Poly[octa-μ-aqua-tetraaquabis(μ-5-sulfonatobenzene-1,3-dicarboxylato)cobalt(II)tetrasodium]
The title compound, [CoNa4(C8H3O7S)2(H2O)12]n, is a three-dimensional coordination polymer bridged by sulfoisophthalate trianions and water molecules. The CoII atom, located on an inversion centre, is coordinated by two carboxylate groups of the sulfoisophthalate trianions and by four water molecule...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809008174 |
| _version_ | 1818492354296807424 |
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| author | Bing-Yu Zhang Jing-Jing Nie Duan-Jun Xu |
| author_facet | Bing-Yu Zhang Jing-Jing Nie Duan-Jun Xu |
| author_sort | Bing-Yu Zhang |
| collection | DOAJ |
| description | The title compound, [CoNa4(C8H3O7S)2(H2O)12]n, is a three-dimensional coordination polymer bridged by sulfoisophthalate trianions and water molecules. The CoII atom, located on an inversion centre, is coordinated by two carboxylate groups of the sulfoisophthalate trianions and by four water molecules in a distorted CoO6 octahedral geometry. Two independent NaI atoms also have a distorted octahedral coordination geometry formed by water, carboxylate O and sulfonate O atoms. An extensive O—H...O and C—H...O hydrogen-bonding network is present in the crystal structure, as well as weak π-π stacking [centroid–centroid distance = 3.9553 (11) Å]. |
| first_indexed | 2024-12-10T17:41:56Z |
| format | Article |
| id | doaj.art-03f03eb82f3e45389d42ace32242dbed |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T17:41:56Z |
| publishDate | 2009-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-03f03eb82f3e45389d42ace32242dbed2022-12-22T01:39:21ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-04-01654m387m38810.1107/S1600536809008174Poly[octa-μ-aqua-tetraaquabis(μ-5-sulfonatobenzene-1,3-dicarboxylato)cobalt(II)tetrasodium]Bing-Yu ZhangJing-Jing NieDuan-Jun XuThe title compound, [CoNa4(C8H3O7S)2(H2O)12]n, is a three-dimensional coordination polymer bridged by sulfoisophthalate trianions and water molecules. The CoII atom, located on an inversion centre, is coordinated by two carboxylate groups of the sulfoisophthalate trianions and by four water molecules in a distorted CoO6 octahedral geometry. Two independent NaI atoms also have a distorted octahedral coordination geometry formed by water, carboxylate O and sulfonate O atoms. An extensive O—H...O and C—H...O hydrogen-bonding network is present in the crystal structure, as well as weak π-π stacking [centroid–centroid distance = 3.9553 (11) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536809008174 |
| spellingShingle | Bing-Yu Zhang Jing-Jing Nie Duan-Jun Xu Poly[octa-μ-aqua-tetraaquabis(μ-5-sulfonatobenzene-1,3-dicarboxylato)cobalt(II)tetrasodium] Acta Crystallographica Section E |
| title | Poly[octa-μ-aqua-tetraaquabis(μ-5-sulfonatobenzene-1,3-dicarboxylato)cobalt(II)tetrasodium] |
| title_full | Poly[octa-μ-aqua-tetraaquabis(μ-5-sulfonatobenzene-1,3-dicarboxylato)cobalt(II)tetrasodium] |
| title_fullStr | Poly[octa-μ-aqua-tetraaquabis(μ-5-sulfonatobenzene-1,3-dicarboxylato)cobalt(II)tetrasodium] |
| title_full_unstemmed | Poly[octa-μ-aqua-tetraaquabis(μ-5-sulfonatobenzene-1,3-dicarboxylato)cobalt(II)tetrasodium] |
| title_short | Poly[octa-μ-aqua-tetraaquabis(μ-5-sulfonatobenzene-1,3-dicarboxylato)cobalt(II)tetrasodium] |
| title_sort | poly octa amp 956 aqua tetraaquabis amp 956 5 sulfonatobenzene 1 3 dicarboxylato cobalt ii tetrasodium |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809008174 |
| work_keys_str_mv | AT bingyuzhang polyoctaamp956aquatetraaquabisamp9565sulfonatobenzene13dicarboxylatocobaltiitetrasodium AT jingjingnie polyoctaamp956aquatetraaquabisamp9565sulfonatobenzene13dicarboxylatocobaltiitetrasodium AT duanjunxu polyoctaamp956aquatetraaquabisamp9565sulfonatobenzene13dicarboxylatocobaltiitetrasodium |