Effect of thickness and temperature on flexible organic P3HT:PCBM solar cell performance

A blend of poly 3-hexylthiophene (P3HT) and [6, 6]-phenyl-C _61 -butyric acid methyl ester (PCBM) is used as a photoactive layer for simulating a bulk heterojunction organic solar using general-purpose photovoltaic device model (GPVDM) software. The optical and electrical performance of the cell had...

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Main Authors: Mahmoud N Zidan, Tawfik Ismail, Irene S Fahim
Format: Article
Language:English
Published: IOP Publishing 2021-01-01
Series:Materials Research Express
Subjects:
Online Access:https://doi.org/10.1088/2053-1591/ac2773
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author Mahmoud N Zidan
Tawfik Ismail
Irene S Fahim
author_facet Mahmoud N Zidan
Tawfik Ismail
Irene S Fahim
author_sort Mahmoud N Zidan
collection DOAJ
description A blend of poly 3-hexylthiophene (P3HT) and [6, 6]-phenyl-C _61 -butyric acid methyl ester (PCBM) is used as a photoactive layer for simulating a bulk heterojunction organic solar using general-purpose photovoltaic device model (GPVDM) software. The optical and electrical performance of the cell had been analyzed by changing the thickness of each layer and substrate material over a range of operating temperatures from −10 °C to – 40 °C. The flexible device exhibits higher PCE compared to a rigid device. The performance of the device was studied using transient simulation at different operating temperatures showing degradation in overall performance while enhancing the de-trapping of charge carrier and the recombination rate. Despite the increase in the number of absorbed photons while increasing the active layer thickness to 300 nm, a successful conversion of photon energy to electrical energy is not possible at higher thickness. The electrical simulation showed that a maximum power conversion efficiency (PCE) can be achieved with 220 nm thick active layer while decreasing the thickness of ITO and PEDOT: PSS layers due to minimization of optical losses.
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spelling doaj.art-03f0f4a070a54c0fa33123f3eec426a92023-08-09T15:55:53ZengIOP PublishingMaterials Research Express2053-15912021-01-018909550810.1088/2053-1591/ac2773Effect of thickness and temperature on flexible organic P3HT:PCBM solar cell performanceMahmoud N Zidan0https://orcid.org/0000-0002-2524-2706Tawfik Ismail1Irene S Fahim2Industrial Engineering, Smart Engineering Systems Research Center (SESC), Nile University , Giza 12677, EgyptIntelligent Networks Center (WINC), Nile University , Giza 12677, Egypt; National Institute of Laser Enhanced Sciences, Cairo University , Giza 12613, EgyptIndustrial Engineering, Smart Engineering Systems Research Center (SESC), Nile University , Giza 12677, EgyptA blend of poly 3-hexylthiophene (P3HT) and [6, 6]-phenyl-C _61 -butyric acid methyl ester (PCBM) is used as a photoactive layer for simulating a bulk heterojunction organic solar using general-purpose photovoltaic device model (GPVDM) software. The optical and electrical performance of the cell had been analyzed by changing the thickness of each layer and substrate material over a range of operating temperatures from −10 °C to – 40 °C. The flexible device exhibits higher PCE compared to a rigid device. The performance of the device was studied using transient simulation at different operating temperatures showing degradation in overall performance while enhancing the de-trapping of charge carrier and the recombination rate. Despite the increase in the number of absorbed photons while increasing the active layer thickness to 300 nm, a successful conversion of photon energy to electrical energy is not possible at higher thickness. The electrical simulation showed that a maximum power conversion efficiency (PCE) can be achieved with 220 nm thick active layer while decreasing the thickness of ITO and PEDOT: PSS layers due to minimization of optical losses.https://doi.org/10.1088/2053-1591/ac2773organic solar cellsbulk-heterojunctionP3HT: PCBMPEDOT: PSSGPVDMflexible photovoltaics
spellingShingle Mahmoud N Zidan
Tawfik Ismail
Irene S Fahim
Effect of thickness and temperature on flexible organic P3HT:PCBM solar cell performance
Materials Research Express
organic solar cells
bulk-heterojunction
P3HT: PCBM
PEDOT: PSS
GPVDM
flexible photovoltaics
title Effect of thickness and temperature on flexible organic P3HT:PCBM solar cell performance
title_full Effect of thickness and temperature on flexible organic P3HT:PCBM solar cell performance
title_fullStr Effect of thickness and temperature on flexible organic P3HT:PCBM solar cell performance
title_full_unstemmed Effect of thickness and temperature on flexible organic P3HT:PCBM solar cell performance
title_short Effect of thickness and temperature on flexible organic P3HT:PCBM solar cell performance
title_sort effect of thickness and temperature on flexible organic p3ht pcbm solar cell performance
topic organic solar cells
bulk-heterojunction
P3HT: PCBM
PEDOT: PSS
GPVDM
flexible photovoltaics
url https://doi.org/10.1088/2053-1591/ac2773
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