Properties of Red Mud Neutralized with Sulfuric Acid and Effects on Cement Mortar

The purpose of this study was to recycle red mud, an industrial byproduct that generates 300,000 tons per year, into the construction industry. Red mud was prepared as a liquid, neutralized with sulfuric acid, and replaced with cement mortar. The properties of liquefied red mud (LRM) neutralized wit...

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Main Authors: Suk-Pyo Kang, Sang-Jin Kim, Seong-Uk Hong, Byoung-Ky Lee
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/13/4730
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author Suk-Pyo Kang
Sang-Jin Kim
Seong-Uk Hong
Byoung-Ky Lee
author_facet Suk-Pyo Kang
Sang-Jin Kim
Seong-Uk Hong
Byoung-Ky Lee
author_sort Suk-Pyo Kang
collection DOAJ
description The purpose of this study was to recycle red mud, an industrial byproduct that generates 300,000 tons per year, into the construction industry. Red mud was prepared as a liquid, neutralized with sulfuric acid, and replaced with cement mortar. The properties of liquefied red mud (LRM) neutralized with sulfuric acid (LRM + S) were investigated as well as its effect on cement mortar’s mechanical and hydration characteristics. The pH of LRM + S stabilized at 7.6; its SO<sub>3</sub> content was ~4.19% higher than that of LRM. Sulfites were contributed by calcium and sodium sulfate. The flows and setting times of the mortars containing LRM and LRM + S decreased as the substitution rate increased. The compressive strength of mortar that replaced 5% of cement with LRM + S was similar to that of the plain cement mortar. Scanning electron microscopy and X-ray diffraction revealed that the hydration products of LRM + S-containing cement mortar were similar to those of the plain cement mortar. Thus, LRM + S can be used as a cement substitute.
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spelling doaj.art-04fde4341a454d368c8c820b343a66cb2023-11-18T16:59:00ZengMDPI AGMaterials1996-19442023-06-011613473010.3390/ma16134730Properties of Red Mud Neutralized with Sulfuric Acid and Effects on Cement MortarSuk-Pyo Kang0Sang-Jin Kim1Seong-Uk Hong2Byoung-Ky Lee3Department of Construction Engineering, Woosuk University, Jincheon 27841, Republic of KoreaDepartment of Architecture, Woosuk University, Jincheon 27841, Republic of KoreaDepartment of Construction Engineering, Woosuk University, Jincheon 27841, Republic of KoreaCOCHEMS Co., Ltd., Industrial Tools Circulating Center, 160, Daehwa-ro, Daedeok-gu, Daejeon 34368, Republic of KoreaThe purpose of this study was to recycle red mud, an industrial byproduct that generates 300,000 tons per year, into the construction industry. Red mud was prepared as a liquid, neutralized with sulfuric acid, and replaced with cement mortar. The properties of liquefied red mud (LRM) neutralized with sulfuric acid (LRM + S) were investigated as well as its effect on cement mortar’s mechanical and hydration characteristics. The pH of LRM + S stabilized at 7.6; its SO<sub>3</sub> content was ~4.19% higher than that of LRM. Sulfites were contributed by calcium and sodium sulfate. The flows and setting times of the mortars containing LRM and LRM + S decreased as the substitution rate increased. The compressive strength of mortar that replaced 5% of cement with LRM + S was similar to that of the plain cement mortar. Scanning electron microscopy and X-ray diffraction revealed that the hydration products of LRM + S-containing cement mortar were similar to those of the plain cement mortar. Thus, LRM + S can be used as a cement substitute.https://www.mdpi.com/1996-1944/16/13/4730red mudliquefied red mudneutralized red mudcement mortarsrecyclingX-ray diffraction
spellingShingle Suk-Pyo Kang
Sang-Jin Kim
Seong-Uk Hong
Byoung-Ky Lee
Properties of Red Mud Neutralized with Sulfuric Acid and Effects on Cement Mortar
Materials
red mud
liquefied red mud
neutralized red mud
cement mortars
recycling
X-ray diffraction
title Properties of Red Mud Neutralized with Sulfuric Acid and Effects on Cement Mortar
title_full Properties of Red Mud Neutralized with Sulfuric Acid and Effects on Cement Mortar
title_fullStr Properties of Red Mud Neutralized with Sulfuric Acid and Effects on Cement Mortar
title_full_unstemmed Properties of Red Mud Neutralized with Sulfuric Acid and Effects on Cement Mortar
title_short Properties of Red Mud Neutralized with Sulfuric Acid and Effects on Cement Mortar
title_sort properties of red mud neutralized with sulfuric acid and effects on cement mortar
topic red mud
liquefied red mud
neutralized red mud
cement mortars
recycling
X-ray diffraction
url https://www.mdpi.com/1996-1944/16/13/4730
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