Diphenyl [(S)-1-phenylpropanamido]phosphate
The title compound, C21H22NO3P, was synthesized from the reaction of (C6H5O)2P(O)(Cl) and S-1-phenylpropylamine (1:2 mole ratio) at 273 K, followed by removal of the S-1-phenylpropylamine hydrochloride by-product by dissolving in H2O. The P atom is located in a distorted tetrahedral en...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811034507 |
| _version_ | 1798026891829968896 |
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| author | Fahimeh Sabbaghi Mehrdad Pourayoubi Monireh Negari Marek Nečas |
| author_facet | Fahimeh Sabbaghi Mehrdad Pourayoubi Monireh Negari Marek Nečas |
| author_sort | Fahimeh Sabbaghi |
| collection | DOAJ |
| description | The title compound, C21H22NO3P, was synthesized from the reaction of (C6H5O)2P(O)(Cl) and S-1-phenylpropylamine (1:2 mole ratio) at 273 K, followed by removal of the S-1-phenylpropylamine hydrochloride by-product by dissolving in H2O. The P atom is located in a distorted tetrahedral environment. The bond angles at the P atom vary from 99.51 (12) to 116.68 (12)°. The sp2 character of the N atom is reflected by the C—N—P angle [120.9 (2)°]. The P=O group and the N—H unit adopt an anti orientation with respect to one another. In the crystal, adjacent molecules are linked via N—H...O(P) hydrogen bonds into a one-dimensional arrangement running parallel to the a axis. |
| first_indexed | 2024-04-11T18:42:34Z |
| format | Article |
| id | doaj.art-05a8943cdc3540dcb7f1b38ee3cf43af |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:42:34Z |
| publishDate | 2011-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-05a8943cdc3540dcb7f1b38ee3cf43af2022-12-22T04:08:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-09-01679o2512o251210.1107/S1600536811034507Diphenyl [(S)-1-phenylpropanamido]phosphateFahimeh SabbaghiMehrdad PourayoubiMonireh NegariMarek NečasThe title compound, C21H22NO3P, was synthesized from the reaction of (C6H5O)2P(O)(Cl) and S-1-phenylpropylamine (1:2 mole ratio) at 273 K, followed by removal of the S-1-phenylpropylamine hydrochloride by-product by dissolving in H2O. The P atom is located in a distorted tetrahedral environment. The bond angles at the P atom vary from 99.51 (12) to 116.68 (12)°. The sp2 character of the N atom is reflected by the C—N—P angle [120.9 (2)°]. The P=O group and the N—H unit adopt an anti orientation with respect to one another. In the crystal, adjacent molecules are linked via N—H...O(P) hydrogen bonds into a one-dimensional arrangement running parallel to the a axis.http://scripts.iucr.org/cgi-bin/paper?S1600536811034507 |
| spellingShingle | Fahimeh Sabbaghi Mehrdad Pourayoubi Monireh Negari Marek Nečas Diphenyl [(S)-1-phenylpropanamido]phosphate Acta Crystallographica Section E |
| title | Diphenyl [(S)-1-phenylpropanamido]phosphate |
| title_full | Diphenyl [(S)-1-phenylpropanamido]phosphate |
| title_fullStr | Diphenyl [(S)-1-phenylpropanamido]phosphate |
| title_full_unstemmed | Diphenyl [(S)-1-phenylpropanamido]phosphate |
| title_short | Diphenyl [(S)-1-phenylpropanamido]phosphate |
| title_sort | diphenyl s 1 phenylpropanamido phosphate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811034507 |
| work_keys_str_mv | AT fahimehsabbaghi diphenyls1phenylpropanamidophosphate AT mehrdadpourayoubi diphenyls1phenylpropanamidophosphate AT monirehnegari diphenyls1phenylpropanamidophosphate AT marekneamp269as diphenyls1phenylpropanamidophosphate |