Insights into hot deformation of medium entropy alloys: Softening mechanisms, microstructural evolution, and constitutive modelling—a comprehensive review

The recent discovery of multicomponent principal alloys and the enhanced comprehension of their physical metallurgy have significantly advanced the understanding of microstructure engineering and material selection for high-tech applications. The exceptional combination of characteristics found in M...

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Main Authors: Sodiq Abiodun Kareem, Justus Uchenna Anaele, Olajesu Favor Olanrewaju, Esther Dolapo Adewale, Nkemakolam Chikodinaka Osondu-Okoro, Emmanuel Omosegunfunmi Aikulola, Samuel Olumide Falana, Bharat Gwalani, Michael Oluwatosin Bodunrin, Kenneth Kanayo Alaneme
Format: Article
Language:English
Published: Elsevier 2024-03-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785424005398
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author Sodiq Abiodun Kareem
Justus Uchenna Anaele
Olajesu Favor Olanrewaju
Esther Dolapo Adewale
Nkemakolam Chikodinaka Osondu-Okoro
Emmanuel Omosegunfunmi Aikulola
Samuel Olumide Falana
Bharat Gwalani
Michael Oluwatosin Bodunrin
Kenneth Kanayo Alaneme
author_facet Sodiq Abiodun Kareem
Justus Uchenna Anaele
Olajesu Favor Olanrewaju
Esther Dolapo Adewale
Nkemakolam Chikodinaka Osondu-Okoro
Emmanuel Omosegunfunmi Aikulola
Samuel Olumide Falana
Bharat Gwalani
Michael Oluwatosin Bodunrin
Kenneth Kanayo Alaneme
author_sort Sodiq Abiodun Kareem
collection DOAJ
description The recent discovery of multicomponent principal alloys and the enhanced comprehension of their physical metallurgy have significantly advanced the understanding of microstructure engineering and material selection for high-tech applications. The exceptional combination of characteristics found in MEAs can be attributed to their distinctive phase constitution, which is aided by their multi-principal constituents. These properties are seldom encountered in ordinary alloys. Nevertheless, the use of these materials in their as-cast state is challenging due to issues such as the presence of heterogeneity in their chemical makeup, shrinkage porosity, unrefined dendritic structure, and the presence of a quasi-stable eutectic at grain boundaries. Consequently, the utilization of hot deformation methods for the purpose of achieving uniform and refined microstructures in as-cast MEAs has garnered significant interest as a viable approach to address these limitations. This review provides a comprehensive summary of the hot deformation characteristics of MEAs. Factors such as the alloy composition, the phase constituent, deformation parameters and recrystallization mechanisms were observed to influence the microstructural development and phase transition, flow curve characteristics, and mechanical characteristics of MEAs. Additionally, the use of processing map analysis for the determination of optimal processing zones for the hot deformation of MEAs was appraised. The discussion also encompassed the constitutive model description, molecular dynamics modeling, and machine learning algorithm for the prediction of the governing deformation mechanism and the deformation flow stress. Finally, future research directions are suggested.
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spelling doaj.art-069e446c46b343bd99cbbfb8b6fe43172024-03-24T06:58:52ZengElsevierJournal of Materials Research and Technology2238-78542024-03-012953695401Insights into hot deformation of medium entropy alloys: Softening mechanisms, microstructural evolution, and constitutive modelling—a comprehensive reviewSodiq Abiodun Kareem0Justus Uchenna Anaele1Olajesu Favor Olanrewaju2Esther Dolapo Adewale3Nkemakolam Chikodinaka Osondu-Okoro4Emmanuel Omosegunfunmi Aikulola5Samuel Olumide Falana6Bharat Gwalani7Michael Oluwatosin Bodunrin8Kenneth Kanayo Alaneme9Materials Design and Structural Integrity Group, Department of Metallurgical and Materials Engineering, Federal University of Technology Akure, P.M.B. 704, Ondo State, Nigeria; Corresponding author.Department of Metallurgical and Materials Engineering, Federal University of Technology, Owerri, NigeriaMaterials Design and Structural Integrity Group, Department of Metallurgical and Materials Engineering, Federal University of Technology Akure, P.M.B. 704, Ondo State, Nigeria; Department of Material Science and Engineering, Iowa State University, AMES, IA 50011, United StatesMaterials Design and Structural Integrity Group, Department of Metallurgical and Materials Engineering, Federal University of Technology Akure, P.M.B. 704, Ondo State, NigeriaDepartment of Metallurgical and Materials Engineering, Federal University of Technology, Owerri, NigeriaMaterials Design and Structural Integrity Group, Department of Metallurgical and Materials Engineering, Federal University of Technology Akure, P.M.B. 704, Ondo State, NigeriaMaterials Design and Structural Integrity Group, Department of Metallurgical and Materials Engineering, Federal University of Technology Akure, P.M.B. 704, Ondo State, NigeriaMaterials Science and Engineering, North Carolina State University, Raleigh, NC, 27695-7907, United StatesSchool of Chemical and Metallurgical Engineering, University of the Witwatersrand, Johannesburg 2050, South AfricaMaterials Design and Structural Integrity Group, Department of Metallurgical and Materials Engineering, Federal University of Technology Akure, P.M.B. 704, Ondo State, Nigeria; Centre for Nanoengineering and Tribocorrosion, School of Mining, Metallurgy and Chemical Engineering, Faculty of Engineering & the Built Environment, University of Johannesburg, South AfricaThe recent discovery of multicomponent principal alloys and the enhanced comprehension of their physical metallurgy have significantly advanced the understanding of microstructure engineering and material selection for high-tech applications. The exceptional combination of characteristics found in MEAs can be attributed to their distinctive phase constitution, which is aided by their multi-principal constituents. These properties are seldom encountered in ordinary alloys. Nevertheless, the use of these materials in their as-cast state is challenging due to issues such as the presence of heterogeneity in their chemical makeup, shrinkage porosity, unrefined dendritic structure, and the presence of a quasi-stable eutectic at grain boundaries. Consequently, the utilization of hot deformation methods for the purpose of achieving uniform and refined microstructures in as-cast MEAs has garnered significant interest as a viable approach to address these limitations. This review provides a comprehensive summary of the hot deformation characteristics of MEAs. Factors such as the alloy composition, the phase constituent, deformation parameters and recrystallization mechanisms were observed to influence the microstructural development and phase transition, flow curve characteristics, and mechanical characteristics of MEAs. Additionally, the use of processing map analysis for the determination of optimal processing zones for the hot deformation of MEAs was appraised. The discussion also encompassed the constitutive model description, molecular dynamics modeling, and machine learning algorithm for the prediction of the governing deformation mechanism and the deformation flow stress. Finally, future research directions are suggested.http://www.sciencedirect.com/science/article/pii/S2238785424005398Medium entropy alloysHot deformationDynamic recrystallizationProcessing mapsConstitutive modelling
spellingShingle Sodiq Abiodun Kareem
Justus Uchenna Anaele
Olajesu Favor Olanrewaju
Esther Dolapo Adewale
Nkemakolam Chikodinaka Osondu-Okoro
Emmanuel Omosegunfunmi Aikulola
Samuel Olumide Falana
Bharat Gwalani
Michael Oluwatosin Bodunrin
Kenneth Kanayo Alaneme
Insights into hot deformation of medium entropy alloys: Softening mechanisms, microstructural evolution, and constitutive modelling—a comprehensive review
Journal of Materials Research and Technology
Medium entropy alloys
Hot deformation
Dynamic recrystallization
Processing maps
Constitutive modelling
title Insights into hot deformation of medium entropy alloys: Softening mechanisms, microstructural evolution, and constitutive modelling—a comprehensive review
title_full Insights into hot deformation of medium entropy alloys: Softening mechanisms, microstructural evolution, and constitutive modelling—a comprehensive review
title_fullStr Insights into hot deformation of medium entropy alloys: Softening mechanisms, microstructural evolution, and constitutive modelling—a comprehensive review
title_full_unstemmed Insights into hot deformation of medium entropy alloys: Softening mechanisms, microstructural evolution, and constitutive modelling—a comprehensive review
title_short Insights into hot deformation of medium entropy alloys: Softening mechanisms, microstructural evolution, and constitutive modelling—a comprehensive review
title_sort insights into hot deformation of medium entropy alloys softening mechanisms microstructural evolution and constitutive modelling a comprehensive review
topic Medium entropy alloys
Hot deformation
Dynamic recrystallization
Processing maps
Constitutive modelling
url http://www.sciencedirect.com/science/article/pii/S2238785424005398
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