The effect of solvent on the kinetics of the oxidation of 3-methyl-2,6-diphenyl-piperidin-4-one by quinolinium fluorochromate in aqueous organic media
The kinetics of the oxidation of 3-methyl-2,6-diphenyl-piperidin-4-one by quinolinium fluorochromate (QFC) have been investigated in aqueous solutions of dimethyl sulphoxide, 1,4-dioxane, tert-butanol and acetone. The influence of the added co-solvent on the reactivity were analysed in the...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2001-01-01
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| Series: | Journal of the Serbian Chemical Society |
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| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2001/0352-51390106359E.pdf |
| _version_ | 1818329857188167680 |
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| author | Elango Kuppanagounder P. |
| author_facet | Elango Kuppanagounder P. |
| author_sort | Elango Kuppanagounder P. |
| collection | DOAJ |
| description | The kinetics of the oxidation of 3-methyl-2,6-diphenyl-piperidin-4-one by
quinolinium fluorochromate (QFC) have been investigated in aqueous solutions
of dimethyl sulphoxide, 1,4-dioxane, tert-butanol and acetone. The influence
of the added co-solvent on the reactivity were analysed in the light of
various simple and multiple regression equations, viz the Laidler-Eyring,
Grunwald-Winstein, Swain and Kamlet-Taft equations. The obtained results
showed that the solvation phenomenon plays a dominant role on the
reactivity. |
| first_indexed | 2024-12-13T12:54:43Z |
| format | Article |
| id | doaj.art-05149112ced642a4983431cf357531fd |
| institution | Directory Open Access Journal |
| issn | 0352-5139 1820-7421 |
| language | English |
| last_indexed | 2024-12-13T12:54:43Z |
| publishDate | 2001-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-05149112ced642a4983431cf357531fd2022-12-21T23:45:13ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212001-01-0166635936510.2298/JSC0106359E0352-51390106359EThe effect of solvent on the kinetics of the oxidation of 3-methyl-2,6-diphenyl-piperidin-4-one by quinolinium fluorochromate in aqueous organic mediaElango Kuppanagounder P.0Gandhigram Rural Institute-Deemed University, Department of Chemistry, Gandhigram, IndiaThe kinetics of the oxidation of 3-methyl-2,6-diphenyl-piperidin-4-one by quinolinium fluorochromate (QFC) have been investigated in aqueous solutions of dimethyl sulphoxide, 1,4-dioxane, tert-butanol and acetone. The influence of the added co-solvent on the reactivity were analysed in the light of various simple and multiple regression equations, viz the Laidler-Eyring, Grunwald-Winstein, Swain and Kamlet-Taft equations. The obtained results showed that the solvation phenomenon plays a dominant role on the reactivity.http://www.doiserbia.nb.rs/img/doi/0352-5139/2001/0352-51390106359E.pdfkineticsoxidationsolvent effect |
| spellingShingle | Elango Kuppanagounder P. The effect of solvent on the kinetics of the oxidation of 3-methyl-2,6-diphenyl-piperidin-4-one by quinolinium fluorochromate in aqueous organic media Journal of the Serbian Chemical Society kinetics oxidation solvent effect |
| title | The effect of solvent on the kinetics of the oxidation of 3-methyl-2,6-diphenyl-piperidin-4-one by quinolinium fluorochromate in aqueous organic media |
| title_full | The effect of solvent on the kinetics of the oxidation of 3-methyl-2,6-diphenyl-piperidin-4-one by quinolinium fluorochromate in aqueous organic media |
| title_fullStr | The effect of solvent on the kinetics of the oxidation of 3-methyl-2,6-diphenyl-piperidin-4-one by quinolinium fluorochromate in aqueous organic media |
| title_full_unstemmed | The effect of solvent on the kinetics of the oxidation of 3-methyl-2,6-diphenyl-piperidin-4-one by quinolinium fluorochromate in aqueous organic media |
| title_short | The effect of solvent on the kinetics of the oxidation of 3-methyl-2,6-diphenyl-piperidin-4-one by quinolinium fluorochromate in aqueous organic media |
| title_sort | effect of solvent on the kinetics of the oxidation of 3 methyl 2 6 diphenyl piperidin 4 one by quinolinium fluorochromate in aqueous organic media |
| topic | kinetics oxidation solvent effect |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2001/0352-51390106359E.pdf |
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