Dichloro(<i>η</i><sup>6</sup>-<i>p</i>-cymene)(<i>P,P</i>-diphenyl-<i>N</i>-propyl-phosphinous amide-<i>κP</i>)ruthenium(II)
The title compound, i.e., [RuCl<sub>2</sub>(<i>η</i><sup>6</sup>-<i>p</i>-cymene)(PPh<sub>2</sub>NH<sup>n</sup>Pr)] (<b>2</b>), was obtained in a 71% yield by reacting a toluene solution of the chlorophosphine comple...
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| Format: | Article |
| Language: | English |
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MDPI AG
2021-05-01
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| Series: | Molbank |
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| Online Access: | https://www.mdpi.com/1422-8599/2021/2/M1217 |
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| author | Rebeca González-Fernández Pascale Crochet Victorio Cadierno |
| author_facet | Rebeca González-Fernández Pascale Crochet Victorio Cadierno |
| author_sort | Rebeca González-Fernández |
| collection | DOAJ |
| description | The title compound, i.e., [RuCl<sub>2</sub>(<i>η</i><sup>6</sup>-<i>p</i>-cymene)(PPh<sub>2</sub>NH<sup>n</sup>Pr)] (<b>2</b>), was obtained in a 71% yield by reacting a toluene solution of the chlorophosphine complex [RuCl<sub>2</sub>(<i>η</i><sup>6</sup>-<i>p</i>-cymene)(PPh<sub>2</sub>Cl)] (<b>1</b>) with two equivalents of <i>n</i>-propylamine at room temperature. The aminophosphine complex <b>2</b> was characterized by elemental analysis, multinuclear NMR (<sup>31</sup>P{<sup>1</sup>H}, <sup>1</sup>H and <sup>13</sup>C{<sup>1</sup>H}) and IR spectroscopy. In addition, its catalytic behavior in the hydration of benzonitrile was briefly explored. |
| first_indexed | 2024-03-10T10:57:10Z |
| format | Article |
| id | doaj.art-051ad6b5c83f42afb48a1a2540264d8f |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-03-10T10:57:10Z |
| publishDate | 2021-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-051ad6b5c83f42afb48a1a2540264d8f2023-11-21T21:45:49ZengMDPI AGMolbank1422-85992021-05-0120212M121710.3390/M1217Dichloro(<i>η</i><sup>6</sup>-<i>p</i>-cymene)(<i>P,P</i>-diphenyl-<i>N</i>-propyl-phosphinous amide-<i>κP</i>)ruthenium(II)Rebeca González-Fernández0Pascale Crochet1Victorio Cadierno2Departamento de Química Orgánica e Inorgánica, Facultad de Química, Universidad de Oviedo, Julián Clavería 8, E-33006 Oviedo, SpainDepartamento de Química Orgánica e Inorgánica, Facultad de Química, Universidad de Oviedo, Julián Clavería 8, E-33006 Oviedo, SpainDepartamento de Química Orgánica e Inorgánica, Facultad de Química, Universidad de Oviedo, Julián Clavería 8, E-33006 Oviedo, SpainThe title compound, i.e., [RuCl<sub>2</sub>(<i>η</i><sup>6</sup>-<i>p</i>-cymene)(PPh<sub>2</sub>NH<sup>n</sup>Pr)] (<b>2</b>), was obtained in a 71% yield by reacting a toluene solution of the chlorophosphine complex [RuCl<sub>2</sub>(<i>η</i><sup>6</sup>-<i>p</i>-cymene)(PPh<sub>2</sub>Cl)] (<b>1</b>) with two equivalents of <i>n</i>-propylamine at room temperature. The aminophosphine complex <b>2</b> was characterized by elemental analysis, multinuclear NMR (<sup>31</sup>P{<sup>1</sup>H}, <sup>1</sup>H and <sup>13</sup>C{<sup>1</sup>H}) and IR spectroscopy. In addition, its catalytic behavior in the hydration of benzonitrile was briefly explored.https://www.mdpi.com/1422-8599/2021/2/M1217aminophosphinesrutheniumhalf-sandwich complexeschlorophosphinesnitrile hydration |
| spellingShingle | Rebeca González-Fernández Pascale Crochet Victorio Cadierno Dichloro(<i>η</i><sup>6</sup>-<i>p</i>-cymene)(<i>P,P</i>-diphenyl-<i>N</i>-propyl-phosphinous amide-<i>κP</i>)ruthenium(II) Molbank aminophosphines ruthenium half-sandwich complexes chlorophosphines nitrile hydration |
| title | Dichloro(<i>η</i><sup>6</sup>-<i>p</i>-cymene)(<i>P,P</i>-diphenyl-<i>N</i>-propyl-phosphinous amide-<i>κP</i>)ruthenium(II) |
| title_full | Dichloro(<i>η</i><sup>6</sup>-<i>p</i>-cymene)(<i>P,P</i>-diphenyl-<i>N</i>-propyl-phosphinous amide-<i>κP</i>)ruthenium(II) |
| title_fullStr | Dichloro(<i>η</i><sup>6</sup>-<i>p</i>-cymene)(<i>P,P</i>-diphenyl-<i>N</i>-propyl-phosphinous amide-<i>κP</i>)ruthenium(II) |
| title_full_unstemmed | Dichloro(<i>η</i><sup>6</sup>-<i>p</i>-cymene)(<i>P,P</i>-diphenyl-<i>N</i>-propyl-phosphinous amide-<i>κP</i>)ruthenium(II) |
| title_short | Dichloro(<i>η</i><sup>6</sup>-<i>p</i>-cymene)(<i>P,P</i>-diphenyl-<i>N</i>-propyl-phosphinous amide-<i>κP</i>)ruthenium(II) |
| title_sort | dichloro i η i sup 6 sup i p i cymene i p p i diphenyl i n i propyl phosphinous amide i κp i ruthenium ii |
| topic | aminophosphines ruthenium half-sandwich complexes chlorophosphines nitrile hydration |
| url | https://www.mdpi.com/1422-8599/2021/2/M1217 |
| work_keys_str_mv | AT rebecagonzalezfernandez dichloroiēisup6supipicymeneippidiphenylinipropylphosphinousamideikpirutheniumii AT pascalecrochet dichloroiēisup6supipicymeneippidiphenylinipropylphosphinousamideikpirutheniumii AT victoriocadierno dichloroiēisup6supipicymeneippidiphenylinipropylphosphinousamideikpirutheniumii |