Thermoelectric Efficiency of Silicon–Germanium Alloys in Finite-Time Thermodynamics

We analyze the efficiency in terms of a thermoelectric system of a one-dimensional Silicon–Germanium alloy. The dependency of thermal conductivity on the stoichiometry is pointed out, and the best fit of the experimental data is determined by a nonlinear regression method (NLRM). The thermoelectric...

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Main Authors: Patrizia Rogolino, Vito Antonio Cimmelli
Format: Article
Language:English
Published: MDPI AG 2020-10-01
Series:Entropy
Subjects:
Online Access:https://www.mdpi.com/1099-4300/22/10/1116
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author Patrizia Rogolino
Vito Antonio Cimmelli
author_facet Patrizia Rogolino
Vito Antonio Cimmelli
author_sort Patrizia Rogolino
collection DOAJ
description We analyze the efficiency in terms of a thermoelectric system of a one-dimensional Silicon–Germanium alloy. The dependency of thermal conductivity on the stoichiometry is pointed out, and the best fit of the experimental data is determined by a nonlinear regression method (NLRM). The thermoelectric efficiency of that system as function of the composition and of the effective temperature gradient is calculated as well. For three different temperatures (<inline-formula><math display="inline"><semantics><mrow><mi>T</mi><mo>=</mo><mn>300</mn><mtext> </mtext><mi mathvariant="normal">K</mi></mrow></semantics></math></inline-formula>, <inline-formula><math display="inline"><semantics><mrow><mi>T</mi><mo>=</mo><mn>400</mn><mtext> </mtext><mi mathvariant="normal">K</mi></mrow></semantics></math></inline-formula>, <inline-formula><math display="inline"><semantics><mrow><mi>T</mi><mo>=</mo><mn>500</mn><mtext> </mtext><mi mathvariant="normal">K</mi></mrow></semantics></math></inline-formula>), we determine the values of composition and thermal conductivity corresponding to the optimal thermoelectric energy conversion. The relationship of our approach with Finite-Time Thermodynamics is pointed out.
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spelling doaj.art-05f01d2991ee416cb78bbdc6f5cd32312023-11-20T15:55:33ZengMDPI AGEntropy1099-43002020-10-012210111610.3390/e22101116Thermoelectric Efficiency of Silicon–Germanium Alloys in Finite-Time ThermodynamicsPatrizia Rogolino0Vito Antonio Cimmelli1Department of Mathematical and Computer Sciences, Physical Sciences and Earth Sciences, University of Messina, Viale F. Stagno d’Alcontres, 31, 98166 Messina, ItalyDepartment of Mathematics, Computer Science and Economics, University of Basilicata, Viale dell’Ateneo Lucano, 10, 85100 Potenza, ItalyWe analyze the efficiency in terms of a thermoelectric system of a one-dimensional Silicon–Germanium alloy. The dependency of thermal conductivity on the stoichiometry is pointed out, and the best fit of the experimental data is determined by a nonlinear regression method (NLRM). The thermoelectric efficiency of that system as function of the composition and of the effective temperature gradient is calculated as well. For three different temperatures (<inline-formula><math display="inline"><semantics><mrow><mi>T</mi><mo>=</mo><mn>300</mn><mtext> </mtext><mi mathvariant="normal">K</mi></mrow></semantics></math></inline-formula>, <inline-formula><math display="inline"><semantics><mrow><mi>T</mi><mo>=</mo><mn>400</mn><mtext> </mtext><mi mathvariant="normal">K</mi></mrow></semantics></math></inline-formula>, <inline-formula><math display="inline"><semantics><mrow><mi>T</mi><mo>=</mo><mn>500</mn><mtext> </mtext><mi mathvariant="normal">K</mi></mrow></semantics></math></inline-formula>), we determine the values of composition and thermal conductivity corresponding to the optimal thermoelectric energy conversion. The relationship of our approach with Finite-Time Thermodynamics is pointed out.https://www.mdpi.com/1099-4300/22/10/1116finite-time thermodynamicsSilicon–Germanium alloysminimum of thermal conductivityefficiency of thermoelectric systemsminimal energy dissipation
spellingShingle Patrizia Rogolino
Vito Antonio Cimmelli
Thermoelectric Efficiency of Silicon–Germanium Alloys in Finite-Time Thermodynamics
Entropy
finite-time thermodynamics
Silicon–Germanium alloys
minimum of thermal conductivity
efficiency of thermoelectric systems
minimal energy dissipation
title Thermoelectric Efficiency of Silicon–Germanium Alloys in Finite-Time Thermodynamics
title_full Thermoelectric Efficiency of Silicon–Germanium Alloys in Finite-Time Thermodynamics
title_fullStr Thermoelectric Efficiency of Silicon–Germanium Alloys in Finite-Time Thermodynamics
title_full_unstemmed Thermoelectric Efficiency of Silicon–Germanium Alloys in Finite-Time Thermodynamics
title_short Thermoelectric Efficiency of Silicon–Germanium Alloys in Finite-Time Thermodynamics
title_sort thermoelectric efficiency of silicon germanium alloys in finite time thermodynamics
topic finite-time thermodynamics
Silicon–Germanium alloys
minimum of thermal conductivity
efficiency of thermoelectric systems
minimal energy dissipation
url https://www.mdpi.com/1099-4300/22/10/1116
work_keys_str_mv AT patriziarogolino thermoelectricefficiencyofsilicongermaniumalloysinfinitetimethermodynamics
AT vitoantoniocimmelli thermoelectricefficiencyofsilicongermaniumalloysinfinitetimethermodynamics