Quantification of formic acid and acetic acid emissions from heritage collections under indoor room conditions. Part I: laboratory and field measurements

Abstract The area-specific emission rates of formic acid and acetic acid from heritage objects made of wood and paper were quantified for normal indoor room conditions (23 °C, 50% RH) as well as for cooler (10 °C) and drier (20% RH) conditions. At normal indoor conditions, the emission rate of formi...

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Main Authors: Signe Hjerrild Smedemark, Morten Ryhl-Svendsen, Alexandra Schieweck
Format: Article
Language:English
Published: SpringerOpen 2020-06-01
Series:Heritage Science
Subjects:
Online Access:http://link.springer.com/article/10.1186/s40494-020-00404-0
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author Signe Hjerrild Smedemark
Morten Ryhl-Svendsen
Alexandra Schieweck
author_facet Signe Hjerrild Smedemark
Morten Ryhl-Svendsen
Alexandra Schieweck
author_sort Signe Hjerrild Smedemark
collection DOAJ
description Abstract The area-specific emission rates of formic acid and acetic acid from heritage objects made of wood and paper were quantified for normal indoor room conditions (23 °C, 50% RH) as well as for cooler (10 °C) and drier (20% RH) conditions. At normal indoor conditions, the emission rate of formic acid and acetic acid together were in the range of 10 to 300 µg m−2 h−1. The emission rate decreased by a factor of 2–4 from wood and paper when lowering the temperature from 23 to 10 °C. The emission rate decreased by more than a factor of 2 when reducing the relative humidity (RH) from 50% to 20%. This corresponds well with field measurements in real storage rooms containing heritage collections. In addition, 36 volatile organic compounds (VOCs) were identified to be released by four paper samples. All the VOCs detected can in general originate from several sources. Therefore, these substances cannot be used as unique degradation markers for paper but rather as an indication of emission sources present in the indoor environment.
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spelling doaj.art-04e3ca67a5b04b6d8f50c319f13358da2022-12-21T18:39:12ZengSpringerOpenHeritage Science2050-74452020-06-01811810.1186/s40494-020-00404-0Quantification of formic acid and acetic acid emissions from heritage collections under indoor room conditions. Part I: laboratory and field measurementsSigne Hjerrild Smedemark0Morten Ryhl-Svendsen1Alexandra Schieweck2The School of Conservation, The Royal Danish Academy of Fine Arts Schools of Architecture, Design and ConservationThe School of Conservation, The Royal Danish Academy of Fine Arts Schools of Architecture, Design and ConservationDepartment of Material Analysis and Indoor Chemistry, Fraunhofer WKIAbstract The area-specific emission rates of formic acid and acetic acid from heritage objects made of wood and paper were quantified for normal indoor room conditions (23 °C, 50% RH) as well as for cooler (10 °C) and drier (20% RH) conditions. At normal indoor conditions, the emission rate of formic acid and acetic acid together were in the range of 10 to 300 µg m−2 h−1. The emission rate decreased by a factor of 2–4 from wood and paper when lowering the temperature from 23 to 10 °C. The emission rate decreased by more than a factor of 2 when reducing the relative humidity (RH) from 50% to 20%. This corresponds well with field measurements in real storage rooms containing heritage collections. In addition, 36 volatile organic compounds (VOCs) were identified to be released by four paper samples. All the VOCs detected can in general originate from several sources. Therefore, these substances cannot be used as unique degradation markers for paper but rather as an indication of emission sources present in the indoor environment.http://link.springer.com/article/10.1186/s40494-020-00404-0Indoor air pollutionVolatile organic compoundsEmission rateRelative humidityTemperatureActive sampling
spellingShingle Signe Hjerrild Smedemark
Morten Ryhl-Svendsen
Alexandra Schieweck
Quantification of formic acid and acetic acid emissions from heritage collections under indoor room conditions. Part I: laboratory and field measurements
Heritage Science
Indoor air pollution
Volatile organic compounds
Emission rate
Relative humidity
Temperature
Active sampling
title Quantification of formic acid and acetic acid emissions from heritage collections under indoor room conditions. Part I: laboratory and field measurements
title_full Quantification of formic acid and acetic acid emissions from heritage collections under indoor room conditions. Part I: laboratory and field measurements
title_fullStr Quantification of formic acid and acetic acid emissions from heritage collections under indoor room conditions. Part I: laboratory and field measurements
title_full_unstemmed Quantification of formic acid and acetic acid emissions from heritage collections under indoor room conditions. Part I: laboratory and field measurements
title_short Quantification of formic acid and acetic acid emissions from heritage collections under indoor room conditions. Part I: laboratory and field measurements
title_sort quantification of formic acid and acetic acid emissions from heritage collections under indoor room conditions part i laboratory and field measurements
topic Indoor air pollution
Volatile organic compounds
Emission rate
Relative humidity
Temperature
Active sampling
url http://link.springer.com/article/10.1186/s40494-020-00404-0
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