Aquabis(4-methylbenzoato)-κO;κ2O,O′-bis(pyridine-κN)nickel(II)
In the title mononuclear complex, [Ni(C8H7O2)2(C5H5N)2(H2O)], the NiII atom is in a distorted octahedral arrangement, coordinated by three carboxylate O atoms from one bidentate 4-methylbenzoate ligand and one monodentate 4-methylbenzoate ligand, two N atoms from pyridine ligands, axially positioned...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680800634X |
| _version_ | 1818320886505144320 |
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| author | Li-Li Ji Hao Wang Wen-Dong Song |
| author_facet | Li-Li Ji Hao Wang Wen-Dong Song |
| author_sort | Li-Li Ji |
| collection | DOAJ |
| description | In the title mononuclear complex, [Ni(C8H7O2)2(C5H5N)2(H2O)], the NiII atom is in a distorted octahedral arrangement, coordinated by three carboxylate O atoms from one bidentate 4-methylbenzoate ligand and one monodentate 4-methylbenzoate ligand, two N atoms from pyridine ligands, axially positioned, and a water molecule. The equatorially positioned water molecule and uncoordinated carboxylate O atom form an intramolecular hydrogen bond. An intermolecular O—H...O hydrogen bond between the coordinated water molecule and carboxylate O atom of the 4-methylbenzoate ligand forms infinite chains along the b axis. These chains are connected by C—H...π interactions. |
| first_indexed | 2024-12-13T10:32:08Z |
| format | Article |
| id | doaj.art-049d2d19890048cf9be8ff358e070ecb |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:32:08Z |
| publishDate | 2008-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-049d2d19890048cf9be8ff358e070ecb2022-12-21T23:50:50ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-04-01644m548m54810.1107/S160053680800634XAquabis(4-methylbenzoato)-κO;κ2O,O′-bis(pyridine-κN)nickel(II)Li-Li JiHao WangWen-Dong SongIn the title mononuclear complex, [Ni(C8H7O2)2(C5H5N)2(H2O)], the NiII atom is in a distorted octahedral arrangement, coordinated by three carboxylate O atoms from one bidentate 4-methylbenzoate ligand and one monodentate 4-methylbenzoate ligand, two N atoms from pyridine ligands, axially positioned, and a water molecule. The equatorially positioned water molecule and uncoordinated carboxylate O atom form an intramolecular hydrogen bond. An intermolecular O—H...O hydrogen bond between the coordinated water molecule and carboxylate O atom of the 4-methylbenzoate ligand forms infinite chains along the b axis. These chains are connected by C—H...π interactions.http://scripts.iucr.org/cgi-bin/paper?S160053680800634X |
| spellingShingle | Li-Li Ji Hao Wang Wen-Dong Song Aquabis(4-methylbenzoato)-κO;κ2O,O′-bis(pyridine-κN)nickel(II) Acta Crystallographica Section E |
| title | Aquabis(4-methylbenzoato)-κO;κ2O,O′-bis(pyridine-κN)nickel(II) |
| title_full | Aquabis(4-methylbenzoato)-κO;κ2O,O′-bis(pyridine-κN)nickel(II) |
| title_fullStr | Aquabis(4-methylbenzoato)-κO;κ2O,O′-bis(pyridine-κN)nickel(II) |
| title_full_unstemmed | Aquabis(4-methylbenzoato)-κO;κ2O,O′-bis(pyridine-κN)nickel(II) |
| title_short | Aquabis(4-methylbenzoato)-κO;κ2O,O′-bis(pyridine-κN)nickel(II) |
| title_sort | aquabis 4 methylbenzoato 954 o 954 2o o 8242 bis pyridine 954 n nickel ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053680800634X |
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