Determinação de ascarel em óleo isolante de transformadores Ascarel determination in insulating oil of transformers

<abstract language="eng">The contamination level of silicon oil used as insulation liquid in high-voltage transformers by ascarel (PCBs) is above those permitted by the Brazilian law. Thus new techniques able to detect ascarel, with low operational costs, are very attractive. The pre...

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Bibliographic Details
Main Authors: Izoldir Antonello, Eduardo Humeres, Ivan Gonçalves de Souza, Nito Angelo Debacher, Alexandre Rios Martins
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2007-06-01
Series:Química Nova
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000300034
Description
Summary:<abstract language="eng">The contamination level of silicon oil used as insulation liquid in high-voltage transformers by ascarel (PCBs) is above those permitted by the Brazilian law. Thus new techniques able to detect ascarel, with low operational costs, are very attractive. The present work proposes an analysis of the contamination levels of silicon oil using the following techniques: naphthalene anion radical reaction for ascarel dechlorination; and potentiometry with an ion-selective electrode for chloride ion determination. The data obtained with the proposed methodology agree well with those from the official methodology, (method IEC 61619).
ISSN:0100-4042
1678-7064