Insight into the efficiency‐stability‐cost balanced organic solar cell based on a polymerized nonfused‐ring electron acceptor
Abstract Organic solar cells (OSCs) have attracted extensive attention from both academia and industry in recent years due to their remarkable improvement in power conversion efficiency (PCE). However, the Golden Triangle (the balance of efficiency‐stability‐cost) required for large‐scale industrial...
| Main Authors: | , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2023-12-01
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| Series: | Aggregate |
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| Online Access: | https://doi.org/10.1002/agt2.388 |
| _version_ | 1797386750636589056 |
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| author | Xiaobin Gu Yanan Wei Guanyu Lu Ziyang Han Di Zheng Guanghao Lu Jianqi Zhang Zhixiang Wei Yunhao Cai Xin Zhang Hui Huang |
| author_facet | Xiaobin Gu Yanan Wei Guanyu Lu Ziyang Han Di Zheng Guanghao Lu Jianqi Zhang Zhixiang Wei Yunhao Cai Xin Zhang Hui Huang |
| author_sort | Xiaobin Gu |
| collection | DOAJ |
| description | Abstract Organic solar cells (OSCs) have attracted extensive attention from both academia and industry in recent years due to their remarkable improvement in power conversion efficiency (PCE). However, the Golden Triangle (the balance of efficiency‐stability‐cost) required for large‐scale industrialization of OSCs still remains a great challenge. Here, a new nonfused‐ring electron acceptor (NFREA) BF and its polymerized counterpart PBF were designed and synthesized, and their photovoltaic performance, storage stability and material cost were systematically investigated. When blended with a widely‐used polymer donor PBDB‐T, the PBF‐based all‐polymer solar cell (all‐PSC) displayed a record high PCE of 12.61% for polymerized NFREAs (PNFREAs) with an excellent stability (95.2% of initial PCE after 800 h storage), superior to the BF counterpart. Impressively, PBF‐based all‐PSC possesses the highest industrial figure‐of‐merit (i‐FOM) value of 0.309 based on an efficiency‐stability‐cost evaluation, in comparison to several representative OSC systems (such as PM6:Y6 and PBDB‐T:PZ1). This work provides an insight into the balance of efficiency, stability, and cost, and also indicates that the PNFREAs are promising materials toward the commercial application of OSCs. |
| first_indexed | 2024-03-08T22:13:53Z |
| format | Article |
| id | doaj.art-03d6a7fd07ea4876b7dc366a12289f51 |
| institution | Directory Open Access Journal |
| issn | 2692-4560 |
| language | English |
| last_indexed | 2024-03-08T22:13:53Z |
| publishDate | 2023-12-01 |
| publisher | Wiley |
| record_format | Article |
| series | Aggregate |
| spelling | doaj.art-03d6a7fd07ea4876b7dc366a12289f512023-12-19T04:23:02ZengWileyAggregate2692-45602023-12-0146n/an/a10.1002/agt2.388Insight into the efficiency‐stability‐cost balanced organic solar cell based on a polymerized nonfused‐ring electron acceptorXiaobin Gu0Yanan Wei1Guanyu Lu2Ziyang Han3Di Zheng4Guanghao Lu5Jianqi Zhang6Zhixiang Wei7Yunhao Cai8Xin Zhang9Hui Huang10College of Materials Science and Opto‐Electronic Technology Center of Materials Science and Optoelectronics Engineering CAS Center for Excellence in Topological Quantum Computation, CAS Key Laboratory of Vacuum Physics, University of Chinese Academy of Sciences BeijingChinaCollege of Materials Science and Opto‐Electronic Technology Center of Materials Science and Optoelectronics Engineering CAS Center for Excellence in Topological Quantum Computation, CAS Key Laboratory of Vacuum Physics, University of Chinese Academy of Sciences BeijingChinaFrontier Institute of Science and Technology Xi'an Jiaotong University Xi'anChinaCollege of Materials Science and Opto‐Electronic Technology Center of Materials Science and Optoelectronics Engineering CAS Center for Excellence in Topological Quantum Computation, CAS Key Laboratory of Vacuum Physics, University of Chinese Academy of Sciences BeijingChinaCollege of Materials Science and Opto‐Electronic Technology Center of Materials Science and Optoelectronics Engineering CAS Center for Excellence in Topological Quantum Computation, CAS Key Laboratory of Vacuum Physics, University of Chinese Academy of Sciences BeijingChinaFrontier Institute of Science and Technology Xi'an Jiaotong University Xi'anChinaCAS Key Laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in Nanoscience National Center for Nanoscience and Technology BeijingChinaCAS Key Laboratory of Nanosystem and Hierarchical Fabrication CAS Center for Excellence in Nanoscience National Center for Nanoscience and Technology BeijingChinaCollege of Materials Science and Opto‐Electronic Technology Center of Materials Science and Optoelectronics Engineering CAS Center for Excellence in Topological Quantum Computation, CAS Key Laboratory of Vacuum Physics, University of Chinese Academy of Sciences BeijingChinaCollege of Materials Science and Opto‐Electronic Technology Center of Materials Science and Optoelectronics Engineering CAS Center for Excellence in Topological Quantum Computation, CAS Key Laboratory of Vacuum Physics, University of Chinese Academy of Sciences BeijingChinaCollege of Materials Science and Opto‐Electronic Technology Center of Materials Science and Optoelectronics Engineering CAS Center for Excellence in Topological Quantum Computation, CAS Key Laboratory of Vacuum Physics, University of Chinese Academy of Sciences BeijingChinaAbstract Organic solar cells (OSCs) have attracted extensive attention from both academia and industry in recent years due to their remarkable improvement in power conversion efficiency (PCE). However, the Golden Triangle (the balance of efficiency‐stability‐cost) required for large‐scale industrialization of OSCs still remains a great challenge. Here, a new nonfused‐ring electron acceptor (NFREA) BF and its polymerized counterpart PBF were designed and synthesized, and their photovoltaic performance, storage stability and material cost were systematically investigated. When blended with a widely‐used polymer donor PBDB‐T, the PBF‐based all‐polymer solar cell (all‐PSC) displayed a record high PCE of 12.61% for polymerized NFREAs (PNFREAs) with an excellent stability (95.2% of initial PCE after 800 h storage), superior to the BF counterpart. Impressively, PBF‐based all‐PSC possesses the highest industrial figure‐of‐merit (i‐FOM) value of 0.309 based on an efficiency‐stability‐cost evaluation, in comparison to several representative OSC systems (such as PM6:Y6 and PBDB‐T:PZ1). This work provides an insight into the balance of efficiency, stability, and cost, and also indicates that the PNFREAs are promising materials toward the commercial application of OSCs.https://doi.org/10.1002/agt2.388all‐polymer solar cellsefficiency‐stability‐cost balancenoncovalently conformational locksorganic solar cellpolymerized nonfused‐ring electron acceptors |
| spellingShingle | Xiaobin Gu Yanan Wei Guanyu Lu Ziyang Han Di Zheng Guanghao Lu Jianqi Zhang Zhixiang Wei Yunhao Cai Xin Zhang Hui Huang Insight into the efficiency‐stability‐cost balanced organic solar cell based on a polymerized nonfused‐ring electron acceptor Aggregate all‐polymer solar cells efficiency‐stability‐cost balance noncovalently conformational locks organic solar cell polymerized nonfused‐ring electron acceptors |
| title | Insight into the efficiency‐stability‐cost balanced organic solar cell based on a polymerized nonfused‐ring electron acceptor |
| title_full | Insight into the efficiency‐stability‐cost balanced organic solar cell based on a polymerized nonfused‐ring electron acceptor |
| title_fullStr | Insight into the efficiency‐stability‐cost balanced organic solar cell based on a polymerized nonfused‐ring electron acceptor |
| title_full_unstemmed | Insight into the efficiency‐stability‐cost balanced organic solar cell based on a polymerized nonfused‐ring electron acceptor |
| title_short | Insight into the efficiency‐stability‐cost balanced organic solar cell based on a polymerized nonfused‐ring electron acceptor |
| title_sort | insight into the efficiency stability cost balanced organic solar cell based on a polymerized nonfused ring electron acceptor |
| topic | all‐polymer solar cells efficiency‐stability‐cost balance noncovalently conformational locks organic solar cell polymerized nonfused‐ring electron acceptors |
| url | https://doi.org/10.1002/agt2.388 |
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