Mechanistic study of oxidation of d-arabinose by N-bromophthalimide in presence of micro-amount of chloro-complex of Ru(III) as a homogeneous catalyst

Mechanistic study of oxidation of d-arabinose by N-bromophthalimide in presence of micro-amount of chloro-complex of Ru(III) as a homogeneous catalyst

The kinetics and mechanism of Ru(III)-catalyzed oxidation of d-arabinose (d-Ara) by N-bromophthalimide (NBP) in a acidic medium were investigated using titrimetric method for the redox reaction in the temperature range of 303–323 K. The reaction was first order with respect to [NBP] and [Ru(III)]. I...

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Bibliographic Details
Main Authors: Neerja Sachdev, Ajaya Kumar Singh, Alpa Shrivastava, Yokraj Katre, Aftab Aslam Parwaz Khan
Format: Article
Language:English
Published: Elsevier 2017-11-01
Series:Arabian Journal of Chemistry
Subjects:
Kinetics
Oxidation
N-bromophthalimide
d-Arabinose
Ru(III) chloride
Phthalimide (NHP)
Online Access:http://www.sciencedirect.com/science/article/pii/S187853521400183X

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