Testing of activated carbon for water and non-volatile LNAPL quantitative determination in porous media under laboratory conditions

Activated carbon is a highly porous form of carbon, which has an exceptionally large surface area. Activated carbon material has been artificially processed as a set of plates, within which two different types of pores are present: micropores (< 2 nm) and transport pores (macropores >...

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Main Authors: Kamila BÁŤKOVÁ, Svatopluk MATULA, Markéta MIHÁLIKOVÁ, Ayele Teressa CHALA, João Manuel MOREIRA BARRADAS, Getu Bekere MEKONNEN
Format: Article
Language:English
Published: Czech Academy of Agricultural Sciences 2014-12-01
Series:Soil and Water Research
Subjects:
Online Access:https://swr.agriculturejournals.cz/artkey/swr-201404-0004_testing-of-activated-carbon-for-water-and-non-volatile-lnapl-quantitative-determination-in-porous-media-under-l.php
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author Kamila BÁŤKOVÁ
Svatopluk MATULA
Markéta MIHÁLIKOVÁ
Ayele Teressa CHALA
João Manuel MOREIRA BARRADAS
Getu Bekere MEKONNEN
author_facet Kamila BÁŤKOVÁ
Svatopluk MATULA
Markéta MIHÁLIKOVÁ
Ayele Teressa CHALA
João Manuel MOREIRA BARRADAS
Getu Bekere MEKONNEN
author_sort Kamila BÁŤKOVÁ
collection DOAJ
description Activated carbon is a highly porous form of carbon, which has an exceptionally large surface area. Activated carbon material has been artificially processed as a set of plates, within which two different types of pores are present: micropores (< 2 nm) and transport pores (macropores > 50 nm and mesopores 2-50 nm). The transport pores bring molecules of different substances (organic compounds) into the micropores, which are basically the active centres where the adsorption takes place. Activated carbon, due to its high adsorption potential, is used in many applications such as air, water, wastewater or chemical purification. In this study, the pelletized activated carbon (Silcarbon SC40) was tested for water and non-volatile LNAPL (Light Non-Aqueous Phase Liquid; medicinal mineral oil used in this study) determination in a porous medium (silica sand). The experiments were carried out under controlled laboratory conditions. Three different sets of experiments were carried out: (i) the water or LNAPL adsorption from pure media (water or LNAPL liquids); (ii) the water or LNAPL adsorption from pure media (water or LNAPL vapours); (iii) water and/or LNAPL adsorption from the porous material at different sampling intervals. Furthermore, the water/LNAPL contents of the porous media were determined on the basis of the water/LNAPL contents of sampled Silcarbon SC40. The results confirmed the suitability of the Silcarbon SC40 for water/LNAPL sampling from the porous media under laboratory conditions. The method is suitable for detection of water and/or LNAPL in a liquid or gaseous phase and also for water and/or LNAPL quantitative determination. For the quantitative determination a calibration of this method would be required.
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spelling doaj.art-0476baa76d8844d0bc97741cb8718f282023-02-23T03:48:26ZengCzech Academy of Agricultural SciencesSoil and Water Research1801-53951805-93842014-12-019416116810.17221/124/2014-SWRswr-201404-0004Testing of activated carbon for water and non-volatile LNAPL quantitative determination in porous media under laboratory conditionsKamila BÁŤKOVÁ0Svatopluk MATULA1Markéta MIHÁLIKOVÁ2Ayele Teressa CHALA3João Manuel MOREIRA BARRADAS4Getu Bekere MEKONNEN5Department of Water Resources, Faculty of Agrobiology, Czech University of Life Sciences Prague, Prague, Czech RepublicDepartment of Water Resources, Faculty of Agrobiology, Czech University of Life Sciences Prague, Prague, Czech RepublicDepartment of Water Resources, Faculty of Agrobiology, Czech University of Life Sciences Prague, Prague, Czech RepublicDepartment of Water Resources, Faculty of Agrobiology, Czech University of Life Sciences Prague, Prague, Czech RepublicDepartment of Water Resources, Faculty of Agrobiology, Czech University of Life Sciences Prague, Prague, Czech RepublicDepartment of Water Resources, Faculty of Agrobiology, Czech University of Life Sciences Prague, Prague, Czech RepublicActivated carbon is a highly porous form of carbon, which has an exceptionally large surface area. Activated carbon material has been artificially processed as a set of plates, within which two different types of pores are present: micropores (< 2 nm) and transport pores (macropores > 50 nm and mesopores 2-50 nm). The transport pores bring molecules of different substances (organic compounds) into the micropores, which are basically the active centres where the adsorption takes place. Activated carbon, due to its high adsorption potential, is used in many applications such as air, water, wastewater or chemical purification. In this study, the pelletized activated carbon (Silcarbon SC40) was tested for water and non-volatile LNAPL (Light Non-Aqueous Phase Liquid; medicinal mineral oil used in this study) determination in a porous medium (silica sand). The experiments were carried out under controlled laboratory conditions. Three different sets of experiments were carried out: (i) the water or LNAPL adsorption from pure media (water or LNAPL liquids); (ii) the water or LNAPL adsorption from pure media (water or LNAPL vapours); (iii) water and/or LNAPL adsorption from the porous material at different sampling intervals. Furthermore, the water/LNAPL contents of the porous media were determined on the basis of the water/LNAPL contents of sampled Silcarbon SC40. The results confirmed the suitability of the Silcarbon SC40 for water/LNAPL sampling from the porous media under laboratory conditions. The method is suitable for detection of water and/or LNAPL in a liquid or gaseous phase and also for water and/or LNAPL quantitative determination. For the quantitative determination a calibration of this method would be required.https://swr.agriculturejournals.cz/artkey/swr-201404-0004_testing-of-activated-carbon-for-water-and-non-volatile-lnapl-quantitative-determination-in-porous-media-under-l.phpactivated carbonlnaplsilica sandsilcarbon sc40sampling interval
spellingShingle Kamila BÁŤKOVÁ
Svatopluk MATULA
Markéta MIHÁLIKOVÁ
Ayele Teressa CHALA
João Manuel MOREIRA BARRADAS
Getu Bekere MEKONNEN
Testing of activated carbon for water and non-volatile LNAPL quantitative determination in porous media under laboratory conditions
Soil and Water Research
activated carbon
lnapl
silica sand
silcarbon sc40
sampling interval
title Testing of activated carbon for water and non-volatile LNAPL quantitative determination in porous media under laboratory conditions
title_full Testing of activated carbon for water and non-volatile LNAPL quantitative determination in porous media under laboratory conditions
title_fullStr Testing of activated carbon for water and non-volatile LNAPL quantitative determination in porous media under laboratory conditions
title_full_unstemmed Testing of activated carbon for water and non-volatile LNAPL quantitative determination in porous media under laboratory conditions
title_short Testing of activated carbon for water and non-volatile LNAPL quantitative determination in porous media under laboratory conditions
title_sort testing of activated carbon for water and non volatile lnapl quantitative determination in porous media under laboratory conditions
topic activated carbon
lnapl
silica sand
silcarbon sc40
sampling interval
url https://swr.agriculturejournals.cz/artkey/swr-201404-0004_testing-of-activated-carbon-for-water-and-non-volatile-lnapl-quantitative-determination-in-porous-media-under-l.php
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