Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ2N2,S}nickel(II): crystal structure and Hirshfeld surface analysis
The complete molecule of the title hydrazine carbodithioate complex, [Ni(C19H21N2S2)2], is generated by the application of a centre of inversion. The NiII atom is N,S-chelated by two hydrazinecarbodithioate ligands, which provide a trans-N2S2 donor set that defines a distorted square-planar geometry...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-03-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989017002419 |
| _version_ | 1819002303308365824 |
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| author | Enis Nadia Md Yusof Thahira B. S. A. Ravoof Mohamed I. M. Tahir Mukesh M. Jotani Edward R. T. Tiekink |
| author_facet | Enis Nadia Md Yusof Thahira B. S. A. Ravoof Mohamed I. M. Tahir Mukesh M. Jotani Edward R. T. Tiekink |
| author_sort | Enis Nadia Md Yusof |
| collection | DOAJ |
| description | The complete molecule of the title hydrazine carbodithioate complex, [Ni(C19H21N2S2)2], is generated by the application of a centre of inversion. The NiII atom is N,S-chelated by two hydrazinecarbodithioate ligands, which provide a trans-N2S2 donor set that defines a distorted square-planar geometry. The conformation of the five-membered chelate ring is an envelope with the NiII atom being the flap atom. In the crystal, p-tolyl-C—H...π(benzene-iPr), iPr-C—H...π(p-tolyl) and π–π interactions [between p-tolyl rings with inter-centroid distance = 3.8051 (12) Å] help to consolidate the three-dimensional architecture. The analysis of the Hirshfeld surface confirms the importance of H-atom contacts in establishing the packing. |
| first_indexed | 2024-12-20T23:02:58Z |
| format | Article |
| id | doaj.art-058afa7c9766466ea4d4acbb61468485 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T23:02:58Z |
| publishDate | 2017-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-058afa7c9766466ea4d4acbb614684852022-12-21T19:23:56ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-03-0173339740210.1107/S2056989017002419hb7658Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ2N2,S}nickel(II): crystal structure and Hirshfeld surface analysisEnis Nadia Md Yusof0Thahira B. S. A. Ravoof1Mohamed I. M. Tahir2Mukesh M. Jotani3Edward R. T. Tiekink4Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400, UPM Serdang, Selangor Darul Ehsan, MalaysiaDepartment of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400, UPM Serdang, Selangor Darul Ehsan, MalaysiaDepartment of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400, UPM Serdang, Selangor Darul Ehsan, MalaysiaDepartment of Physics, Bhavan's Sheth R. A. College of Science, Ahmedabad, Gujarat 380001, IndiaResearch Centre for Crystalline Materials, School of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, MalaysiaThe complete molecule of the title hydrazine carbodithioate complex, [Ni(C19H21N2S2)2], is generated by the application of a centre of inversion. The NiII atom is N,S-chelated by two hydrazinecarbodithioate ligands, which provide a trans-N2S2 donor set that defines a distorted square-planar geometry. The conformation of the five-membered chelate ring is an envelope with the NiII atom being the flap atom. In the crystal, p-tolyl-C—H...π(benzene-iPr), iPr-C—H...π(p-tolyl) and π–π interactions [between p-tolyl rings with inter-centroid distance = 3.8051 (12) Å] help to consolidate the three-dimensional architecture. The analysis of the Hirshfeld surface confirms the importance of H-atom contacts in establishing the packing.http://scripts.iucr.org/cgi-bin/paper?S2056989017002419crystal structurenickel(II)hydrazine carbodithioateHirshfeld surface analysis |
| spellingShingle | Enis Nadia Md Yusof Thahira B. S. A. Ravoof Mohamed I. M. Tahir Mukesh M. Jotani Edward R. T. Tiekink Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ2N2,S}nickel(II): crystal structure and Hirshfeld surface analysis Acta Crystallographica Section E: Crystallographic Communications crystal structure nickel(II) hydrazine carbodithioate Hirshfeld surface analysis |
| title | Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ2N2,S}nickel(II): crystal structure and Hirshfeld surface analysis |
| title_full | Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ2N2,S}nickel(II): crystal structure and Hirshfeld surface analysis |
| title_fullStr | Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ2N2,S}nickel(II): crystal structure and Hirshfeld surface analysis |
| title_full_unstemmed | Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ2N2,S}nickel(II): crystal structure and Hirshfeld surface analysis |
| title_short | Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzylidene]hydrazinecarbodithioato-κ2N2,S}nickel(II): crystal structure and Hirshfeld surface analysis |
| title_sort | bis 4 methylbenzyl 2 4 propan 2 yl benzylidene hydrazinecarbodithioato κ2n2 s nickel ii crystal structure and hirshfeld surface analysis |
| topic | crystal structure nickel(II) hydrazine carbodithioate Hirshfeld surface analysis |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989017002419 |
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