The Effect of Rare Earth Metals Alloying on the Internal Quality of Industrially Produced Heavy Steel Forgings

The paper presented the findings obtained by industrial research and experimental development on the use of rare earth metals (REMs) in the production of heavy steel ingots and their impact on the internal quality of the 42CrMo4 grade steel forging. REMs alloying was carried out after vacuuming the...

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Main Authors: Petr Jonšta, Zdeněk Jonšta, Silvie Brožová, Manuela Ingaldi, Jacek Pietraszek, Dorota Klimecka-Tatar
Format: Article
Language:English
Published: MDPI AG 2021-09-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/14/18/5160
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author Petr Jonšta
Zdeněk Jonšta
Silvie Brožová
Manuela Ingaldi
Jacek Pietraszek
Dorota Klimecka-Tatar
author_facet Petr Jonšta
Zdeněk Jonšta
Silvie Brožová
Manuela Ingaldi
Jacek Pietraszek
Dorota Klimecka-Tatar
author_sort Petr Jonšta
collection DOAJ
description The paper presented the findings obtained by industrial research and experimental development on the use of rare earth metals (REMs) in the production of heavy steel ingots and their impact on the internal quality of the 42CrMo4 grade steel forging. REMs alloying was carried out after vacuuming the steel. A relatively large melting loss of cerium (about 50%) and its further decrease in casting due to reoxidation were observed. Refinement of structure and better mechanical properties of forged bar containing about 0.02 wt.% of Ce compared to that of the standard production were not achieved. The wind power shaft with content of about 0.06 wt.% of Ce showed high amount of REM inclusions, which were locally chained, and in some cases, initiated cracks. Four stoichiometrically different types of REM inclusions were detected in forgings, namely (La-Ce)<sub>2</sub>O<sub>2</sub>S + (La-Ce)O<sub>2</sub> + SiO<sub>2</sub> (minority); oxygen, phosphorus, arsenic, and antimony bound to lanthanum and cerium probably bonded with iron oxides La + Ce, MgO, Al<sub>2</sub>O<sub>3</sub> a SiO<sub>2</sub>; (La-Ce)<sub>2</sub>O<sub>2</sub>S, FeO, SiO<sub>2</sub>, and CaO or CaS.
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spelling doaj.art-04717686bfb34cb7aecf5287c7cc31762023-11-22T13:59:46ZengMDPI AGMaterials1996-19442021-09-011418516010.3390/ma14185160The Effect of Rare Earth Metals Alloying on the Internal Quality of Industrially Produced Heavy Steel ForgingsPetr Jonšta0Zdeněk Jonšta1Silvie Brožová2Manuela Ingaldi3Jacek Pietraszek4Dorota Klimecka-Tatar5Faculty of Materials Science and Technology, VŠB—Technical University of Ostrava, 708 00 Ostrava, Czech RepublicFaculty of Materials Science and Technology, VŠB—Technical University of Ostrava, 708 00 Ostrava, Czech RepublicFaculty of Materials Science and Technology, VŠB—Technical University of Ostrava, 708 00 Ostrava, Czech RepublicFaculty of Management, Czestochowa University of Technology, 42-201 Czestochowa, PolandFaculty of Mechanical Engineering, Cracow University of Technology, 31-155 Cracow, PolandFaculty of Management, Czestochowa University of Technology, 42-201 Czestochowa, PolandThe paper presented the findings obtained by industrial research and experimental development on the use of rare earth metals (REMs) in the production of heavy steel ingots and their impact on the internal quality of the 42CrMo4 grade steel forging. REMs alloying was carried out after vacuuming the steel. A relatively large melting loss of cerium (about 50%) and its further decrease in casting due to reoxidation were observed. Refinement of structure and better mechanical properties of forged bar containing about 0.02 wt.% of Ce compared to that of the standard production were not achieved. The wind power shaft with content of about 0.06 wt.% of Ce showed high amount of REM inclusions, which were locally chained, and in some cases, initiated cracks. Four stoichiometrically different types of REM inclusions were detected in forgings, namely (La-Ce)<sub>2</sub>O<sub>2</sub>S + (La-Ce)O<sub>2</sub> + SiO<sub>2</sub> (minority); oxygen, phosphorus, arsenic, and antimony bound to lanthanum and cerium probably bonded with iron oxides La + Ce, MgO, Al<sub>2</sub>O<sub>3</sub> a SiO<sub>2</sub>; (La-Ce)<sub>2</sub>O<sub>2</sub>S, FeO, SiO<sub>2</sub>, and CaO or CaS.https://www.mdpi.com/1996-1944/14/18/5160heavy forgingslow-alloyed structural steelsrare earth metals (REMs)nonmetallic inclusionsstructuremechanical properties
spellingShingle Petr Jonšta
Zdeněk Jonšta
Silvie Brožová
Manuela Ingaldi
Jacek Pietraszek
Dorota Klimecka-Tatar
The Effect of Rare Earth Metals Alloying on the Internal Quality of Industrially Produced Heavy Steel Forgings
Materials
heavy forgings
low-alloyed structural steels
rare earth metals (REMs)
nonmetallic inclusions
structure
mechanical properties
title The Effect of Rare Earth Metals Alloying on the Internal Quality of Industrially Produced Heavy Steel Forgings
title_full The Effect of Rare Earth Metals Alloying on the Internal Quality of Industrially Produced Heavy Steel Forgings
title_fullStr The Effect of Rare Earth Metals Alloying on the Internal Quality of Industrially Produced Heavy Steel Forgings
title_full_unstemmed The Effect of Rare Earth Metals Alloying on the Internal Quality of Industrially Produced Heavy Steel Forgings
title_short The Effect of Rare Earth Metals Alloying on the Internal Quality of Industrially Produced Heavy Steel Forgings
title_sort effect of rare earth metals alloying on the internal quality of industrially produced heavy steel forgings
topic heavy forgings
low-alloyed structural steels
rare earth metals (REMs)
nonmetallic inclusions
structure
mechanical properties
url https://www.mdpi.com/1996-1944/14/18/5160
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