Hot-dip aluminizing of Fe–Cr–B cast steel in Al–Ti–B alloy melt

The periodic layered structure (PLS) composed of alternative arrangement of Cr–Al–B MAB phase and FeAl3 was formed at the (Cr, Fe)2B/Al interface during hot-dip aluminizing (HDA) of Fe–Cr–B cast steel in molten Al. However, the effect of alloying element in the Al melt on the PLS was still unknown....

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Main Authors: Xianman Zhang, Zhenhai Zheng, Qi Hu, Wei Wen, Zicheng Ling, Hongfeng Luo
Format: Article
Language:English
Published: Elsevier 2024-03-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785424004356
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author Xianman Zhang
Zhenhai Zheng
Qi Hu
Wei Wen
Zicheng Ling
Hongfeng Luo
author_facet Xianman Zhang
Zhenhai Zheng
Qi Hu
Wei Wen
Zicheng Ling
Hongfeng Luo
author_sort Xianman Zhang
collection DOAJ
description The periodic layered structure (PLS) composed of alternative arrangement of Cr–Al–B MAB phase and FeAl3 was formed at the (Cr, Fe)2B/Al interface during hot-dip aluminizing (HDA) of Fe–Cr–B cast steel in molten Al. However, the effect of alloying element in the Al melt on the PLS was still unknown. This work focused on the effect of Ti on the interfacial reaction between Fe–Cr–B cast steel and molten Al–Ti–B alloy. The Ti atoms in Al–Ti–B alloy melt could partially replace the Cr atoms in the M-sites of the Cr–Al–B MAB phase contained in the PLS after it formed in-situ, leading to the formation of (Cr, Ti)–Al–B MAB phase solid solution. The B atoms in the melt absorbed by the Cr–Al–B MAB phase also accounted for the blackening of the Cr–Al–B MAB phase. It was the first time that the M-site MAB phase solid solution in the Cr–Al–B system was prepared by hot-dip aluminizing.
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spelling doaj.art-05133b469ce14b0c9aa121b0969456d22024-03-24T06:58:28ZengElsevierJournal of Materials Research and Technology2238-78542024-03-012938913897Hot-dip aluminizing of Fe–Cr–B cast steel in Al–Ti–B alloy meltXianman Zhang0Zhenhai Zheng1Qi Hu2Wei Wen3Zicheng Ling4Hongfeng Luo5School of Mechanical and Electrical Engineering, Hainan University, Haikou, China; Collaborative Innovation Center of Ecological Civilization, Hainan University, Haikou, China; Corresponding author. School of Mechanical and Electrical Engineering, Hainan University, Haikou, China.School of Mechanical and Electrical Engineering, Hainan University, Haikou, China; Collaborative Innovation Center of Ecological Civilization, Hainan University, Haikou, ChinaSchool of Mechanical and Electrical Engineering, Hainan University, Haikou, China; Collaborative Innovation Center of Ecological Civilization, Hainan University, Haikou, ChinaSchool of Mechanical and Electrical Engineering, Hainan University, Haikou, China; Collaborative Innovation Center of Ecological Civilization, Hainan University, Haikou, ChinaSchool of Materials Science and Engineering, North China University of Water, Resources and Electric Power, Zhengzhou, 450045, ChinaSchool of Mechanical and Electrical Engineering, Hainan University, Haikou, ChinaThe periodic layered structure (PLS) composed of alternative arrangement of Cr–Al–B MAB phase and FeAl3 was formed at the (Cr, Fe)2B/Al interface during hot-dip aluminizing (HDA) of Fe–Cr–B cast steel in molten Al. However, the effect of alloying element in the Al melt on the PLS was still unknown. This work focused on the effect of Ti on the interfacial reaction between Fe–Cr–B cast steel and molten Al–Ti–B alloy. The Ti atoms in Al–Ti–B alloy melt could partially replace the Cr atoms in the M-sites of the Cr–Al–B MAB phase contained in the PLS after it formed in-situ, leading to the formation of (Cr, Ti)–Al–B MAB phase solid solution. The B atoms in the melt absorbed by the Cr–Al–B MAB phase also accounted for the blackening of the Cr–Al–B MAB phase. It was the first time that the M-site MAB phase solid solution in the Cr–Al–B system was prepared by hot-dip aluminizing.http://www.sciencedirect.com/science/article/pii/S2238785424004356Periodic layered structureHot-dip aluminizingMAB phase solid solutionM-siteFe–Cr–B cast steel
spellingShingle Xianman Zhang
Zhenhai Zheng
Qi Hu
Wei Wen
Zicheng Ling
Hongfeng Luo
Hot-dip aluminizing of Fe–Cr–B cast steel in Al–Ti–B alloy melt
Journal of Materials Research and Technology
Periodic layered structure
Hot-dip aluminizing
MAB phase solid solution
M-site
Fe–Cr–B cast steel
title Hot-dip aluminizing of Fe–Cr–B cast steel in Al–Ti–B alloy melt
title_full Hot-dip aluminizing of Fe–Cr–B cast steel in Al–Ti–B alloy melt
title_fullStr Hot-dip aluminizing of Fe–Cr–B cast steel in Al–Ti–B alloy melt
title_full_unstemmed Hot-dip aluminizing of Fe–Cr–B cast steel in Al–Ti–B alloy melt
title_short Hot-dip aluminizing of Fe–Cr–B cast steel in Al–Ti–B alloy melt
title_sort hot dip aluminizing of fe cr b cast steel in al ti b alloy melt
topic Periodic layered structure
Hot-dip aluminizing
MAB phase solid solution
M-site
Fe–Cr–B cast steel
url http://www.sciencedirect.com/science/article/pii/S2238785424004356
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