Preparation and Properties of UV-Curable Waterborne Polyurethane Acrylate/MXene Nanocomposite Films

In this study, waterborne polyurethane acrylate (WPUA)/MXene nanocomposite films with varying MXene loadings were fabricated using UV-curing technology, where MXene (Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>) was employed as a nanofiller. The microstructure and che...

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Main Authors: Ying Wang, Shuai Zhang, Yanli Lin, Qianyi Wang, Ying Zhang, Changmei Sun, Rongjun Qu
Format: Article
Language:English
Published: MDPI AG 2023-11-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/13/23/3022
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author Ying Wang
Shuai Zhang
Yanli Lin
Qianyi Wang
Ying Zhang
Changmei Sun
Rongjun Qu
author_facet Ying Wang
Shuai Zhang
Yanli Lin
Qianyi Wang
Ying Zhang
Changmei Sun
Rongjun Qu
author_sort Ying Wang
collection DOAJ
description In this study, waterborne polyurethane acrylate (WPUA)/MXene nanocomposite films with varying MXene loadings were fabricated using UV-curing technology, where MXene (Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>) was employed as a nanofiller. The microstructure and chemical structure of the WPUA/MXene nanocomposite films were examined by XRD and FTIR, respectively. The water contact angle testing demonstrated that the incorporation of MXene into the nanocomposite films led to an increase in their hydrophilic properties. The tensile strength, the elongation at break, and Young’s modulus of the WPUA/MXene nanocomposite coatings exhibited an initial increase followed by a decrease with increasing MXene loadings. Compared to the pure WPUA film, the tensile strength and elongation at break of nanocomposites with 0.077 wt% MXene loading reached their maximum values, which increased by 39.9% and 38.5%, respectively. Furthermore, the glass transition temperature and the thermal stability were both enhanced by MXene to some extent. This study introduces a novel method for utilizing MXene in UV-curable waterborne coatings.
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spelling doaj.art-05a083e4ddc840bdaf3364862cc385862023-12-08T15:22:55ZengMDPI AGNanomaterials2079-49912023-11-011323302210.3390/nano13233022Preparation and Properties of UV-Curable Waterborne Polyurethane Acrylate/MXene Nanocomposite FilmsYing Wang0Shuai Zhang1Yanli Lin2Qianyi Wang3Ying Zhang4Changmei Sun5Rongjun Qu6School of Chemistry and Materials Science, Ludong University, Yantai 264025, ChinaSchool of Chemistry and Materials Science, Ludong University, Yantai 264025, ChinaSchool of Chemistry and Materials Science, Ludong University, Yantai 264025, ChinaSchool of Chemistry and Materials Science, Ludong University, Yantai 264025, ChinaSchool of Chemistry and Materials Science, Ludong University, Yantai 264025, ChinaSchool of Chemistry and Materials Science, Ludong University, Yantai 264025, ChinaSchool of Chemistry and Materials Science, Ludong University, Yantai 264025, ChinaIn this study, waterborne polyurethane acrylate (WPUA)/MXene nanocomposite films with varying MXene loadings were fabricated using UV-curing technology, where MXene (Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>) was employed as a nanofiller. The microstructure and chemical structure of the WPUA/MXene nanocomposite films were examined by XRD and FTIR, respectively. The water contact angle testing demonstrated that the incorporation of MXene into the nanocomposite films led to an increase in their hydrophilic properties. The tensile strength, the elongation at break, and Young’s modulus of the WPUA/MXene nanocomposite coatings exhibited an initial increase followed by a decrease with increasing MXene loadings. Compared to the pure WPUA film, the tensile strength and elongation at break of nanocomposites with 0.077 wt% MXene loading reached their maximum values, which increased by 39.9% and 38.5%, respectively. Furthermore, the glass transition temperature and the thermal stability were both enhanced by MXene to some extent. This study introduces a novel method for utilizing MXene in UV-curable waterborne coatings.https://www.mdpi.com/2079-4991/13/23/3022waterborne polyurethane acrylateMXeneUV-curablenanocomposite films
spellingShingle Ying Wang
Shuai Zhang
Yanli Lin
Qianyi Wang
Ying Zhang
Changmei Sun
Rongjun Qu
Preparation and Properties of UV-Curable Waterborne Polyurethane Acrylate/MXene Nanocomposite Films
Nanomaterials
waterborne polyurethane acrylate
MXene
UV-curable
nanocomposite films
title Preparation and Properties of UV-Curable Waterborne Polyurethane Acrylate/MXene Nanocomposite Films
title_full Preparation and Properties of UV-Curable Waterborne Polyurethane Acrylate/MXene Nanocomposite Films
title_fullStr Preparation and Properties of UV-Curable Waterborne Polyurethane Acrylate/MXene Nanocomposite Films
title_full_unstemmed Preparation and Properties of UV-Curable Waterborne Polyurethane Acrylate/MXene Nanocomposite Films
title_short Preparation and Properties of UV-Curable Waterborne Polyurethane Acrylate/MXene Nanocomposite Films
title_sort preparation and properties of uv curable waterborne polyurethane acrylate mxene nanocomposite films
topic waterborne polyurethane acrylate
MXene
UV-curable
nanocomposite films
url https://www.mdpi.com/2079-4991/13/23/3022
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