Effect of Surface Treatment on Performance of Electrode Material Based on Carbon Fiber Cloth

The carbon fiber cloth was treated by surface treatment, and then it was used as the electrode substrate. The electrode material based on carbon fibers was synthesized by a galvanostatic electrodeposition method. The interface resistivity, electrochemical property and corrosion resistance of the CF/...

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Main Authors: XU Jian, ZHU Pei-xian, HAN Zhao-hui, CAO Yong, ZHOU Sheng-gang
Format: Article
Language:zho
Published: Journal of Materials Engineering 2018-01-01
Series:Cailiao gongcheng
Subjects:
Online Access:http://jme.biam.ac.cn/CN/Y2018/V46/I1/125
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author XU Jian
ZHU Pei-xian
HAN Zhao-hui
CAO Yong
ZHOU Sheng-gang
author_facet XU Jian
ZHU Pei-xian
HAN Zhao-hui
CAO Yong
ZHOU Sheng-gang
author_sort XU Jian
collection DOAJ
description The carbon fiber cloth was treated by surface treatment, and then it was used as the electrode substrate. The electrode material based on carbon fibers was synthesized by a galvanostatic electrodeposition method. The interface resistivity, electrochemical property and corrosion resistance of the CF/β-PbO<sub>2</sub> electrode were characterized by four-probe method and electrochemical workstation, respectively. The results show that the surface roughness and chemical activity of the carbon fibers can be significantly improved through surface treatment. The carbon fibers possess the best chemical activity on the surface at the hot-air oxidation temperature of 400℃. Joint hot-air and liquid-phase oxidations show that the chemical activity of the carbon fibers on the surface is further improved, the grooves and pits on the surface of the carbon fibers are more obvious, after this treatment, the interface resistivity of the CF/β-PbO<sub>2</sub> electrode reaches the minimum value of 6.19&#215;10<sup>-5</sup>Ω&#183;m, meanwhile, the conductivity and the electrochemical property of the CF/β-PbO<sub>2</sub> electrode reaches the best, and with the best corrosion resistance, the corrosion rate is only 1.44&#215;10<sup>-3</sup>g&#183;cm<sup>-2</sup>&#183;h<sup>-1</sup>.Thus, the interface resistivity, electrochemical property and corrosion resistance of the CF/β-PbO<sub>2</sub> electrode depend on the the interface structure of the CF/β-PbO<sub>2</sub> electrode obtained under different surface treatments.
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spelling doaj.art-042a0406b5684b449e09a26128b6a45d2023-01-03T06:24:17ZzhoJournal of Materials EngineeringCailiao gongcheng1001-43811001-43812018-01-0146112513210.11868/j.issn.1001-4381.2016.000590201801000590Effect of Surface Treatment on Performance of Electrode Material Based on Carbon Fiber ClothXU Jian0ZHU Pei-xian1HAN Zhao-hui2CAO Yong3ZHOU Sheng-gang4Electroslag Chamber, Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaElectroslag Chamber, Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaElectroslag Chamber, Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaElectroslag Chamber, Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaElectroslag Chamber, Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, ChinaThe carbon fiber cloth was treated by surface treatment, and then it was used as the electrode substrate. The electrode material based on carbon fibers was synthesized by a galvanostatic electrodeposition method. The interface resistivity, electrochemical property and corrosion resistance of the CF/β-PbO<sub>2</sub> electrode were characterized by four-probe method and electrochemical workstation, respectively. The results show that the surface roughness and chemical activity of the carbon fibers can be significantly improved through surface treatment. The carbon fibers possess the best chemical activity on the surface at the hot-air oxidation temperature of 400℃. Joint hot-air and liquid-phase oxidations show that the chemical activity of the carbon fibers on the surface is further improved, the grooves and pits on the surface of the carbon fibers are more obvious, after this treatment, the interface resistivity of the CF/β-PbO<sub>2</sub> electrode reaches the minimum value of 6.19&#215;10<sup>-5</sup>Ω&#183;m, meanwhile, the conductivity and the electrochemical property of the CF/β-PbO<sub>2</sub> electrode reaches the best, and with the best corrosion resistance, the corrosion rate is only 1.44&#215;10<sup>-3</sup>g&#183;cm<sup>-2</sup>&#183;h<sup>-1</sup>.Thus, the interface resistivity, electrochemical property and corrosion resistance of the CF/β-PbO<sub>2</sub> electrode depend on the the interface structure of the CF/β-PbO<sub>2</sub> electrode obtained under different surface treatments.http://jme.biam.ac.cn/CN/Y2018/V46/I1/125CF/β-PbO<sub>2</sub> electrodesurface treatmentinterface resistivityelectrochemical propertycorrosion resistance
spellingShingle XU Jian
ZHU Pei-xian
HAN Zhao-hui
CAO Yong
ZHOU Sheng-gang
Effect of Surface Treatment on Performance of Electrode Material Based on Carbon Fiber Cloth
Cailiao gongcheng
CF/β-PbO<sub>2</sub> electrode
surface treatment
interface resistivity
electrochemical property
corrosion resistance
title Effect of Surface Treatment on Performance of Electrode Material Based on Carbon Fiber Cloth
title_full Effect of Surface Treatment on Performance of Electrode Material Based on Carbon Fiber Cloth
title_fullStr Effect of Surface Treatment on Performance of Electrode Material Based on Carbon Fiber Cloth
title_full_unstemmed Effect of Surface Treatment on Performance of Electrode Material Based on Carbon Fiber Cloth
title_short Effect of Surface Treatment on Performance of Electrode Material Based on Carbon Fiber Cloth
title_sort effect of surface treatment on performance of electrode material based on carbon fiber cloth
topic CF/β-PbO<sub>2</sub> electrode
surface treatment
interface resistivity
electrochemical property
corrosion resistance
url http://jme.biam.ac.cn/CN/Y2018/V46/I1/125
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AT caoyong effectofsurfacetreatmentonperformanceofelectrodematerialbasedoncarbonfibercloth
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