trans-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate)
The bidentate 1,3,4-thiadiazole ligand substituted by two 2-pyridyl rings (denoted L) has been found to produce the new monomeric title complex, [Co(C12H8N4S)2(H2O)2](BF4)2. The thiadiazole and pyridyl rings surrounding the Co atom are almost coplanar [dihedral angle = 4.35 (7)&...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811020125 |
| _version_ | 1818958765092765696 |
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| author | Fouad Bentiss Frédéric Capet Michel Lagrenée Mohamed Saadi Lahcen El Ammari |
| author_facet | Fouad Bentiss Frédéric Capet Michel Lagrenée Mohamed Saadi Lahcen El Ammari |
| author_sort | Fouad Bentiss |
| collection | DOAJ |
| description | The bidentate 1,3,4-thiadiazole ligand substituted by two 2-pyridyl rings (denoted L) has been found to produce the new monomeric title complex, [Co(C12H8N4S)2(H2O)2](BF4)2. The thiadiazole and pyridyl rings surrounding the Co atom are almost coplanar [dihedral angle = 4.35 (7)°]. The mean plane defined by these heterocyclic moieties makes a dihedral angle of 18.72 (6)° with the non-coordinated pyridyl ring. The Co2+ cation, located at a crystallographic center of symmetry, is bonded to two ligands and two water molecules in a trans configuration in an octahedral environment. The tetrafluoridoborate ions can be regarded as free anions in the crystal lattice. Nevertheless, they are involved in an infinite two-dimensional network along the [010] and [101] directions of O—H...F hydrogen bonds. |
| first_indexed | 2024-12-20T11:30:56Z |
| format | Article |
| id | doaj.art-03c977f3b7004155b5beef75334e0588 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:30:56Z |
| publishDate | 2011-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-03c977f3b7004155b5beef75334e05882022-12-21T19:42:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m834m83510.1107/S1600536811020125trans-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate)Fouad BentissFrédéric CapetMichel LagrenéeMohamed SaadiLahcen El AmmariThe bidentate 1,3,4-thiadiazole ligand substituted by two 2-pyridyl rings (denoted L) has been found to produce the new monomeric title complex, [Co(C12H8N4S)2(H2O)2](BF4)2. The thiadiazole and pyridyl rings surrounding the Co atom are almost coplanar [dihedral angle = 4.35 (7)°]. The mean plane defined by these heterocyclic moieties makes a dihedral angle of 18.72 (6)° with the non-coordinated pyridyl ring. The Co2+ cation, located at a crystallographic center of symmetry, is bonded to two ligands and two water molecules in a trans configuration in an octahedral environment. The tetrafluoridoborate ions can be regarded as free anions in the crystal lattice. Nevertheless, they are involved in an infinite two-dimensional network along the [010] and [101] directions of O—H...F hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811020125 |
| spellingShingle | Fouad Bentiss Frédéric Capet Michel Lagrenée Mohamed Saadi Lahcen El Ammari trans-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate) Acta Crystallographica Section E |
| title | trans-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate) |
| title_full | trans-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate) |
| title_fullStr | trans-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate) |
| title_full_unstemmed | trans-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate) |
| title_short | trans-Diaquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole]cobalt(II) bis(tetrafluoridoborate) |
| title_sort | trans diaquabis 2 5 bis pyridin 2 yl 1 3 4 thiadiazole cobalt ii bis tetrafluoridoborate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811020125 |
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