Photochemical Synthesis of Gold and Silver Nanoparticles—A Review

Nanomaterials have supported important technological advances due to their unique properties and their applicability in various fields, such as biomedicine, catalysis, environment, energy, and electronics. This has triggered a tremendous increase in their demand. In turn, materials scientists have s...

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Main Authors: Nicole Jara, Nataly S. Milán, Ashiqur Rahman, Lynda Mouheb, Daria C. Boffito, Clayton Jeffryes, Si Amar Dahoumane
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/26/15/4585
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author Nicole Jara
Nataly S. Milán
Ashiqur Rahman
Lynda Mouheb
Daria C. Boffito
Clayton Jeffryes
Si Amar Dahoumane
author_facet Nicole Jara
Nataly S. Milán
Ashiqur Rahman
Lynda Mouheb
Daria C. Boffito
Clayton Jeffryes
Si Amar Dahoumane
author_sort Nicole Jara
collection DOAJ
description Nanomaterials have supported important technological advances due to their unique properties and their applicability in various fields, such as biomedicine, catalysis, environment, energy, and electronics. This has triggered a tremendous increase in their demand. In turn, materials scientists have sought facile methods to produce nanomaterials of desired features, i.e., morphology, composition, colloidal stability, and surface chemistry, as these determine the targeted application. The advent of photoprocesses has enabled the easy, fast, scalable, and cost- and energy-effective production of metallic nanoparticles of controlled properties without the use of harmful reagents or sophisticated equipment. Herein, we overview the synthesis of gold and silver nanoparticles via photochemical routes. We extensively discuss the effect of varying the experimental parameters, such as the pH, exposure time, and source of irradiation, the use or not of reductants and surfactants, reagents’ nature and concentration, on the outcomes of these noble nanoparticles, namely, their size, shape, and colloidal stability. The hypothetical mechanisms that govern these green processes are discussed whenever available. Finally, we mention their applications and insights for future developments.
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spelling doaj.art-0512bbd35c81435e851f283e261974c82023-11-22T06:00:17ZengMDPI AGMolecules1420-30492021-07-012615458510.3390/molecules26154585Photochemical Synthesis of Gold and Silver Nanoparticles—A ReviewNicole Jara0Nataly S. Milán1Ashiqur Rahman2Lynda Mouheb3Daria C. Boffito4Clayton Jeffryes5Si Amar Dahoumane6School of Biological Sciences and Engineering, Yachay Tech University, Hacienda San José s/n, San Miguel de Urcuquí 100119, EcuadorSchool of Biological Sciences and Engineering, Yachay Tech University, Hacienda San José s/n, San Miguel de Urcuquí 100119, EcuadorCenter for Midstream Management and Science, Lamar University, Beaumont, TX 77710, USALaboratoire de Recherche de Chimie Appliquée et de Génie Chimique, Hasnaoua I, Université Mouloud Mammeri B.P.17 RP, Tizi-Ouzou 15000, AlgeriaDepartment of Chemical Engineering, Polytechnique Montréal, C.P. 6079, Succ. Centre-Ville, Montréal, QC H3C 3A7, CanadaCenter for Midstream Management and Science, Lamar University, Beaumont, TX 77710, USASchool of Biological Sciences and Engineering, Yachay Tech University, Hacienda San José s/n, San Miguel de Urcuquí 100119, EcuadorNanomaterials have supported important technological advances due to their unique properties and their applicability in various fields, such as biomedicine, catalysis, environment, energy, and electronics. This has triggered a tremendous increase in their demand. In turn, materials scientists have sought facile methods to produce nanomaterials of desired features, i.e., morphology, composition, colloidal stability, and surface chemistry, as these determine the targeted application. The advent of photoprocesses has enabled the easy, fast, scalable, and cost- and energy-effective production of metallic nanoparticles of controlled properties without the use of harmful reagents or sophisticated equipment. Herein, we overview the synthesis of gold and silver nanoparticles via photochemical routes. We extensively discuss the effect of varying the experimental parameters, such as the pH, exposure time, and source of irradiation, the use or not of reductants and surfactants, reagents’ nature and concentration, on the outcomes of these noble nanoparticles, namely, their size, shape, and colloidal stability. The hypothetical mechanisms that govern these green processes are discussed whenever available. Finally, we mention their applications and insights for future developments.https://www.mdpi.com/1420-3049/26/15/4585photochemistrynanoparticle synthesisAu NPsAg NPsgreen processesmechanistic aspects
spellingShingle Nicole Jara
Nataly S. Milán
Ashiqur Rahman
Lynda Mouheb
Daria C. Boffito
Clayton Jeffryes
Si Amar Dahoumane
Photochemical Synthesis of Gold and Silver Nanoparticles—A Review
Molecules
photochemistry
nanoparticle synthesis
Au NPs
Ag NPs
green processes
mechanistic aspects
title Photochemical Synthesis of Gold and Silver Nanoparticles—A Review
title_full Photochemical Synthesis of Gold and Silver Nanoparticles—A Review
title_fullStr Photochemical Synthesis of Gold and Silver Nanoparticles—A Review
title_full_unstemmed Photochemical Synthesis of Gold and Silver Nanoparticles—A Review
title_short Photochemical Synthesis of Gold and Silver Nanoparticles—A Review
title_sort photochemical synthesis of gold and silver nanoparticles a review
topic photochemistry
nanoparticle synthesis
Au NPs
Ag NPs
green processes
mechanistic aspects
url https://www.mdpi.com/1420-3049/26/15/4585
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