Thermal conductivity of plasma modified polyethylene terephthalate and polyamide-6 layers

Tribological performance of the materials greatly depends on the temperature of the contacting zones and surfaces and hence on the heat conducting behaviour of the materials. Heat conduction of polymers is, however, greatly affected even by a very narrow (few tens of nm) modified layer formed on the...

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Main Authors: G. Kalacska, R. Keresztes, L. Foldi, Sz. Klebert, Z. Karoly, L. Zsidai
Format: Article
Language:English
Published: Budapest University of Technology 2016-05-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0006725&mi=cd
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author G. Kalacska
R. Keresztes
L. Foldi
Sz. Klebert
Z. Karoly
L. Zsidai
author_facet G. Kalacska
R. Keresztes
L. Foldi
Sz. Klebert
Z. Karoly
L. Zsidai
author_sort G. Kalacska
collection DOAJ
description Tribological performance of the materials greatly depends on the temperature of the contacting zones and surfaces and hence on the heat conducting behaviour of the materials. Heat conduction of polymers is, however, greatly affected even by a very narrow (few tens of nm) modified layer formed on the surface after subjecting the polymer to plasma treatment. In this article the heat flow inhibiting properties of plasma modified surface layers were investigated on polyethylene terephthalate (PET) and polyamide-6 (PA6) engineering polymers. Nitrogen Plasma Immersion Ion Implantation gave rise to compositional and structural changes of the polymers in a depth of 110 nm. It was found that even this thin layer exhibited significant heat flow inhibiting effect. The modified layer considerably decreased the thermal conductivity coefficient of the treated polymer and resulted in a reduced heat transmission for PET and PA6 by 33 and 28%, respectively. This new information supports and is in accordance with the former tribological results about extra friction heat generation experienced under NPIII surface layer of PA6 and PET during dry sliding.
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spelling doaj.art-05c3d221f62746be90335aa618bc7d812022-12-21T23:13:29ZengBudapest University of TechnologyeXPRESS Polymer Letters1788-618X2016-05-0110537338010.3144/expresspolymlett.2016.35Thermal conductivity of plasma modified polyethylene terephthalate and polyamide-6 layersG. KalacskaR. KeresztesL. FoldiSz. KlebertZ. KarolyL. ZsidaiTribological performance of the materials greatly depends on the temperature of the contacting zones and surfaces and hence on the heat conducting behaviour of the materials. Heat conduction of polymers is, however, greatly affected even by a very narrow (few tens of nm) modified layer formed on the surface after subjecting the polymer to plasma treatment. In this article the heat flow inhibiting properties of plasma modified surface layers were investigated on polyethylene terephthalate (PET) and polyamide-6 (PA6) engineering polymers. Nitrogen Plasma Immersion Ion Implantation gave rise to compositional and structural changes of the polymers in a depth of 110 nm. It was found that even this thin layer exhibited significant heat flow inhibiting effect. The modified layer considerably decreased the thermal conductivity coefficient of the treated polymer and resulted in a reduced heat transmission for PET and PA6 by 33 and 28%, respectively. This new information supports and is in accordance with the former tribological results about extra friction heat generation experienced under NPIII surface layer of PA6 and PET during dry sliding.http://www.expresspolymlett.com/letolt.php?file=EPL-0006725&mi=cdAdhesionion implantationtribologythermal conductivitysurfaces
spellingShingle G. Kalacska
R. Keresztes
L. Foldi
Sz. Klebert
Z. Karoly
L. Zsidai
Thermal conductivity of plasma modified polyethylene terephthalate and polyamide-6 layers
eXPRESS Polymer Letters
Adhesion
ion implantation
tribology
thermal conductivity
surfaces
title Thermal conductivity of plasma modified polyethylene terephthalate and polyamide-6 layers
title_full Thermal conductivity of plasma modified polyethylene terephthalate and polyamide-6 layers
title_fullStr Thermal conductivity of plasma modified polyethylene terephthalate and polyamide-6 layers
title_full_unstemmed Thermal conductivity of plasma modified polyethylene terephthalate and polyamide-6 layers
title_short Thermal conductivity of plasma modified polyethylene terephthalate and polyamide-6 layers
title_sort thermal conductivity of plasma modified polyethylene terephthalate and polyamide 6 layers
topic Adhesion
ion implantation
tribology
thermal conductivity
surfaces
url http://www.expresspolymlett.com/letolt.php?file=EPL-0006725&mi=cd
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AT lfoldi thermalconductivityofplasmamodifiedpolyethyleneterephthalateandpolyamide6layers
AT szklebert thermalconductivityofplasmamodifiedpolyethyleneterephthalateandpolyamide6layers
AT zkaroly thermalconductivityofplasmamodifiedpolyethyleneterephthalateandpolyamide6layers
AT lzsidai thermalconductivityofplasmamodifiedpolyethyleneterephthalateandpolyamide6layers