Coordination Nature of 4-Mercaptoaniline to Sn(II) Ion: Formation of a One Dimensional Coordination Polymer and Its Decomposition to a Mono Nuclear Sn(IV) Complex
The coordination of the bifunctional ligand 4-mercaptoaniline with aqueo us tin(II) metal ion was studied. A coordination polymer was synthesized when an aqueous solution of SnCl2 was treated with 4-MA. The crystalline material is stable under atmospheric conditions retaining its oxidation state. Ho...
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| Format: | Article |
| Language: | English |
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MDPI AG
2014-12-01
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| Series: | Inorganics |
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| Online Access: | http://www.mdpi.com/2304-6740/2/4/652 |
| _version_ | 1811200139114577920 |
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| author | Eon S. Burkett Tasneem A. Siddiquee |
| author_facet | Eon S. Burkett Tasneem A. Siddiquee |
| author_sort | Eon S. Burkett |
| collection | DOAJ |
| description | The coordination of the bifunctional ligand 4-mercaptoaniline with aqueo us tin(II) metal ion was studied. A coordination polymer was synthesized when an aqueous solution of SnCl2 was treated with 4-MA. The crystalline material is stable under atmospheric conditions retaining its oxidation state. However, when submerged in a solution saturated with oxygen, the compound oxidizes to a mononuclear tin(IV) complex. Both the compounds were characterized by single crystal X-ray diffraction studies. Although the structure of the tin(IV) complex was previously reported, crystal structure of this compound was redetermined. |
| first_indexed | 2024-04-12T01:58:43Z |
| format | Article |
| id | doaj.art-041e229565174b0bb9f4e9ac005cafc5 |
| institution | Directory Open Access Journal |
| issn | 2304-6740 |
| language | English |
| last_indexed | 2024-04-12T01:58:43Z |
| publishDate | 2014-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Inorganics |
| spelling | doaj.art-041e229565174b0bb9f4e9ac005cafc52022-12-22T03:52:43ZengMDPI AGInorganics2304-67402014-12-012465265910.3390/inorganics2040652inorganics2040652Coordination Nature of 4-Mercaptoaniline to Sn(II) Ion: Formation of a One Dimensional Coordination Polymer and Its Decomposition to a Mono Nuclear Sn(IV) ComplexEon S. Burkett0Tasneem A. Siddiquee1Boswell Science Complex, Department of Chemistry, Tennessee State University, 3500 John A. Merritt Blvd., Nashville, TN 37209, USABoswell Science Complex, Department of Chemistry, Tennessee State University, 3500 John A. Merritt Blvd., Nashville, TN 37209, USAThe coordination of the bifunctional ligand 4-mercaptoaniline with aqueo us tin(II) metal ion was studied. A coordination polymer was synthesized when an aqueous solution of SnCl2 was treated with 4-MA. The crystalline material is stable under atmospheric conditions retaining its oxidation state. However, when submerged in a solution saturated with oxygen, the compound oxidizes to a mononuclear tin(IV) complex. Both the compounds were characterized by single crystal X-ray diffraction studies. Although the structure of the tin(IV) complex was previously reported, crystal structure of this compound was redetermined.http://www.mdpi.com/2304-6740/2/4/652tin(II)tin(IV)coordination complexpolymermetal sulfide4-Aminothiophenolmercaptoanilineaqueoussynthesizeredox |
| spellingShingle | Eon S. Burkett Tasneem A. Siddiquee Coordination Nature of 4-Mercaptoaniline to Sn(II) Ion: Formation of a One Dimensional Coordination Polymer and Its Decomposition to a Mono Nuclear Sn(IV) Complex Inorganics tin(II) tin(IV) coordination complex polymer metal sulfide 4-Aminothiophenol mercaptoaniline aqueous synthesize redox |
| title | Coordination Nature of 4-Mercaptoaniline to Sn(II) Ion: Formation of a One Dimensional Coordination Polymer and Its Decomposition to a Mono Nuclear Sn(IV) Complex |
| title_full | Coordination Nature of 4-Mercaptoaniline to Sn(II) Ion: Formation of a One Dimensional Coordination Polymer and Its Decomposition to a Mono Nuclear Sn(IV) Complex |
| title_fullStr | Coordination Nature of 4-Mercaptoaniline to Sn(II) Ion: Formation of a One Dimensional Coordination Polymer and Its Decomposition to a Mono Nuclear Sn(IV) Complex |
| title_full_unstemmed | Coordination Nature of 4-Mercaptoaniline to Sn(II) Ion: Formation of a One Dimensional Coordination Polymer and Its Decomposition to a Mono Nuclear Sn(IV) Complex |
| title_short | Coordination Nature of 4-Mercaptoaniline to Sn(II) Ion: Formation of a One Dimensional Coordination Polymer and Its Decomposition to a Mono Nuclear Sn(IV) Complex |
| title_sort | coordination nature of 4 mercaptoaniline to sn ii ion formation of a one dimensional coordination polymer and its decomposition to a mono nuclear sn iv complex |
| topic | tin(II) tin(IV) coordination complex polymer metal sulfide 4-Aminothiophenol mercaptoaniline aqueous synthesize redox |
| url | http://www.mdpi.com/2304-6740/2/4/652 |
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