A triclinic polymorph of bis(μ-di-tert-butylphosphanido)bis[(di-tert-butylphosphane)palladium(I)]
A new polymorph of the title compound, [Pd2(C8H18P)2(C8H19P)2], has been found. It belongs to the triclinic P-1 space group, whereas the known form [Leoni, Sommovigo, Pasquali, Sabatino & Braga (1992), J. Organomet. Chem. 423, 263–270] crystallizes in the monoclinic C2/c sp...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812023574 |
| _version_ | 1828137889793310720 |
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| author | Jens Breunig Hans-Wolfram Lerner Michael Bolte |
| author_facet | Jens Breunig Hans-Wolfram Lerner Michael Bolte |
| author_sort | Jens Breunig |
| collection | DOAJ |
| description | A new polymorph of the title compound, [Pd2(C8H18P)2(C8H19P)2], has been found. It belongs to the triclinic P-1 space group, whereas the known form [Leoni, Sommovigo, Pasquali, Sabatino & Braga (1992), J. Organomet. Chem. 423, 263–270] crystallizes in the monoclinic C2/c space group. The title compound features a dinuclear palladium complex with a planar central Pd2(μ-P)2 core (r.m.s. deviation = 0.003 Å). The Pd—Pd distance of 2.5988 (5) Å is within the range of a PdI—PdI bond. The molecules of both polymorphs are located on a crystallographic centre of inversion. The molecular conformations of the two polymorphs are essentially identical. The crystal packing patterns, on the other hand, are slightly different. |
| first_indexed | 2024-04-11T18:27:07Z |
| format | Article |
| id | doaj.art-04e84e1079f6425ea33e05f1f1b81ba6 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:27:07Z |
| publishDate | 2012-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-04e84e1079f6425ea33e05f1f1b81ba62022-12-22T04:09:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686m836m83610.1107/S1600536812023574A triclinic polymorph of bis(μ-di-tert-butylphosphanido)bis[(di-tert-butylphosphane)palladium(I)]Jens BreunigHans-Wolfram LernerMichael BolteA new polymorph of the title compound, [Pd2(C8H18P)2(C8H19P)2], has been found. It belongs to the triclinic P-1 space group, whereas the known form [Leoni, Sommovigo, Pasquali, Sabatino & Braga (1992), J. Organomet. Chem. 423, 263–270] crystallizes in the monoclinic C2/c space group. The title compound features a dinuclear palladium complex with a planar central Pd2(μ-P)2 core (r.m.s. deviation = 0.003 Å). The Pd—Pd distance of 2.5988 (5) Å is within the range of a PdI—PdI bond. The molecules of both polymorphs are located on a crystallographic centre of inversion. The molecular conformations of the two polymorphs are essentially identical. The crystal packing patterns, on the other hand, are slightly different.http://scripts.iucr.org/cgi-bin/paper?S1600536812023574 |
| spellingShingle | Jens Breunig Hans-Wolfram Lerner Michael Bolte A triclinic polymorph of bis(μ-di-tert-butylphosphanido)bis[(di-tert-butylphosphane)palladium(I)] Acta Crystallographica Section E |
| title | A triclinic polymorph of bis(μ-di-tert-butylphosphanido)bis[(di-tert-butylphosphane)palladium(I)] |
| title_full | A triclinic polymorph of bis(μ-di-tert-butylphosphanido)bis[(di-tert-butylphosphane)palladium(I)] |
| title_fullStr | A triclinic polymorph of bis(μ-di-tert-butylphosphanido)bis[(di-tert-butylphosphane)palladium(I)] |
| title_full_unstemmed | A triclinic polymorph of bis(μ-di-tert-butylphosphanido)bis[(di-tert-butylphosphane)palladium(I)] |
| title_short | A triclinic polymorph of bis(μ-di-tert-butylphosphanido)bis[(di-tert-butylphosphane)palladium(I)] |
| title_sort | triclinic polymorph of bis amp 956 di tert butylphosphanido bis di tert butylphosphane palladium i |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812023574 |
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