Assessing the Effects of Different Process Parameters on the Pyrolysis Behaviors and Thermal Dynamics of Corncob Fractions
The influence of heating rate, gas flow, and biomass particle size on the pyrolysis and thermal dynamics of corncobs (CC) was investigated experimentally using the quantitative method of thermogravimetric analysis (TGA) coupled with mass spectrometry (MS), and the obtained results were compared in d...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
North Carolina State University
2017-02-01
|
Series: | BioResources |
Subjects: | |
Online Access: | https://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_12_2_2748_Yao_Different_Process_Parameters_Pyrolysis |
_version_ | 1828971900252979200 |
---|---|
author | Xiwen Yao Kaili Xu Yu Liang |
author_facet | Xiwen Yao Kaili Xu Yu Liang |
author_sort | Xiwen Yao |
collection | DOAJ |
description | The influence of heating rate, gas flow, and biomass particle size on the pyrolysis and thermal dynamics of corncobs (CC) was investigated experimentally using the quantitative method of thermogravimetric analysis (TGA) coupled with mass spectrometry (MS), and the obtained results were compared in depth. For the examined heating rates of 5, 10, and 20 °C/min, the CC pyrolysis at higher heating rates resulted in a more complete decomposition. The initial pyrolysis temperature decreased when gas flow was increased from 30 to 90 mL/min, whereas the weight loss increased. Particle sizes (d ≤ 74 μm, 74 μm < d ≤ 154 μm, 154 μm < d ≤ 280 μm, and 280 μm < d ≤ 450 μm) had pronounced effects on the thermal decomposition and bio-syngas compounds (CO, CO2, CH4, and H2) distribution. The emission intensities of most the gaseous products increased at the elevated heating rate, while they decreased with increasing gas flow. In sum, the pyrolysis of CC particles of 154 μm < d ≤ 280 μm under 20 °C/min and in a gas flow of 30 to 60 mL/min was the most appropriate for bio-syngas production in industrial applications. |
first_indexed | 2024-12-14T13:18:19Z |
format | Article |
id | doaj.art-0523895ac21547779c170c937d5fb89d |
institution | Directory Open Access Journal |
issn | 1930-2126 1930-2126 |
language | English |
last_indexed | 2024-12-14T13:18:19Z |
publishDate | 2017-02-01 |
publisher | North Carolina State University |
record_format | Article |
series | BioResources |
spelling | doaj.art-0523895ac21547779c170c937d5fb89d2022-12-21T22:59:59ZengNorth Carolina State UniversityBioResources1930-21261930-21262017-02-0112227482767Assessing the Effects of Different Process Parameters on the Pyrolysis Behaviors and Thermal Dynamics of Corncob FractionsXiwen Yao0Kaili Xu1Yu Liang2School of Resources and Civil Engineering; Northeastern University; ChinaSchool of Resources and Civil Engineering; Northeastern University; ChinaCollege of Information Science and Engineering; Northeastern University; ChinaThe influence of heating rate, gas flow, and biomass particle size on the pyrolysis and thermal dynamics of corncobs (CC) was investigated experimentally using the quantitative method of thermogravimetric analysis (TGA) coupled with mass spectrometry (MS), and the obtained results were compared in depth. For the examined heating rates of 5, 10, and 20 °C/min, the CC pyrolysis at higher heating rates resulted in a more complete decomposition. The initial pyrolysis temperature decreased when gas flow was increased from 30 to 90 mL/min, whereas the weight loss increased. Particle sizes (d ≤ 74 μm, 74 μm < d ≤ 154 μm, 154 μm < d ≤ 280 μm, and 280 μm < d ≤ 450 μm) had pronounced effects on the thermal decomposition and bio-syngas compounds (CO, CO2, CH4, and H2) distribution. The emission intensities of most the gaseous products increased at the elevated heating rate, while they decreased with increasing gas flow. In sum, the pyrolysis of CC particles of 154 μm < d ≤ 280 μm under 20 °C/min and in a gas flow of 30 to 60 mL/min was the most appropriate for bio-syngas production in industrial applications.https://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_12_2_2748_Yao_Different_Process_Parameters_PyrolysisCorncob; Pyrolysis; Heating rate; Gas Flow; Particle Size; Thermal Dynamics; Bio-syngas |
spellingShingle | Xiwen Yao Kaili Xu Yu Liang Assessing the Effects of Different Process Parameters on the Pyrolysis Behaviors and Thermal Dynamics of Corncob Fractions BioResources Corncob; Pyrolysis; Heating rate; Gas Flow; Particle Size; Thermal Dynamics; Bio-syngas |
title | Assessing the Effects of Different Process Parameters on the Pyrolysis Behaviors and Thermal Dynamics of Corncob Fractions |
title_full | Assessing the Effects of Different Process Parameters on the Pyrolysis Behaviors and Thermal Dynamics of Corncob Fractions |
title_fullStr | Assessing the Effects of Different Process Parameters on the Pyrolysis Behaviors and Thermal Dynamics of Corncob Fractions |
title_full_unstemmed | Assessing the Effects of Different Process Parameters on the Pyrolysis Behaviors and Thermal Dynamics of Corncob Fractions |
title_short | Assessing the Effects of Different Process Parameters on the Pyrolysis Behaviors and Thermal Dynamics of Corncob Fractions |
title_sort | assessing the effects of different process parameters on the pyrolysis behaviors and thermal dynamics of corncob fractions |
topic | Corncob; Pyrolysis; Heating rate; Gas Flow; Particle Size; Thermal Dynamics; Bio-syngas |
url | https://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_12_2_2748_Yao_Different_Process_Parameters_Pyrolysis |
work_keys_str_mv | AT xiwenyao assessingtheeffectsofdifferentprocessparametersonthepyrolysisbehaviorsandthermaldynamicsofcorncobfractions AT kailixu assessingtheeffectsofdifferentprocessparametersonthepyrolysisbehaviorsandthermaldynamicsofcorncobfractions AT yuliang assessingtheeffectsofdifferentprocessparametersonthepyrolysisbehaviorsandthermaldynamicsofcorncobfractions |