Modelling the adsorption of iron and manganese by activated carbon from teak and shea charcoal for continuous low flow

Nearly 6494 boreholes with iron (Fe) and manganese (Mn) concentrations above permissible limits of 0.3 mg/L and 0.4 mg/L respectively in Ghana have been abandoned because of ineffective water treatment solutions. Activated carbon prepared from teak (Tectona grandis) and shea (Vitellaria paradoxa) ch...

Full description

Bibliographic Details
Main Authors: Worlanyo Kwadjo Siabi, Emmanuel Degraft-Johnson Owusu-Ansah, Helen Michelle Korkor Essandoh, Nana Yaw Asiedu
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2021-01-01
Series:Water-Energy Nexus
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2588912521000023
_version_ 1798013770158571520
author Worlanyo Kwadjo Siabi
Emmanuel Degraft-Johnson Owusu-Ansah
Helen Michelle Korkor Essandoh
Nana Yaw Asiedu
author_facet Worlanyo Kwadjo Siabi
Emmanuel Degraft-Johnson Owusu-Ansah
Helen Michelle Korkor Essandoh
Nana Yaw Asiedu
author_sort Worlanyo Kwadjo Siabi
collection DOAJ
description Nearly 6494 boreholes with iron (Fe) and manganese (Mn) concentrations above permissible limits of 0.3 mg/L and 0.4 mg/L respectively in Ghana have been abandoned because of ineffective water treatment solutions. Activated carbon prepared from teak (Tectona grandis) and shea (Vitellaria paradoxa) charcoal (ACM), of effective grain sizes 0.075–0.2 mm and 0.2–2.0 mm was found to achieve 92.5–100% Fe and Mn removal in batch tests. The experiments, which were repeated for natural groundwater with a low flow similar to boreholes simulated with handpumps and limited mechanized water systems achieved similar Fe and Mn adsorption levels. Data on Fe and Mn adsorption for varying ACM mass and grain sizes, using fixed columns in continuous flow tests were fitted to Adam-Bohart, Thomas and Yoon-Nelson adsorption models to generate data for improvement in water treatment designs. The objective of this modelling process is to develop a prediction mechanism for ACM mass and grain size needed for the design of Fe and Mn removal plants for groundwater with various characteristics. Adsorption constants obtained for Yoon-Nelson; 0.3095 and Adams-Bohart; 0.07335 at R2 values of 0.9728 and 0.9841 respectively are appropriate for generating ACM mass needed, when the target contaminant is Fe and Mn
first_indexed 2024-04-11T15:06:47Z
format Article
id doaj.art-049021476e1f48fe83ffb437f7aa7926
institution Directory Open Access Journal
issn 2588-9125
language English
last_indexed 2024-04-11T15:06:47Z
publishDate 2021-01-01
publisher KeAi Communications Co., Ltd.
record_format Article
series Water-Energy Nexus
spelling doaj.art-049021476e1f48fe83ffb437f7aa79262022-12-22T04:16:46ZengKeAi Communications Co., Ltd.Water-Energy Nexus2588-91252021-01-0148894Modelling the adsorption of iron and manganese by activated carbon from teak and shea charcoal for continuous low flowWorlanyo Kwadjo Siabi0Emmanuel Degraft-Johnson Owusu-Ansah1Helen Michelle Korkor Essandoh2Nana Yaw Asiedu3Community Water and Sanitation Agency, PMB, KIA, Accra, Ghana; Civil Engineering Department, College of Engineering, Kwame Nkrumah University of Science and Technology, Kumasi, Ghana; Corresponding author.Department of Statistics and Actuarial Science, College of Sciences, Kwame Nkrumah University of Science and Technology, Kumasi, GhanaCivil Engineering Department, College of Engineering, Kwame Nkrumah University of Science and Technology, Kumasi, GhanaDepartment of Chemical Engineering, College of Sciences, Kwame Nkrumah University of Science and Technology, Kumasi, GhanaNearly 6494 boreholes with iron (Fe) and manganese (Mn) concentrations above permissible limits of 0.3 mg/L and 0.4 mg/L respectively in Ghana have been abandoned because of ineffective water treatment solutions. Activated carbon prepared from teak (Tectona grandis) and shea (Vitellaria paradoxa) charcoal (ACM), of effective grain sizes 0.075–0.2 mm and 0.2–2.0 mm was found to achieve 92.5–100% Fe and Mn removal in batch tests. The experiments, which were repeated for natural groundwater with a low flow similar to boreholes simulated with handpumps and limited mechanized water systems achieved similar Fe and Mn adsorption levels. Data on Fe and Mn adsorption for varying ACM mass and grain sizes, using fixed columns in continuous flow tests were fitted to Adam-Bohart, Thomas and Yoon-Nelson adsorption models to generate data for improvement in water treatment designs. The objective of this modelling process is to develop a prediction mechanism for ACM mass and grain size needed for the design of Fe and Mn removal plants for groundwater with various characteristics. Adsorption constants obtained for Yoon-Nelson; 0.3095 and Adams-Bohart; 0.07335 at R2 values of 0.9728 and 0.9841 respectively are appropriate for generating ACM mass needed, when the target contaminant is Fe and Mnhttp://www.sciencedirect.com/science/article/pii/S2588912521000023Kinetic ModellingContinuous flowActivated carbonAdsorptionIron and Manganese removal
spellingShingle Worlanyo Kwadjo Siabi
Emmanuel Degraft-Johnson Owusu-Ansah
Helen Michelle Korkor Essandoh
Nana Yaw Asiedu
Modelling the adsorption of iron and manganese by activated carbon from teak and shea charcoal for continuous low flow
Water-Energy Nexus
Kinetic Modelling
Continuous flow
Activated carbon
Adsorption
Iron and Manganese removal
title Modelling the adsorption of iron and manganese by activated carbon from teak and shea charcoal for continuous low flow
title_full Modelling the adsorption of iron and manganese by activated carbon from teak and shea charcoal for continuous low flow
title_fullStr Modelling the adsorption of iron and manganese by activated carbon from teak and shea charcoal for continuous low flow
title_full_unstemmed Modelling the adsorption of iron and manganese by activated carbon from teak and shea charcoal for continuous low flow
title_short Modelling the adsorption of iron and manganese by activated carbon from teak and shea charcoal for continuous low flow
title_sort modelling the adsorption of iron and manganese by activated carbon from teak and shea charcoal for continuous low flow
topic Kinetic Modelling
Continuous flow
Activated carbon
Adsorption
Iron and Manganese removal
url http://www.sciencedirect.com/science/article/pii/S2588912521000023
work_keys_str_mv AT worlanyokwadjosiabi modellingtheadsorptionofironandmanganesebyactivatedcarbonfromteakandsheacharcoalforcontinuouslowflow
AT emmanueldegraftjohnsonowusuansah modellingtheadsorptionofironandmanganesebyactivatedcarbonfromteakandsheacharcoalforcontinuouslowflow
AT helenmichellekorkoressandoh modellingtheadsorptionofironandmanganesebyactivatedcarbonfromteakandsheacharcoalforcontinuouslowflow
AT nanayawasiedu modellingtheadsorptionofironandmanganesebyactivatedcarbonfromteakandsheacharcoalforcontinuouslowflow