trans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II)
The title dichlorocobalt(II) complex, trans-[CoCl2(1)2] [1 = 8-(benzylsulfanyl)quinoline, C16H13NS], has a central CoII atom (site symmetry \overline1) that exhibits a distorted octahedral coordination geometry and is coordinated by two N and two S atoms from the bidentate N,S-ligand (1) situated in...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2021-10-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314621009925 |
| _version_ | 1818826778657947648 |
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| author | Shintaro Kodama Kazuki Bunno Akihiro Nomoto Akiya Ogawa |
| author_facet | Shintaro Kodama Kazuki Bunno Akihiro Nomoto Akiya Ogawa |
| author_sort | Shintaro Kodama |
| collection | DOAJ |
| description | The title dichlorocobalt(II) complex, trans-[CoCl2(1)2] [1 = 8-(benzylsulfanyl)quinoline, C16H13NS], has a central CoII atom (site symmetry \overline1) that exhibits a distorted octahedral coordination geometry and is coordinated by two N and two S atoms from the bidentate N,S-ligand (1) situated in an equatorial plane and two Cl atoms in the axial positions. Complexes are linked by weak intermolecular C—H...π interactions between the 8-(benzylsulfanyl)quinoline ligands, forming a chain extending along the a-axis direction. |
| first_indexed | 2024-12-19T00:33:04Z |
| format | Article |
| id | doaj.art-03b4b88c6cd14aa9b822ccda0670d853 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-19T00:33:04Z |
| publishDate | 2021-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-03b4b88c6cd14aa9b822ccda0670d8532022-12-21T20:45:00ZengInternational Union of CrystallographyIUCrData2414-31462021-10-01610x21099210.1107/S2414314621009925zl4046trans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II)Shintaro Kodama0Kazuki Bunno1Akihiro Nomoto2Akiya Ogawa3Department of Applied Chemistry, Graduate School of Engineering, Osaka, Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, JapanDepartment of Applied Chemistry, Graduate School of Engineering, Osaka, Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, JapanDepartment of Applied Chemistry, Graduate School of Engineering, Osaka, Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, JapanDepartment of Applied Chemistry, Graduate School of Engineering, Osaka, Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, JapanThe title dichlorocobalt(II) complex, trans-[CoCl2(1)2] [1 = 8-(benzylsulfanyl)quinoline, C16H13NS], has a central CoII atom (site symmetry \overline1) that exhibits a distorted octahedral coordination geometry and is coordinated by two N and two S atoms from the bidentate N,S-ligand (1) situated in an equatorial plane and two Cl atoms in the axial positions. Complexes are linked by weak intermolecular C—H...π interactions between the 8-(benzylsulfanyl)quinoline ligands, forming a chain extending along the a-axis direction.http://scripts.iucr.org/cgi-bin/paper?S2414314621009925crystal structurecobalt(ii) complexbidentate n,s-ligand |
| spellingShingle | Shintaro Kodama Kazuki Bunno Akihiro Nomoto Akiya Ogawa trans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II) IUCrData crystal structure cobalt(ii) complex bidentate n,s-ligand |
| title | trans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II) |
| title_full | trans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II) |
| title_fullStr | trans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II) |
| title_full_unstemmed | trans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II) |
| title_short | trans-Bis[8-(benzylsulfanyl)quinoline-κ2N,S]dichloridocobalt(II) |
| title_sort | trans bis 8 benzylsulfanyl quinoline κ2n s dichloridocobalt ii |
| topic | crystal structure cobalt(ii) complex bidentate n,s-ligand |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314621009925 |
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