Hydration Properties of Cement with Liquefied Red Mud Neutralized by Nitric Acid

An increasing amount of red mud (RM) is being generated globally due to the growth in aluminum production. To avoid RM pollution, low-cost methods for effectively recycling RM are being investigated. We propose a method for recycling RM as a construction material. Liquefied RM (LRM) was neutralized...

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Main Authors: Sukpyo Kang, Hyeju Kang, Byoungky Lee
Format: Article
Language:English
Published: MDPI AG 2021-05-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/14/10/2641
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author Sukpyo Kang
Hyeju Kang
Byoungky Lee
author_facet Sukpyo Kang
Hyeju Kang
Byoungky Lee
author_sort Sukpyo Kang
collection DOAJ
description An increasing amount of red mud (RM) is being generated globally due to the growth in aluminum production. To avoid RM pollution, low-cost methods for effectively recycling RM are being investigated. We propose a method for recycling RM as a construction material. Liquefied RM (LRM) was neutralized by nitric acid and added to cement paste, and the hydration heat, compressive strength, and hydration products were investigated. The cement paste with neutralized LRM had a higher compressive strength than that of plain cement paste and cement paste with LRM without neutralization at 1 day of aging; this indicates that nitric acid neutralization increases the early-age strength. Furthermore, the cement paste with 10% neutralized LRM showed 28 days-compressive strength and hydration heating curves similar to the plain mixture, indicating the positive impact of LRM neutralization on the strength. It was noted that a greater quantity of portlandite was produced earlier in cement paste with neutralized LRM than in that without. Therefore, the proposed method of using RM as a concrete additive has the potential to reduce the cost and environmental impact of both construction materials and RM waste management.
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spelling doaj.art-0623dd572b0b47b4b884cd72f14a65cf2023-11-21T20:17:21ZengMDPI AGMaterials1996-19442021-05-011410264110.3390/ma14102641Hydration Properties of Cement with Liquefied Red Mud Neutralized by Nitric AcidSukpyo Kang0Hyeju Kang1Byoungky Lee2Department of Architecture, Woosuk University, Jincheon 27841, KoreaDepartment of Construction Engineering, Woosuk University, Jincheon 27841, KoreaCOCHEMS Co., Ltd. Industrial Tools Circulating Center, 160, Daehwa-ro, Daedeok-gu, Daejeon 34368, KoreaAn increasing amount of red mud (RM) is being generated globally due to the growth in aluminum production. To avoid RM pollution, low-cost methods for effectively recycling RM are being investigated. We propose a method for recycling RM as a construction material. Liquefied RM (LRM) was neutralized by nitric acid and added to cement paste, and the hydration heat, compressive strength, and hydration products were investigated. The cement paste with neutralized LRM had a higher compressive strength than that of plain cement paste and cement paste with LRM without neutralization at 1 day of aging; this indicates that nitric acid neutralization increases the early-age strength. Furthermore, the cement paste with 10% neutralized LRM showed 28 days-compressive strength and hydration heating curves similar to the plain mixture, indicating the positive impact of LRM neutralization on the strength. It was noted that a greater quantity of portlandite was produced earlier in cement paste with neutralized LRM than in that without. Therefore, the proposed method of using RM as a concrete additive has the potential to reduce the cost and environmental impact of both construction materials and RM waste management.https://www.mdpi.com/1996-1944/14/10/2641red mudliquefied red mudred mud neutralizationcement pastecompressive strengthhydration heat
spellingShingle Sukpyo Kang
Hyeju Kang
Byoungky Lee
Hydration Properties of Cement with Liquefied Red Mud Neutralized by Nitric Acid
Materials
red mud
liquefied red mud
red mud neutralization
cement paste
compressive strength
hydration heat
title Hydration Properties of Cement with Liquefied Red Mud Neutralized by Nitric Acid
title_full Hydration Properties of Cement with Liquefied Red Mud Neutralized by Nitric Acid
title_fullStr Hydration Properties of Cement with Liquefied Red Mud Neutralized by Nitric Acid
title_full_unstemmed Hydration Properties of Cement with Liquefied Red Mud Neutralized by Nitric Acid
title_short Hydration Properties of Cement with Liquefied Red Mud Neutralized by Nitric Acid
title_sort hydration properties of cement with liquefied red mud neutralized by nitric acid
topic red mud
liquefied red mud
red mud neutralization
cement paste
compressive strength
hydration heat
url https://www.mdpi.com/1996-1944/14/10/2641
work_keys_str_mv AT sukpyokang hydrationpropertiesofcementwithliquefiedredmudneutralizedbynitricacid
AT hyejukang hydrationpropertiesofcementwithliquefiedredmudneutralizedbynitricacid
AT byoungkylee hydrationpropertiesofcementwithliquefiedredmudneutralizedbynitricacid