Whitish haze, soapy globules: micro-analysis of degraded burmese paintings on zinc supports

Abstract Two Burmese oil paintings on zinc supports depicting portraits of royal families, dated to the early 20th century by Saya Aye and Saya Mya, showed interesting corrosion, efflorescence and soapy globules for analytical investigation prior to conservation for exhibition. The features and colo...

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Main Author: Lynn Chua
Format: Article
Language:English
Published: SpringerOpen 2019-07-01
Series:Heritage Science
Subjects:
Online Access:http://link.springer.com/article/10.1186/s40494-019-0287-5
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author Lynn Chua
author_facet Lynn Chua
author_sort Lynn Chua
collection DOAJ
description Abstract Two Burmese oil paintings on zinc supports depicting portraits of royal families, dated to the early 20th century by Saya Aye and Saya Mya, showed interesting corrosion, efflorescence and soapy globules for analytical investigation prior to conservation for exhibition. The features and colours on the two paintings, one of which was in worse condition than the other, were obscured by a whitish haze. Paint rupture and losses due to corrosion of the zinc support were apparent. Using a combination of 3D digital microscopy, FTIR microscopy and SEM–EDS, the degradation, as well as the paint materials and artists’ techniques were analysed and discussed. Zinc soaps, oxalates, silicates, hydroxychlorides, carbonates, wax and mould characterized the haze. Interestingly, brown outlines in Aye’s painting appeared unusually dark. Upon analysis, this degradation phenomenon was attributed to micro-sized greenish soap globules that have developed around copper/zinc (brass) particles, causing the brown outlines to lose their intended luminosity. The other painting by Mya, in which the same brown outline was applied, did not show such formation of globules. Detection of oxalates in the corrosion of zinc support and brown outlines are discussed. This study shows the importance in understanding the artists’ materials and techniques, which have consequential effects to the degradation observed.
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spelling doaj.art-04045dee64c8447aacca8463e3315c0b2022-12-22T01:58:22ZengSpringerOpenHeritage Science2050-74452019-07-017111210.1186/s40494-019-0287-5Whitish haze, soapy globules: micro-analysis of degraded burmese paintings on zinc supportsLynn Chua0Heritage Conservation Centre (National Heritage Board)Abstract Two Burmese oil paintings on zinc supports depicting portraits of royal families, dated to the early 20th century by Saya Aye and Saya Mya, showed interesting corrosion, efflorescence and soapy globules for analytical investigation prior to conservation for exhibition. The features and colours on the two paintings, one of which was in worse condition than the other, were obscured by a whitish haze. Paint rupture and losses due to corrosion of the zinc support were apparent. Using a combination of 3D digital microscopy, FTIR microscopy and SEM–EDS, the degradation, as well as the paint materials and artists’ techniques were analysed and discussed. Zinc soaps, oxalates, silicates, hydroxychlorides, carbonates, wax and mould characterized the haze. Interestingly, brown outlines in Aye’s painting appeared unusually dark. Upon analysis, this degradation phenomenon was attributed to micro-sized greenish soap globules that have developed around copper/zinc (brass) particles, causing the brown outlines to lose their intended luminosity. The other painting by Mya, in which the same brown outline was applied, did not show such formation of globules. Detection of oxalates in the corrosion of zinc support and brown outlines are discussed. This study shows the importance in understanding the artists’ materials and techniques, which have consequential effects to the degradation observed.http://link.springer.com/article/10.1186/s40494-019-0287-5Zinc supportSoapOxalateCorrosionEfflorescence
spellingShingle Lynn Chua
Whitish haze, soapy globules: micro-analysis of degraded burmese paintings on zinc supports
Heritage Science
Zinc support
Soap
Oxalate
Corrosion
Efflorescence
title Whitish haze, soapy globules: micro-analysis of degraded burmese paintings on zinc supports
title_full Whitish haze, soapy globules: micro-analysis of degraded burmese paintings on zinc supports
title_fullStr Whitish haze, soapy globules: micro-analysis of degraded burmese paintings on zinc supports
title_full_unstemmed Whitish haze, soapy globules: micro-analysis of degraded burmese paintings on zinc supports
title_short Whitish haze, soapy globules: micro-analysis of degraded burmese paintings on zinc supports
title_sort whitish haze soapy globules micro analysis of degraded burmese paintings on zinc supports
topic Zinc support
Soap
Oxalate
Corrosion
Efflorescence
url http://link.springer.com/article/10.1186/s40494-019-0287-5
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