuInS2/Se2 nanoparticles

Ternary chalcogenide nanoparticles, CuInS2 and CuInSe2, were synthesized in high- temperature boiling organic non-polar solvent. The X-ray diffraction analysis revealed that both materials have tetragonal (chalcopyrite) crystal structure. Morphology of the obtained materials was revealed by using...

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Main Authors: Abazović Nadica D., Jovanović Dragana J., Stoiljković Milovan M., Mitrić Miodrag N., Ahrenkil Phillip S., Nedeljković Jovan M., Čomor Mirjana I.
Format: Article
Language:English
Published: Serbian Chemical Society 2012-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2012/0352-51391100220A.pdf
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author Abazović Nadica D.
Jovanović Dragana J.
Stoiljković Milovan M.
Mitrić Miodrag N.
Ahrenkil Phillip S.
Nedeljković Jovan M.
Čomor Mirjana I.
author_facet Abazović Nadica D.
Jovanović Dragana J.
Stoiljković Milovan M.
Mitrić Miodrag N.
Ahrenkil Phillip S.
Nedeljković Jovan M.
Čomor Mirjana I.
author_sort Abazović Nadica D.
collection DOAJ
description Ternary chalcogenide nanoparticles, CuInS2 and CuInSe2, were synthesized in high- temperature boiling organic non-polar solvent. The X-ray diffraction analysis revealed that both materials have tetragonal (chalcopyrite) crystal structure. Morphology of the obtained materials was revealed by using transmission electron microscopy. Agglomerated spherical CuInS2 nanoparticles with broad size distribution in the range from 2 to 20 nm were obtained. In the case of CuInSe2, isolated particles with spherical or prismatic shape in the size range from 10 to 25 nm were obtained, as well as agglomerates consisting of much smaller particles with diameter of about 2-5 nm. The particles with the smallest diameters of both materials exhibit quantum size effect.
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spelling doaj.art-03ae00e549d44e719952f5edd1733bef2022-12-21T21:17:19ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392012-01-0177678979710.2298/JSC110420220AColloidal-chemistry based synthesis of quantized CuInS2/Se2 nanoparticlesAbazović Nadica D.Jovanović Dragana J.Stoiljković Milovan M.Mitrić Miodrag N.Ahrenkil Phillip S.Nedeljković Jovan M.Čomor Mirjana I.Ternary chalcogenide nanoparticles, CuInS2 and CuInSe2, were synthesized in high- temperature boiling organic non-polar solvent. The X-ray diffraction analysis revealed that both materials have tetragonal (chalcopyrite) crystal structure. Morphology of the obtained materials was revealed by using transmission electron microscopy. Agglomerated spherical CuInS2 nanoparticles with broad size distribution in the range from 2 to 20 nm were obtained. In the case of CuInSe2, isolated particles with spherical or prismatic shape in the size range from 10 to 25 nm were obtained, as well as agglomerates consisting of much smaller particles with diameter of about 2-5 nm. The particles with the smallest diameters of both materials exhibit quantum size effect.http://www.doiserbia.nb.rs/img/doi/0352-5139/2012/0352-51391100220A.pdfI-III-VI2 semiconductorsquantizationX-ray diffractionoptical properties
spellingShingle Abazović Nadica D.
Jovanović Dragana J.
Stoiljković Milovan M.
Mitrić Miodrag N.
Ahrenkil Phillip S.
Nedeljković Jovan M.
Čomor Mirjana I.
Colloidal-chemistry based synthesis of quantized CuInS2/Se2 nanoparticles
Journal of the Serbian Chemical Society
I-III-VI2 semiconductors
quantization
X-ray diffraction
optical properties
title Colloidal-chemistry based synthesis of quantized CuInS2/Se2 nanoparticles
title_full Colloidal-chemistry based synthesis of quantized CuInS2/Se2 nanoparticles
title_fullStr Colloidal-chemistry based synthesis of quantized CuInS2/Se2 nanoparticles
title_full_unstemmed Colloidal-chemistry based synthesis of quantized CuInS2/Se2 nanoparticles
title_short Colloidal-chemistry based synthesis of quantized CuInS2/Se2 nanoparticles
title_sort colloidal chemistry based synthesis of quantized cuins2 se2 nanoparticles
topic I-III-VI2 semiconductors
quantization
X-ray diffraction
optical properties
url http://www.doiserbia.nb.rs/img/doi/0352-5139/2012/0352-51391100220A.pdf
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