Natural djurleite with refined composition Cu61.39S32 revealing disorder of some Cu sites

A djurleite crystal was discovered from a natural sample originally labelled as chalcocite. The djurleite crystal under investigation has a refined composition of Cu61.39S32, thus revealing a Cu deficiency compared to the originally reported Cu62S32 phase [Evans (1979). Z. Kristallogr. 150, 299–320]...

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Autori principali: Yawei Zhou, Changzeng Fan, Bin Wen, Lifeng Zhang
Natura: Articolo
Lingua:English
Pubblicazione: International Union of Crystallography 2022-07-01
Serie:IUCrData
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Accesso online:http://scripts.iucr.org/cgi-bin/paper?S2414314622006940
Descrizione
Riassunto:A djurleite crystal was discovered from a natural sample originally labelled as chalcocite. The djurleite crystal under investigation has a refined composition of Cu61.39S32, thus revealing a Cu deficiency compared to the originally reported Cu62S32 phase [Evans (1979). Z. Kristallogr. 150, 299–320], where all atomic sites are reported to be fully occupied. In addition, the current refinement revealed a splitting of eight of the Cu sites into pairs.
ISSN:2414-3146