Fusion of Ni Plating on CP-Titanium by Electron Beam Single-Track Scanning: Toward a New Approach for Fabricating TiNi Self-Healing Shape Memory Coating

The limited wear resistance of commercially pure titanium (CP-Ti) hinders its use in abrasive and erosive environments, despite its good strength–weight ratio and corrosion resistance. This paper reports the first study proposing a novel method for wear-resistant TiNi coating through Ni plating and...

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Main Authors: Lei Wang, Masayuki Okugawa, Hirokazu Konishi, Yuheng Liu, Yuichiro Koizumi, Takayoshi Nakano
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/15/5449
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author Lei Wang
Masayuki Okugawa
Hirokazu Konishi
Yuheng Liu
Yuichiro Koizumi
Takayoshi Nakano
author_facet Lei Wang
Masayuki Okugawa
Hirokazu Konishi
Yuheng Liu
Yuichiro Koizumi
Takayoshi Nakano
author_sort Lei Wang
collection DOAJ
description The limited wear resistance of commercially pure titanium (CP-Ti) hinders its use in abrasive and erosive environments, despite its good strength–weight ratio and corrosion resistance. This paper reports the first study proposing a novel method for wear-resistant TiNi coating through Ni plating and electron beam (EB) irradiation in an in situ synthetic approach. Single-track melting experiments were conducted using the EB to investigate the feasibility of forming a TiNi phase by fusing the Ni plate with the CP-Ti substrate. Varying beam powers were employed at a fixed scanning speed to determine the optimal conditions for TiNi phase formation. The concentration of the melt region was found to be approximate as estimated from the ratio of the Ni-plate thickness to the depth of the melt region, and the region with Ni-48.7 at.% Ti was successfully formed by EB irradiation. The study suggests that the mixing of Ti atoms and Ni atoms was facilitated by fluid flow induced by Marangoni and thermal convections. It is proposed that a more uniform TiNi layer can be achieved through multi-track melting under appropriate conditions. This research demonstrates the feasibility of utilizing EB additive manufacturing as a coating method and the potential for developing TiNi coatings with shape memory effects and pseudoelasticity.
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spelling doaj.art-03fba79e0b504b5f83ee81773907f48f2023-11-18T23:13:27ZengMDPI AGMaterials1996-19442023-08-011615544910.3390/ma16155449Fusion of Ni Plating on CP-Titanium by Electron Beam Single-Track Scanning: Toward a New Approach for Fabricating TiNi Self-Healing Shape Memory CoatingLei Wang0Masayuki Okugawa1Hirokazu Konishi2Yuheng Liu3Yuichiro Koizumi4Takayoshi Nakano5Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita 565-0871, JapanGraduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita 565-0871, JapanGraduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita 565-0871, JapanGraduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita 565-0871, JapanGraduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita 565-0871, JapanGraduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita 565-0871, JapanThe limited wear resistance of commercially pure titanium (CP-Ti) hinders its use in abrasive and erosive environments, despite its good strength–weight ratio and corrosion resistance. This paper reports the first study proposing a novel method for wear-resistant TiNi coating through Ni plating and electron beam (EB) irradiation in an in situ synthetic approach. Single-track melting experiments were conducted using the EB to investigate the feasibility of forming a TiNi phase by fusing the Ni plate with the CP-Ti substrate. Varying beam powers were employed at a fixed scanning speed to determine the optimal conditions for TiNi phase formation. The concentration of the melt region was found to be approximate as estimated from the ratio of the Ni-plate thickness to the depth of the melt region, and the region with Ni-48.7 at.% Ti was successfully formed by EB irradiation. The study suggests that the mixing of Ti atoms and Ni atoms was facilitated by fluid flow induced by Marangoni and thermal convections. It is proposed that a more uniform TiNi layer can be achieved through multi-track melting under appropriate conditions. This research demonstrates the feasibility of utilizing EB additive manufacturing as a coating method and the potential for developing TiNi coatings with shape memory effects and pseudoelasticity.https://www.mdpi.com/1996-1944/16/15/5449commercially pure TiTiNi coatingshape memory alloypseudoelasticitywear resistanceelectron beam melting
spellingShingle Lei Wang
Masayuki Okugawa
Hirokazu Konishi
Yuheng Liu
Yuichiro Koizumi
Takayoshi Nakano
Fusion of Ni Plating on CP-Titanium by Electron Beam Single-Track Scanning: Toward a New Approach for Fabricating TiNi Self-Healing Shape Memory Coating
Materials
commercially pure Ti
TiNi coating
shape memory alloy
pseudoelasticity
wear resistance
electron beam melting
title Fusion of Ni Plating on CP-Titanium by Electron Beam Single-Track Scanning: Toward a New Approach for Fabricating TiNi Self-Healing Shape Memory Coating
title_full Fusion of Ni Plating on CP-Titanium by Electron Beam Single-Track Scanning: Toward a New Approach for Fabricating TiNi Self-Healing Shape Memory Coating
title_fullStr Fusion of Ni Plating on CP-Titanium by Electron Beam Single-Track Scanning: Toward a New Approach for Fabricating TiNi Self-Healing Shape Memory Coating
title_full_unstemmed Fusion of Ni Plating on CP-Titanium by Electron Beam Single-Track Scanning: Toward a New Approach for Fabricating TiNi Self-Healing Shape Memory Coating
title_short Fusion of Ni Plating on CP-Titanium by Electron Beam Single-Track Scanning: Toward a New Approach for Fabricating TiNi Self-Healing Shape Memory Coating
title_sort fusion of ni plating on cp titanium by electron beam single track scanning toward a new approach for fabricating tini self healing shape memory coating
topic commercially pure Ti
TiNi coating
shape memory alloy
pseudoelasticity
wear resistance
electron beam melting
url https://www.mdpi.com/1996-1944/16/15/5449
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