Experimental method of ammonia decomposition study based on thermal-hydraulic approach

Hydrogen is the promising carbon-free fuel to be used massively in future transport based on fuel cell electric vehicles (FCEV) and internal combustion engines (ICE). The reliable and safe way to store hydrogen in vehicles is an open question. As a promising potential solution, hydrogen storage in l...

Full description

Bibliographic Details
Main Authors: Vasyl Ruzaikin, Ivan Lukashov
Format: Article
Language:English
Published: Elsevier 2022-09-01
Series:Results in Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2590123022002705
_version_ 1798003397407801344
author Vasyl Ruzaikin
Ivan Lukashov
author_facet Vasyl Ruzaikin
Ivan Lukashov
author_sort Vasyl Ruzaikin
collection DOAJ
description Hydrogen is the promising carbon-free fuel to be used massively in future transport based on fuel cell electric vehicles (FCEV) and internal combustion engines (ICE). The reliable and safe way to store hydrogen in vehicles is an open question. As a promising potential solution, hydrogen storage in liquid ammonia is postulated. In this case, the hydrogen is released due to ammonia decomposition under heat energy supply. In the hydrogen ICE, the ammonia decomposition could be provided at the expense of exhaust gas energy. The current article deals with developing test tools and methods for the experimental study of catalysts and reactor prototypes appropriate to the hydrogen ICE. A thermal-hydraulic approach without chromatography and mass spectrometry has been proposed to determine ammonia decomposition kinetics at different fluid pressure, temperature, and flow rate. The tests have validated the approach with the decomposition of ammonia in catalysts with aluminium shavings in stainless steel tube with an inner diameter of 10 mm. The identified ammonia decomposition rate is 0.0119 mol of H2 per gram of catalysts in 1 h.
first_indexed 2024-04-11T12:06:55Z
format Article
id doaj.art-0612231aab0a459095500f3b22961d69
institution Directory Open Access Journal
issn 2590-1230
language English
last_indexed 2024-04-11T12:06:55Z
publishDate 2022-09-01
publisher Elsevier
record_format Article
series Results in Engineering
spelling doaj.art-0612231aab0a459095500f3b22961d692022-12-22T04:24:42ZengElsevierResults in Engineering2590-12302022-09-0115100600Experimental method of ammonia decomposition study based on thermal-hydraulic approachVasyl Ruzaikin0Ivan Lukashov1Corresponding author.; National Aerospace University “Kharkiv Aviation Institute”, Chkalov Str. 17, 61070 Kharkiv, UkraineNational Aerospace University “Kharkiv Aviation Institute”, Chkalov Str. 17, 61070 Kharkiv, UkraineHydrogen is the promising carbon-free fuel to be used massively in future transport based on fuel cell electric vehicles (FCEV) and internal combustion engines (ICE). The reliable and safe way to store hydrogen in vehicles is an open question. As a promising potential solution, hydrogen storage in liquid ammonia is postulated. In this case, the hydrogen is released due to ammonia decomposition under heat energy supply. In the hydrogen ICE, the ammonia decomposition could be provided at the expense of exhaust gas energy. The current article deals with developing test tools and methods for the experimental study of catalysts and reactor prototypes appropriate to the hydrogen ICE. A thermal-hydraulic approach without chromatography and mass spectrometry has been proposed to determine ammonia decomposition kinetics at different fluid pressure, temperature, and flow rate. The tests have validated the approach with the decomposition of ammonia in catalysts with aluminium shavings in stainless steel tube with an inner diameter of 10 mm. The identified ammonia decomposition rate is 0.0119 mol of H2 per gram of catalysts in 1 h.http://www.sciencedirect.com/science/article/pii/S2590123022002705HydrogenAmmonia decompositionInternal combustion engineCatalystsReactor
spellingShingle Vasyl Ruzaikin
Ivan Lukashov
Experimental method of ammonia decomposition study based on thermal-hydraulic approach
Results in Engineering
Hydrogen
Ammonia decomposition
Internal combustion engine
Catalysts
Reactor
title Experimental method of ammonia decomposition study based on thermal-hydraulic approach
title_full Experimental method of ammonia decomposition study based on thermal-hydraulic approach
title_fullStr Experimental method of ammonia decomposition study based on thermal-hydraulic approach
title_full_unstemmed Experimental method of ammonia decomposition study based on thermal-hydraulic approach
title_short Experimental method of ammonia decomposition study based on thermal-hydraulic approach
title_sort experimental method of ammonia decomposition study based on thermal hydraulic approach
topic Hydrogen
Ammonia decomposition
Internal combustion engine
Catalysts
Reactor
url http://www.sciencedirect.com/science/article/pii/S2590123022002705
work_keys_str_mv AT vasylruzaikin experimentalmethodofammoniadecompositionstudybasedonthermalhydraulicapproach
AT ivanlukashov experimentalmethodofammoniadecompositionstudybasedonthermalhydraulicapproach