Effect of μPlasma Modification on the Wettability and the Ageing Behaviour of Glass Fibre Reinforced Polyamide 6 (GFPA6)

Glass fibre reinforced polyamide 6 (GFPA6) thermoplastic composites (TPCs) are promising materials with excellent properties, but due to their low surface free energy they are usually difficult to wet, and therefore, possesses poor adhesion properties. μPlasma modification offers potential solutions...

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Main Authors: Chang Che, Behnam Dashtbozorg, Xiaoying Li, Hanshan Dong, Mike Jenkins
Format: Article
Language:English
Published: MDPI AG 2021-12-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/14/24/7721
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author Chang Che
Behnam Dashtbozorg
Xiaoying Li
Hanshan Dong
Mike Jenkins
author_facet Chang Che
Behnam Dashtbozorg
Xiaoying Li
Hanshan Dong
Mike Jenkins
author_sort Chang Che
collection DOAJ
description Glass fibre reinforced polyamide 6 (GFPA6) thermoplastic composites (TPCs) are promising materials with excellent properties, but due to their low surface free energy they are usually difficult to wet, and therefore, possesses poor adhesion properties. μPlasma modification offers potential solutions to this problem through functionalisation of the GFPA6 surface. In this study, the effect of μPlasma on the wetting behaviour of GFPA6 surfaces was investigated. Following single μPlasma treatment scans of GFPA6 samples, a substantial enhancement in wettability was observed. However, the effect of the μPlasma modification was subject to an ageing (hydrophobic recovery) phenomenon, although the enhancement was still partially maintained after 4 weeks. The ageing process was slower when the GFPA6 material was pre-dried and stored in low humidity conditions, thereby demonstrating the importance of the storage environment to the rate of ageing. Orientation of the fibres to the observed contact angle was found to be crucial for obtaining reproducible measurements with lower deviation. The influence of testing liquid, droplet volume and surface texture on the repeatability of the measured contact angle were also investigated.
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spelling doaj.art-040c4dac162a4eaa8eec4dd24c21b42c2023-11-23T09:22:03ZengMDPI AGMaterials1996-19442021-12-011424772110.3390/ma14247721Effect of μPlasma Modification on the Wettability and the Ageing Behaviour of Glass Fibre Reinforced Polyamide 6 (GFPA6)Chang Che0Behnam Dashtbozorg1Xiaoying Li2Hanshan Dong3Mike Jenkins4School of Metallurgy and Materials, University of Birmingham, Birmingham B15 2TT, UKSchool of Metallurgy and Materials, University of Birmingham, Birmingham B15 2TT, UKSchool of Metallurgy and Materials, University of Birmingham, Birmingham B15 2TT, UKSchool of Metallurgy and Materials, University of Birmingham, Birmingham B15 2TT, UKSchool of Metallurgy and Materials, University of Birmingham, Birmingham B15 2TT, UKGlass fibre reinforced polyamide 6 (GFPA6) thermoplastic composites (TPCs) are promising materials with excellent properties, but due to their low surface free energy they are usually difficult to wet, and therefore, possesses poor adhesion properties. μPlasma modification offers potential solutions to this problem through functionalisation of the GFPA6 surface. In this study, the effect of μPlasma on the wetting behaviour of GFPA6 surfaces was investigated. Following single μPlasma treatment scans of GFPA6 samples, a substantial enhancement in wettability was observed. However, the effect of the μPlasma modification was subject to an ageing (hydrophobic recovery) phenomenon, although the enhancement was still partially maintained after 4 weeks. The ageing process was slower when the GFPA6 material was pre-dried and stored in low humidity conditions, thereby demonstrating the importance of the storage environment to the rate of ageing. Orientation of the fibres to the observed contact angle was found to be crucial for obtaining reproducible measurements with lower deviation. The influence of testing liquid, droplet volume and surface texture on the repeatability of the measured contact angle were also investigated.https://www.mdpi.com/1996-1944/14/24/7721microplasmathermoplastic compositespolyamide 6wettabilityageingcontact angles
spellingShingle Chang Che
Behnam Dashtbozorg
Xiaoying Li
Hanshan Dong
Mike Jenkins
Effect of μPlasma Modification on the Wettability and the Ageing Behaviour of Glass Fibre Reinforced Polyamide 6 (GFPA6)
Materials
microplasma
thermoplastic composites
polyamide 6
wettability
ageing
contact angles
title Effect of μPlasma Modification on the Wettability and the Ageing Behaviour of Glass Fibre Reinforced Polyamide 6 (GFPA6)
title_full Effect of μPlasma Modification on the Wettability and the Ageing Behaviour of Glass Fibre Reinforced Polyamide 6 (GFPA6)
title_fullStr Effect of μPlasma Modification on the Wettability and the Ageing Behaviour of Glass Fibre Reinforced Polyamide 6 (GFPA6)
title_full_unstemmed Effect of μPlasma Modification on the Wettability and the Ageing Behaviour of Glass Fibre Reinforced Polyamide 6 (GFPA6)
title_short Effect of μPlasma Modification on the Wettability and the Ageing Behaviour of Glass Fibre Reinforced Polyamide 6 (GFPA6)
title_sort effect of μplasma modification on the wettability and the ageing behaviour of glass fibre reinforced polyamide 6 gfpa6
topic microplasma
thermoplastic composites
polyamide 6
wettability
ageing
contact angles
url https://www.mdpi.com/1996-1944/14/24/7721
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