Influence of Al and N Content and Cooling Rate on the Characteristics of Complex MnS Inclusions in AHSS

This study focused on the characteristics of complex MnS inclusions in advanced high strength steels. The effect of metal chemistry (Al and N) and the cooling rate of steel were evaluated by analyzing the inclusions present in five laboratory produced steels. The observed complex MnS inclusions cont...

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Main Authors: Muhammad Nabeel, Michelia Alba, Neslihan Dogan
Format: Article
Language:English
Published: MDPI AG 2020-11-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/10/11/1054
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author Muhammad Nabeel
Michelia Alba
Neslihan Dogan
author_facet Muhammad Nabeel
Michelia Alba
Neslihan Dogan
author_sort Muhammad Nabeel
collection DOAJ
description This study focused on the characteristics of complex MnS inclusions in advanced high strength steels. The effect of metal chemistry (Al and N) and the cooling rate of steel were evaluated by analyzing the inclusions present in five laboratory produced steels. The observed complex MnS inclusions contained Al<sub>2</sub>O<sub>3</sub>-MnS, AlN-MnS, and AlON-MnS. An increase in Al content from 0.5% to 6% increased the number of complex MnS inclusions by ~4 times. In comparison, a decrease of ~80% was observed due to the increased N content of steel from <10 ppm to ~50 ppm. MnS precipitation ratio was used to determine the potency of different inclusions forming complex MnS inclusions due to heterogeneous nucleation. It was found that the MnS precipitation ratio of the observed inclusions was related to their misfit with MnS, and it decreased in the order of AlN > AlON > Al<sub>2</sub>O<sub>3</sub>. Moreover, it was determined that AlN particles could be easily engulfed at the solidification front relative to Al<sub>2</sub>O<sub>3</sub>, which resulted in a higher MnS precipitation ratio for Al<sub>2</sub>O<sub>3</sub> under slow cooling conditions.
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spelling doaj.art-057d97417cfa4ae79920d5b0b86211e22023-11-20T21:34:50ZengMDPI AGCrystals2073-43522020-11-011011105410.3390/cryst10111054Influence of Al and N Content and Cooling Rate on the Characteristics of Complex MnS Inclusions in AHSSMuhammad Nabeel0Michelia Alba1Neslihan Dogan2Department of Material Science and Engineering, Faculty of Engineering, McMaster University, 1280 Main Street West, Hamilton, ON L8S 4L7, CanadaDepartment of Material Science and Engineering, Faculty of Engineering, McMaster University, 1280 Main Street West, Hamilton, ON L8S 4L7, CanadaDepartment of Material Science and Engineering, Faculty of Engineering, McMaster University, 1280 Main Street West, Hamilton, ON L8S 4L7, CanadaThis study focused on the characteristics of complex MnS inclusions in advanced high strength steels. The effect of metal chemistry (Al and N) and the cooling rate of steel were evaluated by analyzing the inclusions present in five laboratory produced steels. The observed complex MnS inclusions contained Al<sub>2</sub>O<sub>3</sub>-MnS, AlN-MnS, and AlON-MnS. An increase in Al content from 0.5% to 6% increased the number of complex MnS inclusions by ~4 times. In comparison, a decrease of ~80% was observed due to the increased N content of steel from <10 ppm to ~50 ppm. MnS precipitation ratio was used to determine the potency of different inclusions forming complex MnS inclusions due to heterogeneous nucleation. It was found that the MnS precipitation ratio of the observed inclusions was related to their misfit with MnS, and it decreased in the order of AlN > AlON > Al<sub>2</sub>O<sub>3</sub>. Moreover, it was determined that AlN particles could be easily engulfed at the solidification front relative to Al<sub>2</sub>O<sub>3</sub>, which resulted in a higher MnS precipitation ratio for Al<sub>2</sub>O<sub>3</sub> under slow cooling conditions.https://www.mdpi.com/2073-4352/10/11/1054complex MnSheterogeneous nucleationprecipitation ratioengulfment and pushingmisfitAlN inclusions
spellingShingle Muhammad Nabeel
Michelia Alba
Neslihan Dogan
Influence of Al and N Content and Cooling Rate on the Characteristics of Complex MnS Inclusions in AHSS
Crystals
complex MnS
heterogeneous nucleation
precipitation ratio
engulfment and pushing
misfit
AlN inclusions
title Influence of Al and N Content and Cooling Rate on the Characteristics of Complex MnS Inclusions in AHSS
title_full Influence of Al and N Content and Cooling Rate on the Characteristics of Complex MnS Inclusions in AHSS
title_fullStr Influence of Al and N Content and Cooling Rate on the Characteristics of Complex MnS Inclusions in AHSS
title_full_unstemmed Influence of Al and N Content and Cooling Rate on the Characteristics of Complex MnS Inclusions in AHSS
title_short Influence of Al and N Content and Cooling Rate on the Characteristics of Complex MnS Inclusions in AHSS
title_sort influence of al and n content and cooling rate on the characteristics of complex mns inclusions in ahss
topic complex MnS
heterogeneous nucleation
precipitation ratio
engulfment and pushing
misfit
AlN inclusions
url https://www.mdpi.com/2073-4352/10/11/1054
work_keys_str_mv AT muhammadnabeel influenceofalandncontentandcoolingrateonthecharacteristicsofcomplexmnsinclusionsinahss
AT micheliaalba influenceofalandncontentandcoolingrateonthecharacteristicsofcomplexmnsinclusionsinahss
AT neslihandogan influenceofalandncontentandcoolingrateonthecharacteristicsofcomplexmnsinclusionsinahss